Main Chemistry Group (eBook)

Cover 1
Contents 6
Chapter 1. The Reactions of Stable Nucleophilic Carbenes with Main Group Compounds 10
I. Introduction 10
II. Group 1, 2, and 12 Complexes 12
III. Group 13 Complexes 18
IV. Silicon, Germanium, Tin, and Lead Complexes 25
V. Group 15 Complexes 29
VI. Sulfur, Selenium, and Tellurium Complexes 31
VII. Halogen Complexes 34
VIII. Conclusions 37
References 38
Chapter 2. Group I Complexes of P- and As-Donor Ligands 42
I. Introduction 42
II. Charge-Localized Ligands 44
III. Charge-Delocalized Ligands 80
IV. Tertiary Phosphine-Functionalized Ligands 98
V. Miscellaneous Complexes 106
VI. Conclusion 110
References 110
Chapter 3. Aqueous Solution Chemistry of Beryllium 118
I. Introduction 118
II. Properties of Beryllium 124
III. The Beryllium Ion 124
IV. Beryllium Hydrolysis 125
V. Interaction with Inorganic Ligands 140
VI. Interaction with Organic Ligands 145
VII. Conclusions 172
References 173
Chapter 4. Group 2 Element Precursors for the Chemical Vapor Deposition of Electronic Materials 182
Text 182
References 199
Chapter 5. Molecular, Complex Ionic, and Solid-State PON Compounds 202
I. Introduction 202
II. Molecular PON Compounds 203
III. Acyclic Molecular Ionic PON Compounds 204
IV. Cyclic PON Compounds 206
V. Solid-State PON Compounds 218
VI. Conclusion 234
References 235
Chapter 6. Molecular Clusters of Dimetalated Primary Phosphanes and Arsanes 244
I. Introduction 245
II. Dilithiation and Disodiation of Primary Phosphanes and Arsanes 250
III. Dicopper Phosphandiides 267
IV. Magnesium Phosphandiides 268
V. Tin(II) Phosphandiides 271
VI. Aluminum, Gallium, and Indium Phosphandiides and Arsandiides 276
VII. Mixed-Metalated Phosphandiides and Arsandiides. 283
VIII. Conclusion 289
References 291
Chapter 7. Coordination Complexes of Bismuth(III) Involving Organic Ligands with Pnictogen or Chalcogen Donors 294
I. Introduction and Scope 295
II. Alkoxides, Thiolates, and Selenolates 305
III. Carboxylates, Thiocarboxylates, Dithiocarboxylates, and Diselenocarboxylates 315
IV. Ethers and Thioethers 324
V. Ketones and Thiones 330
VI. Amides 333
VII. Amines, Phosphines, and Arsines 335
VIII. Nonsymmetric Bifunctional and Multifunctional Ligands 343
IX. Conclusions 358
References 358
Chapter 8. Phanes Bridged by Group 14 Heavy Elements 368
I. Introduction 368
II. An Introductory Case Study on 3,4,7,8-Tetrasilacycloocta-1,5-diyne 370
III. [2.2]Cyclophanes 372
IV. Tetrasila[2.2](2,5)heterophanes 389
V. Hexasila[2.2.2](1,3,5)cyclophane 400
VI. [2n]Paracyclophanes Bridged by Si, Ge, and Sn 404
VII. [n]Cyclophanes Bridged by Si 409
VIII. Conclusion 414
References 415
Index 418
Contents of Previous Volumes 430