Organic Transformations in Water (eBook)
670 Seiten
Wiley-VCH (Verlag)
978-3-527-84682-5 (ISBN)
Harness sustainable, environmentally friendly chemical processes with this timely volume
Green chemistry has played a leading role in the broader search for environmentally sustainable industry. One of its most important goals is the shift from volatile, hazardous organic solvents to environmentally friendly ones, of which by far the most promising is water. Cultivating organic transformations using water as a solvent is one of the most crucial steps towards the creation of green, sustainable chemical production processes.
Organic Transformations in Water provides a cutting-edge overview of water as a reaction medium for synthesis and catalysis. After a brief introduction, the book moves through each of the most important classes of organic transformation before concluding with a survey of industrial applications.
The book will also cover:
- Chemistry and physicochemical aspects of 'on-water' and 'in-water' reactions
- C-H activation, metathesis, nucleophilic addition and substitution, oxidation and reduction, and many more
- Asymmetric organic reactions in water
- Applications in organocatalysis, electrocatalysis, and photocatalysis
Timely and comprehensive, Organic Transformations in Water is a must-own volume for researchers and industry professionals looking to revolutionize their work in a sustainable way.
Gopinathan Anilkumar is a Professor of Organic Chemistry at the School of Chemical Sciences, Mahatma Gandhi University in Kerala, India. His research interests lie in the areas of organic synthesis, medicinal chemistry, heterocycles, and catalysis. He has published more than 215 papers in peer-reviewed journals, 7 patents, 11 book chapters, and edited two books.
Nissy Ann Harry is an Assistant Professor in the Department of Chemistry at Catholicate College in Pathanamthitta, Kerala, India, since 2021. Her research interests include organic synthesis, catalysis, and green chemistry.
Sankuviruthiyil M. Ujwaldev is an Assistant Professor in the Department of Chemistry at Sree Kerala Varma College in Thrissur, Kerala, India, since 2022. His research interests include synthetic organic chemistry and transition metal catalysis.
List of Abbreviations
| A3 | aldehyde-alkyne-amine |
| ABNO | 9-azabicyclo[3.3.1]nonane N-oxyl |
| ADH | alcohol dehydrogenase |
| API | active pharmaceutical ingredient |
| ATRP | atom transfer radical polymerization |
| BIMs | bis(indolyl)methanes |
| BMIDA | boronic acid N-methyliminodiacetic acid |
| Bpy | bipyridine |
| BVMs | Baeyer–Villiger monooxygenases |
| C-H | carbon–hydrogen |
| C4A4 | calix[4]arene tetracarboxylic acid |
| cBRIDP | di-t-butyl(2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine |
| CDC | cross dehydrogenative coupling |
| CE | coulombic efficiency |
| CFP | carbon fiber paper |
| COMU | 1-cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylamino-morpholinocarbenium hexafluorophosphate |
| Cryo-TEM | cryogenic transmission electron microscopy |
| CSTR | continuously stirred tank reactor |
| CTAB | cetrimonium bromide |
| CTAC | cetyltrimethylammonium chloride |
| CTF | covalent triazine framework |
| β-CD | β-cyclodextrin |
| CZA | citrazinic acid |
| CoQ10 | coenzyme Q10 |
| D-A | Diels–Alder |
| DABCO | 1,4-diazabicyclo[2.2.2]octane |
| DBPNA | 2,6-dibromo-4-nitroaniline |
| DBSA | 4-dodecylbenzene sulfonic acid |
| DBU | 1,8-diazabicyclo[5.4.0]undec-7-ene |
| DCGS | diester cationic gemini surfactant |
| DCILs | dicationic ionic liquids |
| DCM | dichloromethane |
| DEAD | diethyl azodicarboxylate |
| DELs | DNA-encoded libraries |
| DEPO | diethylphosphine oxide |
| DFT | density functional theory |
| DG | directing group |
| DIPEA | N,N-di-isopropylethylamine |
| DLS | dynamic light scattering |
| DMAD | dimethyl azodicarboxylate |
| DMC | dimethyl carbonate |
| DMF | dimethylformamide |
| DmgH | dimethylglyox |
| DPBS | Dulbecco’s phosphate buffered saline |
