Liquid Phase Oxidation via Heterogeneous Catalysis (eBook)
546 Seiten
John Wiley & Sons (Verlag)
978-1-118-35675-3 (ISBN)
organic syntheses
From basic principles to new and emerging industrial
applications, this book offers comprehensive coverage of
heterogeneous liquid-phase selective oxidation catalysis. It fully
examines the synthesis, characterization, and application of
catalytic materials for environmentally friendly organic syntheses.
Readers will find coverage of all the important classes of
catalysts, with an emphasis on their stability and reusability.
Liquid Phase Oxidation via Heterogeneous Catalysis
features contributions from an international team of leading
chemists representing both industry and academia. The book begins
with a chapter on environmentally benign oxidants and then
covers:
* Selective oxidations catalyzed by TS-1 and other
metal-substituted zeolites
* Selective catalytic oxidation over ordered nanoporous
metallo-aluminophosphates
* Selective oxidations catalyzed by mesoporous
metal-silicates
* Liquid phase oxidation of organic compounds by supported
metal-based catalysts
* Selective liquid phase oxidations in the presence of supported
polyoxometalates
* Selective oxidations catalyzed by supported metal
complexes
* Liquid phase oxidation of organic compounds by metal-organic
frameworks
* Heterogeneous photocatalysis for selective oxidations with
molecular oxygen
All the chapters dedicated to specific types of catalysts follow
a similar organization and structure, making it easy to compare the
advantages and disadvantages of different catalysts. The final
chapter examines the latest industrial applications, such as the
production of catechol and hydroquinone, cyclohexanone oxime, and
propylene oxide.
With its unique focus on liquid phase heterogeneous oxidation
catalysis, this book enables researchers in organic synthesis and
oxidation catalysis to explore and develop promising new catalytic
materials and synthetic routes for a broad range of industrial
applications.
MARIO G. CLERICI, Laurea in Chemistry, has over thirty-five years of industry experience working with organic synthesis and homogeneous and heterogeneous catalysis in the ENI group. He also taught courses in the Department of Industrial Chemistry at the University of Turin, Italy, for eight years and served as a scientific expert on clean catalytic technologies at the International Centre for Science and High Technology, Trieste. A recipient of the Donald W. Breck Award, Dr. Clerici holds more than forty patents. OXANA A. KHOLDEEVA, PhD, is Head of the Research Group for Heterogeneous Catalysis for Liquid-Phase Selective Oxidations at the Boreskov Institute of Catalysis, Russia, and a visiting professor at several universities in Europe and the United States. As the author of over 100 articles and nine patents, she participated in the expert panel of the sixth World Congress on Oxidation Catalysis and is a member of the International Advisory Board for the International Symposium on Activation of Dioxygen and Homogeneous Catalytic Oxidation (ADHOC).
