Liquid Phase Oxidation via Heterogeneous Catalysis (eBook)

MARIO G. CLERICI, Laurea in Chemistry, has over thirty-five years of industry experience working with organic synthesis and homogeneous and heterogeneous catalysis in the ENI group. He also taught courses in the Department of Industrial Chemistry at the University of Turin, Italy, for eight years and served as a scientific expert on clean catalytic technologies at the International Centre for Science and High Technology, Trieste. A recipient of the Donald W. Breck Award, Dr. Clerici holds more than forty patents. OXANA A. KHOLDEEVA, PhD, is Head of the Research Group for Heterogeneous Catalysis for Liquid-Phase Selective Oxidations at the Boreskov Institute of Catalysis, Russia, and a visiting professor at several universities in Europe and the United States. As the author of over 100 articles and nine patents, she participated in the expert panel of the sixth World Congress on Oxidation Catalysis and is a member of the International Advisory Board for the International Symposium on Activation of Dioxygen and Homogeneous Catalytic Oxidation (ADHOC).

Preface

List of contributors

1 Environmentally Benign Oxidants
Giorgio Strukul and Alessandro Scarso

1.1 Introduction

1.2 Oxygen (Air)

1.3 Alkylhydroperoxides

1.4 Hydrogen Peroxide

1.5 Conclusions

References

2 Oxidation Reactions Catalyzed by Transition Metal-Substituted Zeolites
Mario G. Clerici and Marcelo E. Domine

2.1 Introduction

2.2 Synthesis and Characterization of Zeolites

2.3 Catalytic Properties

2.4 Mechanistic Aspects

2.5 Stability of Metal-Substituted Zeolites to Reaction Conditions

2.6 Conclusions

References

3 Selective Catalytic Oxidation over Ordered Nanoporous Metallo-Aluminophosphates
Parasuraman Selvam and Ayyamperumal Sakthivel

3.1 Introduction

3.2 Synthesis

3.3 Characterization

3.4 Catalytic Properties

3.5 Mechanistic Aspects

3.6 Catalysts Stability

3.7 Conclusion

References

4 Selective Oxidations Catalyzed by Mesoporous Metal-Silicates
Oxana A. Kholdeeva

4.1 Introduction

4.2 Synthesis and Characterization

4.3 Catalytic Properties

4.4 Mechanistic Aspects 4.5 Stability

4.5.1 Mechanisms of Deactivation 4.5.2 Solving Problem of Hydrothermal Stability 4.5.3 Hydrothermally Stable Catalysts: Scope and Limitations 4.6 Conclusion and Outlook

References

5 Liquid phase oxidation of organic compounds by supported metal-based catalysts with a focus on gold
Cristina Della Pina, Ermelinda Falletta and Michele Rossi

5.1 Introduction

5.2 Catalyst Preparation and Characterization

5.3 Catalytic Properties

5.3.3 Oxidation of Carbohydrates: the Case of Glucose

5.4 Reaction Mechanisms

5.5 Catalyst Stability

5.6 Conclusions

References

6 Selective Liquid Phase Oxidations in the Presence of Supported Polyoxometalates
Craig L. Hill and Oxana A. Kholdeeva

6.1 Introduction

6.2 Synthesis and Characterization

6.3 Catalytic Properties

6.4 Mechanistic Aspects

6.5 Stability

6.6 Conclusion

References

7 Selective Oxidations Catalyzed by Supported Metal Complexes
Alexander Sorokin

7.1 Introduction

7.2 Synthesis and Characterization

7.2.1 General Synthetic Strategies 7.2.1.1 Grafting

7.3 Catalytic Properties and Stability

7.4 General Remarks on Stability

7.5 Conclusion

References

8 Liquid Phase Oxidation of Organic Compounds by Metal-Organic Frameworks
YoungKyu Hwang, Gérard Férey, U-Hwang Lee and Jong-San Chang

8.1 Introduction 8.2 Characteristics and Active Sites

8.2.1 Characteristics

8.3 Catalytic Properties

8.4 Mechanistic Aspects

8.5 Stability

8.6 Conclusion

References

9 Heterogeneous Photocatalysis for Selective Oxidations with Molecular Oxygen
Andrea Maldotti, Rossano Amadelli and Alessandra Molinari

9.1 Introduction

9.2 Catalysts Preparation and Mechanistic Aspects

9.3 Catalytic Properties

9.4 Stability

9.5 Conclusions

References

10 Industrial Applications

10.1 The Hydroxylation of Phenol to Hydroquinone and Catechol
Ugo Romano and Marco Ricci

References

10.2 The Greening of Nylon: the Ammoximation Process
Franco Rivetti and Roberto Buzzoni

References

10.3 Production of Propylene Oxide
Anna Forlin, Massimo Bergamo and Joerg Lindner

References

10.4 Engineering Aspects of Liquid Phase Oxidations
Bruce D. Hook

Reactor.

ReferencesIndex

"I strongly recommend it, as it covers recent advances and
concepts all within one volume. PhD students will draw inspiration
from this book, both for the preparation of new or modified
catalytic materials and for applications in the selective
oxy-functionalization of organic substrates, while more experienced
researchers will benefit from the opportunity to read a
comprehensive and comparative analysis of the relevant
literature." (Angew. Chem. Int.
Ed., 1 October 2014)