Anionic Polymerization -

Anionic Polymerization

Principles, Practice, Strength, Consequences and Applications
Buch | Hardcover
1082 Seiten
2015 | 1st ed. 2015
Springer Verlag, Japan
978-4-431-54185-1 (ISBN)
427,99 inkl. MwSt
This book examines a wide range of topics on anionic polymerization, from basic principles to experimental techniques important for practice. Coverage includes recent advances and potential applications.
This book presents these important facts: a) The mechanism of anionic polymerization, a more than 50-year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, and their structural mixed (co)polymers, etc.) have been advanced significantly; c) Based on such polymers, new morphological and self-organizing nano-objects and supra molecular assemblies have been created and widely studied and are considered nanodevices in the fields of nano science and technology; d) New high-tech and industrial applications for polymeric materials synthesized by anionic polymerization have been proposed. These remarkable developments have taken place in the last 15 years. Anionic polymerization continues to be the only truly living polymerization system (100 % termination free under appropriate conditions) and consequently the only one with unique capabilities in the synthesis of well-defined (i.e., precisely controlled molecular weight, nearly mono-disperse molecular weight distribution, structural and compositional homogeneity) complex macromolecular architectures. This book, with contributions from the world’s leading specialists, will be useful for all researchers, including students, working in universities, in research organizations, and in industry.

Professor Nikos Hadjichristidis Professor of Chemical Sciences Division of Chemical and Life Sciences & Engineering King Abdullah University of Science and Technology (KAUST) Kingdom of Saudi Arabia *Chemistry of Thermoplastic Elastomers Award of ACS, Rubber Division, USA, 2011 *Cooperative Award of ACS Division of Polymeric Materials: Science and Engineering, USA, 2010 *International Award of the Society of Polymer Science, Japan, 2007 Akira HIRAO, Ph.D. Professor of Organic and Polymeric Materials Tokyo Institute of Technology Japan *Japan Polymer Society Award (2010) *member of the Editorial Board of "Macromolecules", "Polymer Journal"

Schlenk Techniques for Anionic Polymerization.- High Vacuum Techniques for Anionic Polymerization.- Non-Polar Monomers: Styrene and 1,3-Butadiene Derivatives.- Anionic Polymerization of Polar Vinyl Monomers: Vinylpyridines, (Meth)acrylates, (Meth)acrylamides, (Meth)acrylonitrile, Phenyl Vinyl Sulfoxide, Benzofulvene and Other Monomers.- Cyclic Monomers: Epoxides, Lactide, Lactones, Lactams, Cyclic Silicon-containing monomers, Cyclic Carbonates and others.- Ring-opening polymerization of N-carboxyanhydrides for preparation of polypeptides and polypeptide-based hybrid materials with various molecular architectures.- Living Anionic Polymerization of Isocyanates.- Poly(ferrocenylsilanes) with controlled macromolecular architecture by anionic polymerization: Applications in patterning and lithography.- Polymerization Using Phosphazene Bases.- Group Transfer Polymerization of Acrylic Monomers.- Surface Initiated Anionic Polymerization from Nanomaterials.- Block Copolymers by Anionic Polymerization: Recent Synthetic Routes and Developments.- Graft and Comblike Polymers.- Star-Branched Polymers (Star Polymers).- Synthesis of Dendrimer-like Polymers.- Complex Branched Polymers.- Block Copolymers Containing Polythiophene Segments.- Block Copolymers and Miktoarm Star-Branched Polymers.- Control of Surface Structure and Dynamics of Polymers Based on Precision Synthesis.- Block Copolymers as Anti-fouling and Fouling Resistant Coatings.- Micellar Structures from Anionically Synthesized Block Copolymers.- Block Copolymers for Self-assembling Lithographic Materials.- Methacrylate-Based Polymers for Industrial Uses.- The Critical Role of Anionic Polymerization for Advances in the Physics of Polyolefins.- Future Remarks.

Zusatzinfo 127 Illustrations, color; 690 Illustrations, black and white; IX, 1082 p. 817 illus., 127 illus. in color.
Verlagsort Tokyo
Sprache englisch
Maße 155 x 235 mm
Themenwelt Naturwissenschaften Chemie Organische Chemie
Naturwissenschaften Chemie Physikalische Chemie
Technik Maschinenbau
Schlagworte Anionic Polymerization • block copolymers • Complex Macromolecular Architectures • Cyclic Monomers • Morphological Self-organized Nanomaterial • Nano-objects • Non-polar Monomers • Polar Monomers • Polymerization • Polyolefins
ISBN-10 4-431-54185-3 / 4431541853
ISBN-13 978-4-431-54185-1 / 9784431541851
Zustand Neuware
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