Thermoelectric Thin Films (eBook)

Materials and Devices
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2019 | 1st ed. 2019
XV, 211 Seiten
Springer International Publishing (Verlag)
978-3-030-20043-5 (ISBN)

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This book will provide readers with deep insight into the intriguing science of thermoelectric thin films. It serves as a fundamental information source on the techniques and methodologies involved in thermoelectric thin film growth, characterization and device processing. This book involves widespread contributions on several categories of thermoelectric thin films: oxides, chalcogenides, iodates, nitrides and polymers. This will serve as an invaluable resource for experts to consolidate their knowledge and will provide insight and inspiration to beginners wishing to learn about thermoelectric thin films.

  • Provides a single-source reference on a wide spectrum of topics related to thermoelectric thin films, from organic chemistry to devices, from physical chemistry to applied physics, from synthesis to device implementation;
  • Covers several categories of thermoelectric thin films based on different material approaches such as oxides, chalcogenides, iodates, nitrides and polymers;
  • Discusses synthesis, characterization, and device processing of thermoelectric thin films, as well as the nanoengineering approach to tailor the properties of the used materials at the nanoscale level.



Paolo Mele is currently Professor at SIT Research laboratories, Shibaura Institute of Technology, Tokyo, Japan.. He obtained a Master degree in Chemistry and Ph.D. in Chemical Sciences at Genova University (Italy). In 2003 he moved to ISTEC-SRL in Tokyo to study melt-textured ceramic superconductors. Then he worked as postdoc at Kyoto University (JSPS fellowship) from 2004 to 2007, at Kyushu Institute of Technology (JST fellowship) from 2007 to 2011, at Hiroshima University (as lecturer) from 2011 to 2014 and at Muroran Institute of Technology (as associate professor) from 2015 to 2018 before reaching his current position. His research interests include materials for energy and sustainable development (superconductors and thermoelectrics); fabrication and characterization of thin films of oxides, ceramics and metals; study of the effect of nanostructuration on the physical properties; thermal transport; and vortex matter. He is the author of more than 100 papers in international scientific journals and four book chapters, and has two patents and has contributed to hundreds of communications at international conferences. He edited five books for Springer, including this one.

Dario Narducci obtained his Ph.D. in Chemistry at the University of Milan. From 1988 to 1990 he was Post-Doctoral Fellow at IBM T.J. Watson Research Center. In 1990 he re-joined the University of Milan as an Assistant Professor, moving in 1997 to the University of Milano Bicocca, where he became Associate Professor of Physical Chemistry in 2000. His research interests have focused on the physical chemistry of silicon and on the transport properties of disordered materials. Since 2008 Narducci has developed an intense research activity on thermoelectricity for microharvesting. Since 2010 he is the Chief Technical Officer of a start-up developing silicon-based thermoelectric generators. He is currently involved in the ERC NanoThermMA project and is coordinating a Marie Skłodowska-Curie Global Fellowship in collaboration with the MIT to develop hybrid photovoltaic-thermoelectric generators. He is currently the president of the Italian Thermoelectric Society and served as the treasurer of the European Thermoelectric Society. Author of more than one hundred publications, Narducci also wrote books on nanotechnology and on hybrid thermoelectric-photovoltaic solar harvesters, and filed fifteen patents as well.

Michihiro Ohta received his Ph.D from the Kyushu Institute of Technology in 2002. He was a postdoctoral fellow at the National Institute for Materials Science (NIMS) and the Muroran Institute of Technology before joining the National Institute of Advanced Industrial Science and Technology (AIST) in 2006. He has been a senior researcher at AIST since 2013. He was a visiting scholar at Argonne National Laboratory and Northwestern University from 2011 to 2012. He is a board member of the Thermoelectrics Society of Japan. Ohta is also a technical advisor at the startup company, Mottainai Energy, founded in 2016. His research focuses on the exploration of sulfides and nanostructured materials for thermoelectrics.

Kanishka Biswas obtained his MS and Ph.D degree from the Solid State Structural Chemistry Unit, Indian Institute of Science (2009) under supervision of Prof. C. N. R. Rao and did postdoctoral research with Prof. Mercouri G. Kanatzidis at the Department of Chemistry, Northwestern University (2009-2012). He is an Associate Professor in the New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore. He is pursuing research in solid state chemistry, thermoelectrics, topological materials, 2D materials, perovskite halides and water purification. He has published 95 research papers, 1 book and 5 book chapters. He is a Young Affiliate of The World Academy of Sciences (TWAS) and an Associate of Indian Academy of Science (IASc), Bangalore, India. He is also recipient of Young Scientist Medal-2016 from Indian National Science Academy (INSA), Delhi, India and Young Scientist Platinum Jubilee Award-2015 from The National Academy of Sciences (NASI), Allahabad, India. He is recipient of IUMRS-MRS Singapore Young Researcher Merit Awards in 2016. He is recipient of Materials Research Society of India Medal in 2017. He has also received Young Scientist Wiley Award from IUMRS 2017 in Kyoto, Japan. He is selected as Emerging Investigator by Journal of Materials Chemistry C (2017) and Chem. Commun (2018), Royal Society of Chemistry (RSC).

