Handbook of Elemental Speciation (eBook)

Rita Cornelis, Department of Analytical Chemistry, Ghent University, The Netherlands.

List of Contributors.

Preface.

Technical Abbreviations and Acronyms.

1 Introduction.

2 Sampling: Collection, Storage.

2.1 Sampling: Collection, Processing and Storage of
Environmental Samples.

2.2 Sampling of Clinical Samples: Collection and Storage.

2.3 Food: Sampling with Special Reference to Legislation,
Uncertainty and Fitness for Purpose.

2.4 Sampling: Collection, Storage - Occupational
Health.

3 Sample Preparation.

3.1 Sample Treatment for Speciation Analysis in Biological
Samples.

3.2 Sample Preparation Techniques for Elemental Speciation
Studies.

3.3 Sample Preparation - Fractionation (Sediments, Soils,
Aerosols and Fly Ashes).

4 Separation Techniques.

4.1 Liquid Chromatography.

4.2 Gas Chromatography and Other Gas Based Methods.

4.3 Capillary Electrophoresis in Speciation Analysis.

4.4 Gel Electrophoresis for Speciation Purposes.

5 Detection.

5.1 Atomic Absorption and Atomic Emission Spectrometry.

5.2 Flow Injection Atomic Spectrometry for Speciation.

5.3 Detection by ICP-Mass Spectrometry.

5.4 Plasma Source Time-of-flight Mass Spectrometry: a Powerful
Tool for Elemental Speciation.

5.5 Glow Discharge Plasmas as Tunable Sources for Elemental
Speciation.

5.6 Electrospray Methods for Elemental Speciation.

5.7 Elemental Speciation by Inductively Coupled Plasma-Mass
Spectrometry with High Resolution Instruments.

5.8 On-line Elemental Speciation with Functionalised Fused
Silica Capillaries in Combination with DIN-ICP-MS.

5.9 Speciation Analysis by Electrochemical Methods.

5.10 Future Instrumental Development for Speciation.

5.11 Biosensors for Monitoring of Metal Ions.

5.12 Possibilities Offered by Radiotracers for Method
Development in Elemental Speciation Analysis and for Metabolic and
Environmentally Related Speciation Studies.

6 Direct Speciation of Solids.

6.1 Characterization of Individual Aerosol Particles with
Special Reference to Speciation Techniques.

6.2 Direct Speciation of Solids: X-ray Absorption Fine Structure
Spectroscopy for Species Analysis in Solid Samples.

7 Calibration.

7.1 Calibration in Elemental Speciation Analysis.

7.2 Reference Materials.

8 Screening Methods for Semiquantitative Speciation
Analysis.

9 Risk Assessments/Regulations.

9.1 Environmental Risk Assessment and the Bioavailability of
Elemental Species.

9.2 Speciation and Legislation.

Index.

"This book provides broad coverage of the different aspects of the
analysis of elemental species..." (Journal of the American
Chemistry Society, 2004 Vol. 126)

"...a welcome contribution to the literature...will provide a
useful insight..." (Trends in Analytical Chemistry, Vol 23(4),
April 2004)

"...the reader can use this book as a reference book for the
next 5 to 10 years.." (Applied Organmettallic Chemistry, Jan
2004)

"...a long-awaited high-quality handbook...will be of great
value in both academia and industry." (Angewandte Chemie, Vol.43,
No.42, 25th October 2004)

"Each chapter, written by an expert on the field, is a stand
alone reference...an excellent introductory text" (International
Journal of Environmental Analytical Chemistry 2004)

"...provides an excellent compendium of information on all the
important methods of speciation analysis..." (Analytical &
Bioanalytical Chemistry, No.380, 2004)

"...this is a long-awaited high-quality handbook for speciation
analysis ...(and) has the potential to become one of the most
frequently used books in the personal shelves of specialists in the
field and teachers of analytical chemistry!" (also in German,
Angewandte Chemie, 2004; Vol 43; No. 42)