Preface
List of contributors
1 Environmentally Benign Oxidants
Giorgio Strukul and Alessandro Scarso
1.1 Introduction
1.2 Oxygen (Air)
1.3 Alkylhydroperoxides
1.4 Hydrogen Peroxide
1.5 Conclusions
References
2 Oxidation Reactions Catalyzed by Transition Metal-Substituted Zeolites
Mario G. Clerici and Marcelo E. Domine
2.1 Introduction
2.2 Synthesis and Characterization of Zeolites
2.3 Catalytic Properties
2.4 Mechanistic Aspects
2.5 Stability of Metal-Substituted Zeolites to Reaction Conditions
2.6 Conclusions
References
3 Selective Catalytic Oxidation over Ordered Nanoporous Metallo-Aluminophosphates
Parasuraman Selvam and Ayyamperumal Sakthivel
3.1 Introduction
3.2 Synthesis
3.3 Characterization
3.4 Catalytic Properties
3.5 Mechanistic Aspects
3.6 Catalysts Stability
3.7 Conclusion
References
4 Selective Oxidations Catalyzed by Mesoporous Metal-Silicates
Oxana A. Kholdeeva
4.1 Introduction
4.2 Synthesis and Characterization
4.3 Catalytic Properties
4.4 Mechanistic Aspects 4.5 Stability
4.5.1 Mechanisms of Deactivation 4.5.2 Solving Problem of Hydrothermal Stability 4.5.3 Hydrothermally Stable Catalysts: Scope and Limitations 4.6 Conclusion and Outlook
References
5 Liquid phase oxidation of organic compounds by supported metal-based catalysts with a focus on gold
Cristina Della Pina, Ermelinda Falletta and Michele Rossi
5.1 Introduction
5.2 Catalyst Preparation and Characterization
5.3 Catalytic Properties
5.3.3 Oxidation of Carbohydrates: the Case of Glucose
5.4 Reaction Mechanisms
5.5 Catalyst Stability
5.6 Conclusions
References
6 Selective Liquid Phase Oxidations in the Presence of Supported Polyoxometalates
Craig L. Hill and Oxana A. Kholdeeva
6.1 Introduction
6.2 Synthesis and Characterization
6.3 Catalytic Properties
6.4 Mechanistic Aspects
6.5 Stability
6.6 Conclusion
References
7 Selective Oxidations Catalyzed by Supported Metal Complexes
Alexander Sorokin
7.1 Introduction
7.2 Synthesis and Characterization
7.2.1 General Synthetic Strategies 7.2.1.1 Grafting
7.3 Catalytic Properties and Stability
7.4 General Remarks on Stability
7.5 Conclusion
References
8 Liquid Phase Oxidation of Organic Compounds by Metal-Organic Frameworks
YoungKyu Hwang, Gérard Férey, U-Hwang Lee and Jong-San Chang
8.1 Introduction 8.2 Characteristics and Active Sites
8.2.1 Characteristics
8.3 Catalytic Properties
8.4 Mechanistic Aspects
8.5 Stability
8.6 Conclusion
References
9 Heterogeneous Photocatalysis for Selective Oxidations with Molecular Oxygen
Andrea Maldotti, Rossano Amadelli and Alessandra Molinari
9.1 Introduction
9.2 Catalysts Preparation and Mechanistic Aspects
9.3 Catalytic Properties
9.4 Stability
9.5 Conclusions
References
10 Industrial Applications
10.1 The Hydroxylation of Phenol to Hydroquinone and Catechol
Ugo Romano and Marco Ricci
References
10.2 The Greening of Nylon: the Ammoximation Process
Franco Rivetti and Roberto Buzzoni
References
10.3 Production of Propylene Oxide
Anna Forlin, Massimo Bergamo and Joerg Lindner
References
10.4 Engineering Aspects of Liquid Phase Oxidations
Bruce D. Hook
Reactor.
ReferencesIndex
"I strongly recommend it, as it covers recent advances and
concepts all within one volume. PhD students will draw inspiration
from this book, both for the preparation of new or modified
catalytic materials and for applications in the selective
oxy-functionalization of organic substrates, while more experienced
researchers will benefit from the opportunity to read a
comprehensive and comparative analysis of the relevant
literature." (Angew. Chem. Int.
Ed., 1 October 2014)
Erscheint lt. Verlag | 26.4.2013 |
---|---|
Sprache | englisch |
Themenwelt | Naturwissenschaften ► Chemie ► Organische Chemie |
Naturwissenschaften ► Chemie ► Physikalische Chemie | |
Naturwissenschaften ► Chemie ► Technische Chemie | |
Technik | |
Schlagworte | catalysis • Chemie • Chemistry • Heterogene Katalyse • Industrial Chemistry • Katalyse • Methods - Synthesis & Techniques • Organische Chemie / Methoden, Synthesen, Verfahren • Technische u. Industrielle Chemie |
ISBN-10 | 1-118-35675-6 / 1118356756 |
ISBN-13 | 978-1-118-35675-3 / 9781118356753 |
Haben Sie eine Frage zum Produkt? |
Größe: 9,0 MB
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