Professor J.R. Morante is, since 1985, full professor of the Faculty of Physics of the University of Barcelona. Since 2009 he has been the director of the advanced materials for energy area of the Energy Research Institute of Catalonia, IREC, and since the end of 2015 he has been appointed as director of this institute. Previously he has been Vice Dean and dean of the Faculty of Physics of the University of Barcelona, director of the Department of Electronics of this university, head of studies in Electronic Engineering and co-coordinator of the interuniversity master between the University of Barcelona and the Polytechnic University of Catalonia of the master on Engineering in Energy. His activities have been centered in electronic materials and devices; the assessment of their related technologies and produc^ 50), organized various international technological scientific conferences in the field of sensors / microsystems and 'nano-energy' and has been distinguished with the medal Narcís Monturiol of the Generalitat de Catalunya. He has also served as vice president of the European Materials Society and is the editor-in-chief of the Journal of Physics D: Applied Physics.

Dr. Shrikant Saini is a researcher at deprtment of Mechanical engineering at Kyushu Inst. Tech, Kitakyushu, Japan. He obtained his Ph.D. in Mechanical Engineering from the Jeju National University, South Korea in 2011. He has worked in various institutes as a researcher such as the Institute of Technology (IIT) Kanpur, India; Jeju National University, South Korea; Hiroshima University, Japan; University of Utah, USA, and Muroran Institute of Technology, Japan. Dr. Saini has to date published more than 30 peer reviewed research articles in international journals and 2 US patents (applied). His current research interest is energy harvesting/conversion materials specially thermoelectric and superconducting materials

Tamio Endo holds Ph.D. (Kyoto University, Japan) and MsD (Gifu University, Japan) degrees. He is Emeritus Professor at Mie University (Japan), Gifu University Special Researcher (Japan), Honorary Professor of Southwest Jiaotong University (China), Visiting Researcher at University of California- San Diego 1995 (USA). He is currently Special Adviser of Japan Advanced Chemicals in Atsugi, Japan. His research interests include oxide thin films, heterostructures, plasma effects and bonding of polymer films. He has been part of many international academic projects such as Japan-India Cooperative Science Program. He has been organizer and plenary speaker of many of international conferences and has given many foreign university guest talks and a Representative of Team Harmonized Oxides.

 

