Advances in Inorganic Chemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry, Volume 46 4
Copyright Page 5
Contents 6
Chapter 1. The Octahedral M6Y8 and M6Y12 Clusters of Group 4 and 5 Transition Metals 10
I. Introduction 10
II. Group 6 12
III. Group 5 Metal Halide Clusters 33
IV. Materials Chemistry Derived from Soluble Metal Halide Clusters 44
References 53
Chapter 2. Recent Advances in Noble-Gas Chemistry 60
I. Introduction 60
II. Recent Review Literature 62
III. The Possibility of Argon Chemistry 63
IV. Krypton Chemistry 64
V. Xenon Chemistry 70
VI. Radon Chemistry 100
References 102
Chapter 3. Coming to Grips with Reactive Intermediates 110
I. Introduction 110
II. Reaction Intermediates: Nerve Centers of Chemical Reactions 115
III. Experimental Characterization of Reaction Intermediates: Retardation 116
IV. Experimental Characterization of Reaction Intermediates: Time-Resolved Methods 145
V. Experimental Characterization of Reaction Intermediates: Flow and Other Methods 164
VI. Conclusions 172
References 175
Chapter 4. Toward the Construction of Functional Solid-State Supramolecular Metal Complexes Containing Copper(I) and Silver(I) 182
I. Introduction 183
II. Helical Frameworks 185
III. S----S Contact-Assembled Frameworks 201
IV. Hexagonal Frameworks and Graphite-like Structures 213
V. Hydrogen-Bond-Assembled Frameworks 228
VI. .–.-Interaction-Assembled Frameworks 237
VII. Diamondoid Frameworks 249
VIII. Other Frameworks Based on Covalent Bonds 260
IX. Concluding Remarks 301
References 302
Chapter 5. Manganese Redox Enzymes and Model Systems: Properties, Structures, and Reactivity 314
I. Introduction 314
II. The Enzymes 319
III. Structural Models 352
IV. Physical Properties 388
V. Reactivity 402
VI. Conclusion 433
References 434
Chapter 6. Calcium-Binding Proteins 450
I. Introduction 450
II. Intracellular EF-Hand Calcium-Binding Proteins 452
III. Calcium-Mediated Membrane-Binding Proteins 465
IV. Extracellular Calcium-Binding Proteins 479
V. Summary 494
References 494
Chapter 7. Leghemoglobin: Properties and Reactions 504
I. Introduction 504
II. Structure 506
III. Biological Localization 508
IV. Reactions with Different Molecules 510
V. Oxidation of Fe(II) Leghemoglobin 516
VI. Oxidation of Fe(III) Leghemoglobin 520
VII. Reduction of Fe(IV)=O Leghemoglobin 528
VIII. Reduction of Fe(III) Leghemoglobin 533
IX. Reactions of Globin-Derived Radicals 536
References 547
Index 552
Contents of Previous Volumes 564