Advances in Inorganic Chemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry, Volume 41 4
Copyright Page 5
CONTENTS 6
Chapter 1. The Coordination Chemistry of Technetium 10
I. Introduction 11
II. Technetium(-I) 14
III. Technetium(0) 14
IV. Technetium(I) 16
V. Technetium(II) 26
VI. Technetium(III) 36
VII. Technetium(IV) 54
VIII. Technetium(V) 63
IX. Technetium(VI) 89
X. Technetium(VII) 103
XI. Appendix: Abbreviations 108
References 110
Chapter 2. Chemistry of Pentafluorosulfanyl Compounds 134
I. Introduction 135
II. Pentafluorosulfanyl Halides 135
III. Pentafluorosulfanyl Hypohalites, SF5OX 139
IV. Pentafluorosulfanylalkanes, Alkenes, and Alkynes 141
V. Sulfur Isocyanate Pentafluoride and Sulfur Isothiocyanate Pentafluoride 147
VI . Sulfur Cyanate Pentafluoride, SF5OCN 151
VII. Sulfur Cyanide Pentafluoride, SF5CN 152
VIII. Sulfur Isocyanide Pentafluoride, SF5NC 152
IX. Pentafluorosulfanylamine and Other Derivatives 153
X. Pentafluorosulfanyl N,N-Dichloroamine, SF5NCl2 154
XI. Pentafluorosulfanyl N,N Difluoramine, SF5NF2 155
XII. Pentafluorosulfanyl Perfluoroalkylamines, SF5N(H)Rf 155
XIII. SF5N(CF3)2 156
XIV. SF5N(X)CF3 (X = F, C1, Br, I) 156
XV. SF5N(Cl)Rf (Rf = C2F5, n-C3F7, n-C4F9) 158
XVI. Bis(pentafluorosulfany1)perfluoroalkylamines 158
XVII. Tris(pentafluorosulfanyl)amine, (SF5)3N 159
XVIII. Bis(pentafluorosulfanyl)bis( trifluoromethyl)hydrazine, SF5(CF3)NN(CF2)SF5 159
XIX. Tetrakis(pentafluorosulfanyl)hydrazine, (SF5)2NN(SF5)2 159
XX. Bis(pentafluorosulfanyl)amine, (SF5)2NH 160
XXI. (SF5)2NX (X=F, Cl) 160
XXII. N-Pentafluorosulfanyl Haloimines, F5SN = CX2 (X = Cl, F) 161
XXIII. Pentafluorosulfanyliminodihalosulfanes, SF5N = SX2 (X = F, Cl) 164
XXIV. Pentafluorosulfanyl-P-Sultones and Sulfonic Acids 166
XXIV. Pentafluorosulfanyl-ß-Sultones and Sulfonic Acids 166
References 170
Chapter 3. The Hunting of the Gallium Hydrides 180
I. Introduction 181
II. History and Chemical Background 182
III. Conduct of the Hunt: Practical Methods of Attack 186
IV. Toward Gallane: Preparations for the Hunt 197
V. Gallane at Last! 205
VI. Hydrogen-Rich Derivatives of Gallane 220
VII. Hydrides of the Other Group 13 Metals: Preliminaries and Prospects 230
References 237
Chapter 4. The Structures of the Group 15 Element(III) Halides and Halogenoanions 242
I. Introduction 242
II. Element Trihalides, EX3 243
III. Element(III) Halogenoanions 247
IV. General Comments 273
References 277
Note Added in Proof 280
Chapter 5. lntervalence Charge Transfer and Electron Exchange Studies of Dinuclear Ruthenium Complexes 282
I. Introduction 282
II. Mixed-Valence Complexes 283
III. Electron Exchange 313
IV. Future Studies 322
V. Glossary of Abbreviations and Ligand Structures 323
References 328
Chapter 6. Recent Synthetic, Structural, Spectroscopic, and Theoretical Studies on Molecular Phosphorus Oxides and Oxide Sulfides 336
I. Introduction 336
II. Molecular Phosphorus Oxides 338
III. Molecular Phosphorus Oxide Sulfides 373
IV. Comparative Considerations 390
V. Concluding Remarks 392
References 393
Chapter 7. Structure and Reactivity of Transferrins 398
I. Introduction 398
II. Biological Roles 400
III. Transferrin Structure 402
IV. Properties of the Metal and Anion Sites 428
V. Mechanisms of Binding and Release 454
VI. Recombinant DNA Studies 461
VII. Concluding Remarks 464
References 465
INDEX 474
CONTENTS OF PREVIOUS VOLUMES 486