Preface 5
Introduction 7
Contents 9
Contributors 10
About the Editors 12
1 Thin Films of Bismuth-Telluride-Based Alloys 15
1.1 Introduction 15
1.2 Thin-Film Deposition Methods 17
1.2.1 Conventional Deposition Methods for Bi2Te3-Based Alloy Thin Films 17
1.2.2 Sputtering Deposition Method 17
1.2.3 Electrodeposition Methods 22
1.2.4 Combination Method of Sputtering and Electrodeposition 26
1.2.5 Printing Method 29
1.3 Thin-Film Thermoelectric Generators 38
1.4 Summary 40
References 41
2 Wearable Thermoelectric Devices 44
2.1 Introduction 44
2.2 Materials 45
2.3 Device Design and Fabrication 46
2.4 Applications 49
2.5 Reliability 51
2.6 Summary 54
References 54
3 Theory and Simulations of Lattice Thermal Conduction 56
3.1 Introduction 56
3.2 Theory 57
3.2.1 BTE Under RTA 57
3.2.2 Expression of the Relaxation Time 58
3.2.3 From RTA and Semi-Empirical Scheme to Full Solution: Self-Consistent Calculation of the Relaxation Times 60
3.3 Simulation Procedure 62
3.4 Illustration of Computation of Lattice Thermal Conductivity 62
3.4.1 Aluminium 62
3.4.2 Diamond 63
3.4.3 GaAs 65
3.5 Impact of Rattlers on ? of Thermoelectric Clathrates 67
3.5.1 Ba8 Ga16Ge30 (Ref. Tadano:2015-Impac) 67
3.5.2 CoSb3 and BaCo4Sb12 (Ref. Li:2014-Therm) 71
3.6 Thermal Conductivity of the Earth's Lower Mantle 72
3.7 Molecular Crystals: Limitations of BTE Approach 74
3.8 Conclusions and Outlook 75
References 75
4 Fabrication and Thermoelectric Properties of PEDOT Films and Their Composites 81
4.1 Introduction 81
4.2 Two Types of PEDOT 82
4.3 The TE Performance Optimization of PEDOT:PSS Films 82
4.3.1 Synthesis of PEDOT:PSS 82
4.3.2 TE Properties of Pristine PEDOT:PSS 82
4.3.3 Structural Distortion in PEDOT:PSS 83
4.3.4 Secondary Doping of PEDOT:PSS 84
4.3.5 Removal of PSS 85
4.4 The Synthesis and TE Performance Optimization of S-PEDOT Film 86
4.4.1 Crystalline Structure of S-PEDOT 86
4.4.2 Developments in S-PEDOT's Synthesis 87
4.5 Dedoping Treatments 91
4.6 PEDOT-Based Nanocomposite Film 93
4.6.1 In-Situ Synthesis 93
4.6.2 Particle Size Control 93
4.6.3 One-Step Synthesis Using Multi-Functional Oxidants 95
4.7 Future Prospective on PEDOT-Based TE Films 96
References 100
5 Electric Field Thermopower Modulation of 2D Electron Systems 109
5.1 Introduction 109
5.2 Electric Field Thermopower Modulation Method [16–22] 110
5.3 Electric Field Thermopower Modulation of SrTiO3 [22] 113
5.4 Electric Field Thermopower Modulation of BaSnO3 [18] 116
5.5 Unusually Large Thermopower Modulation in Water-Gated SrTiO3 TFT [20, 21] 122
5.6 Electric Field Thermopower Modulation of AlGaN/GaN Interfaces [17] 125
5.7 Summary 130
References 130
6 Transition-Metal-Nitride-Based Thin Films as Novel Thermoelectric Materials 133
6.1 Introduction 133
6.2 Brief Introduction to Thermoelectricity 134
6.3 The Early Transition-Metal Nitrides 135
6.3.1 Overall Trends 135
6.3.2 ScN 137
6.3.3 CrN 138
6.4 Theoretical Methodology 140
6.5 Ternary Systems 142
6.6 Concluding Remarks 146
References 146
7 Thermoelectric Modules Based on Oxide Thin Films 151
7.1 Introduction 151
7.2 The Promise of Oxide Thin Films Thermoelectric Modules 153
7.2.1 Use of Oxide Thin Films as Sustainable Thermoelectric Materials 153
7.2.2 Enhancement of Conversion Efficiency by Addition of Controlled Nanodefects 154
7.3 State-of-the-art of Oxide Thin Films Thermoelectric Modules 156
7.3.1 Modules Based on n- and p-Type Oxide Thin Film Legs 156
7.3.2 Hybrid Modules Based on Oxide and Metallic Legs 159
7.3.3 Uni-Leg Modules 162
7.4 Summary and Perspective 164
References 167
8 Thermoelectric Properties of Metal Chalcogenides Nanosheets and Nanofilms Grown by Chemical and Physical Routes 169
8.1 Introduction 169
8.2 Thermoelectric Transport Mechanism in Nanosheets 171
8.3 Thin Films of Layered Chalcogenides Prepared by Physical Route 173
8.4 Nanosheets of Layered Chalcogenides Synthesized by Chemical Route 178
8.4.1 Bismuth Telluride 178
8.4.2 Bismuth Selenide 180
8.4.3 Antimony Telluride 182
8.4.4 Solid Solutions and Nanocomposites of Bi2Te3 and Bi2Se3 182
8.4.5 SnSe 184
8.4.6 SnSe2 184
8.4.7 Layered Intergrowth Chalcogenides 186
8.4.8 BiCuSeO 189
8.4.9 Cu2Se 191
8.5 Conclusions and Future Directions 193
References 194
9 Thermoelectric Oxide Thin Films with Hopping Transport 197
9.1 Introduction 197
9.2 Thermoelectric Properties of the Thermoelectric Hopping Oxides 199
9.3 Thin Films for Thermoelectric Applications 201
9.3.1 Thin Films Preparation and Specificity 201
9.3.2 Thin Films Geometry for Thermoelectric Applications 203
9.3.3 The Case of the Hopping Transport in Thin Films for Thermoelectric Applications 205
9.4 Measurement of the Physical Properties of Hopping Conduction Thin Films (in Plane Geometry) 206
9.5 The Example of the Delafossite Oxide Thin Films 208
9.5.1 Influence of the Annealing Temperature 209
9.5.2 Influence of the Film Thickness 211
9.5.3 Elaboration and Properties of Thin Film Thermoelectric Modules Containing a Hopping Oxide 212
9.6 Conclusion 214
References 214
Editorial Note 217
Index 218

Erscheint lt. Verlag 17.7.2019
Zusatzinfo XV, 211 p. 120 illus., 99 illus. in color.
Sprache englisch
Themenwelt Technik Elektrotechnik / Energietechnik
Schlagworte Oxide Thin Films, Multilayers and Nanocomposites • Pulsed Laser Deposition of Thin Films • Thermoelectric materials • Thin films as novel thermoelectric materials • Wearable thermoelectric devices
ISBN-10 3-030-20043-4 / 3030200434
ISBN-13 978-3-030-20043-5 / 9783030200435
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