| DPEN | 1,2-diphenyl-1,2-ethylenediamine |
| DTBP | di-tert-butyl peroxide |
| DTMs | dithiomalonates |
| E factor | environmental factor |
| EAN | ethyl ammonium nitrate |
| ECH | electrocatalytic hydrogenation |
| EDA | electron donor–acceptor |
| EDA | ethylenediamine |
| EDC | 1-ethyl-3-(3-(dimethylamino)propyl) carbodiimide |
| EDTA | ethylenediaminetetraaceticacid |
| EHS | environment health safety |
| ERED | Ene-reductase |
| et al. | et alia |
| EnT | energy transfer |
| FAD | flavin adenine dinucleotide |
| FAP | fatty acid photodecarboxylase |
| FDCA | 2,5-furan dicarboxylic acid |
| FMO | frontier molecular orbital |
| G1 | Grubbs first-generation catalyst |
| G2 | Grubbs second-generation catalyst |
| GBB | Groebke–Blackburn–Bienayme |
| HAT | hydrogen atom transfer |
| HATU | hexafluorophosphate azabenzotriazole tetramethyl uronium |
| HBD | hydrogen bond donors |
| HE | Hantzsch ester |
| HER | hydrogen evolution reaction |
| HFIP | 1,1,1,3,3,3-hexafluoroisopropanol |
| HG | Hoveyda–Grubbs |
| HMPC | hydroxypropyl methylcellulose |
| i-GAL | innovation green aspiration level |
| I-MCRs | isocyanide-based multicomponent reaction |
| KREDs | ketoreductases |
| LUMO | lowest unoccupied molecular orbital |
| MCCA | medium-chain carboxylic acids |
| MCR | multicomponent reaction |
| MNPs | magnetic nanoparticles |
| MO | molecular orbital |
| MOF | metal-organic framework |
| Mpg-CN | mesoporous graphitic carbon nitride |
| MVK | methyl vinyl ketone |
| MVS | methyl vinyl sulfone |
| MWCNTs MNCs | multiwalled carbon nanotubes magnetic nanocomposites |
| MWI | microwave irradiation |
| NADPH | nicotinamide adenine dinucleotide phosphate hydrogen |
| NGO | N-doped graphene oxide |
| NHC | N-heterocyclic carbene |
| Ni-MPA | NiII-3-mercaptopropionic acid |
| NMP | N-methylpyrrolidone |
| NMR | nuclear magnetic resonance |
| NP | nanoparticle |
| OBBD | B-alkyl-9-oxa-10-borabicyclo[3.3.2]decane |
| oCB | oxidised carbon black |
| OEOMA | oligo(ethylene oxide) methyl ether methacrylate |
| OER | oxygen evolution reaction |
| OFRs | oscillatory plug flow reactor |
| o-QMs | ortho-quinone methides |
| ORR | oxygen reduction reaction |
| PAA | polyacrylic acid |
| PBAM-ran-PHPAM | poly(N-(benzyl acrylamide))-ran-poly(N-(2-hydroxypropyl)acrylamide) |
| PCET | proton-coupled-electron-transfer |
| PChlide | protochlorophyllide |
| pDApr | polydiacetylene-proline |
| PEG | polyethylene glycol |
| pH | potential of hydrogen |
| PHU | 1-(3,5-bis(trifluoromethyl)phenyl)-3-((R)-phenyl((S)-pyrrolidin-2-yl)methyl)urea |
| PIDA | poly(diiododiacetylene) |
| PIL | polymer ionic liquid |
| PILs | protic ionic liquids |
| PMI | process mass intensity |
| ppm | parts per million |
| PQS | polyethyleneglycol ubiquinol succinate |
| PTC | phase transfer catalysis |
| PTS | polyoxyethanyl-α-tocopheryl sebacate |
| RCM | ring-closing metathesis |
| RDS | rate determining step |
| ROMP | ring-opening metathesis polymerization |
| RT | room temperature |
| SCF | supercritical fluids |
| SDOSS | sodium dioctyl sulfosuccinate |
| SDS | sodium dodecyl sulfate |
| SERS | surface-enhanced Raman spectroscopy |
| SET | single electron... |
| Erscheint lt. Verlag | 30.10.2024 |
|---|---|
| Sprache | englisch |
| Themenwelt | Naturwissenschaften ► Chemie ► Organische Chemie |
| Schlagworte | asymmetric synthesis • carbene reaction • C-H Activation • electrocatalysis • Green chemistry • green solvents • Industrial Applications • in-water • micellar catalysis • multicomponent reactions • Nucleophilic addition • Nucleophilic substitution • Olefin Metathesis • on-water • organic synthesis, catalysis • Organocatalysis • Oxidation • Pericyclic Reactions • phase-transfer catalysis • radical reaction • reduction • Sustainable chemistry • Visible light photocatalysis • Water |
| ISBN-10 | 3-527-84682-4 / 3527846824 |
| ISBN-13 | 978-3-527-84682-5 / 9783527846825 |
| Haben Sie eine Frage zum Produkt? |
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