Analysis and Fate of Surfactants in the Aquatic Environment (eBook)
994 Seiten
Elsevier Science (Verlag)
978-0-08-054833-3 (ISBN)
The EU-funded PRISTINE project (Priority surfactants and their toxic metabolites in wastewater effluents: An integrated study, ENV4-CT97-0494) provides the basis for the content of this title. It provides policy makers and industry with detailed information on analysis and concentrations of surfactants and their degradation products in the environment.
In addition to a general introduction to surfactants, this book comprises a comprehensive variety of analytical techniques, including sample handling, for the analysis of surfactants in the aquatic environment. Readers will find all the necessary information for analyzing the different groups of surfactants, with special emphasis on transformation products. Quality assurance is also reported on in detail. Chapters on toxicity and risk assessment are also included and give a complete perspective on the surfactants problem in the aquatic environment.
?Presents the finding of EU-funded research into fate and behaviour of organic chemicals in the environment
?Comprises a comprehensive variety of analytical techniques, including sample handling, for the analysis of surfactants in the aquatic environment
?Provides relevant information to all groups working in the field of surfactants"
An understanding of the fate and behaviour of organic chemicals, such as surfactants, in the environment is a prerequisite for the sustainable development of human health and ecosystems. As surfactants are being produced in huge amounts, it is important to have a detailed knowledge about their lifetime in the environment, their biodegradability in wastewater treatment plants and in natural waters, and their ecotoxicity. Parameters relevant for the assessment of long-term behaviour, such as interactions with hormonal systems need to be understood to avoid unexpected adverse effects to future generations of people and the environment. However, the identification and quantification of commercial surfactants in the environment is made more complicated and cumbersome because they comprise of tens to hundreds of homologues, oligomers and isomers of anionic, nonionic, cationic and amphoteric compounds.The EU-funded PRISTINE project (Priority surfactants and their toxic metabolites in wastewater effluents: An integrated study; ENV4-CT97-0494) provides the basis for the content of this title. It provides policy makers and industry with detailed information on analysis and concentrations of surfactants and their degradation products in the environment.In addition to a general introduction to surfactants, this book comprises a comprehensive variety of analytical techniques, including sample handling, for the analysis of surfactants in the aquatic environment. Readers will find all the necessary information for analyzing the different groups of surfactants, with special emphasis on transformation products. Quality assurance is also reported on in detail. Chapters on toxicity and risk assessment are also included and give a complete perspective on the surfactants problem in the aquatic environment.*Presents the finding of EU-funded research into fate and behaviour of organic chemicals in the environment*Comprises a comprehensive variety of analytical techniques, including sample handling, for the analysis of surfactants in the aquatic environment*Provides relevant information to all groups working in the field of surfactants
Cover 1
Contents 12
Series Editor's Preface 22
Editor's Preface 24
Foreword 28
Chapter 1. Surfactants: properties, production and environmental aspects 30
1.1 Introduction: from soap to modern surfactants 30
1.2 General properties of surfactants 32
1.3 Production rates and use of relevant surfactants 39
1.4 Raw materials 48
1.5 Synthesis of surfactants 58
1.6 Analysis of surfactants and their degradation products 62
1.7 Fate of surfactants and environmental problems 65
1.8 Conclusion 73
References 74
Chapter 2. Separation and detection 80
2.1 GC and GC–MS determination of surfactants 80
2.2 Capillary electrophoresis in surfactant analysis 106
2.3 LC determination using conventional detectors 118
2.4 Atmospheric pressure ionisation mass spectrometry„I. General aspects 144
2.5 Atmospheric pressure ionisation mass spectrometry„II. Flow injection analysis„mass and tandem mass spectrometry in the analysis of surfactants„advantages and disadvantages 152
2.6 Atmospheric pressure ionisation mass spectrometry„III. Non-ionic surfactants: LC.MS and LC.MS.MS of alkylphenol ethoxylates and their degradation products 192
2.7 Atmospheric pressure ionisation mass spectrometry„IV. Non-ionic surfactants: LC.MS of alkyl polyglucosides and alkyl glucamides 220
2.8 Atmospheric pressure ionisation mass spectrometry„V. Non-ionic surfactants: Flow injection analysis„mass spectrometry and liquid chromatography„mass spectrometry of organosilicone surfactants 234
2.9 Atmospheric pressure ionisation mass spectrometry„VI. Non-ionic surfactants LC.MS of other non-ionic surfactants 256
2.10 Atmospheric pressure ionisation mass spectrometry„VII. Anionic surfactants: LC.MS of alkylbenzene sulfonates and related compounds 318
2.11 Atmospheric pressure ionisation mass spectrometry„VIII. Anionic surfactants: LC.MS of other anionic surfactants 334
2.12 Atmospheric pressure ionisation mass spectrometry„IX. LC.MS analyses of cationic surfactants. methods and applications 382
2.13 Atmospheric pressure ionisation mass spectrometry„X. LC„MS of amphoteric surfactants 414
Chapter 3. Sample handling 422
3.1 Sampling and sample treatment for surfactant analysis in water 422
3.2 Methods for the sample handling of non-ionic surfactants in sludges and sediments 444
3.3 Sample handling for the determination of surfactants in biota 458
Chapter 4. Quantification and quality assurance in surfactant analysis 472
4.1 Introduction 472
4.2 Reference compounds in quantification of surfactants, their metabolites and reaction by-products 476
4.3 Advantages and limitations in surfactant quantification by liquid chromatography-mass spectrometry 502
4.4 Stability of surfactants in post-sampling storage 524
4.5 Interlaboratory studies for the determination of surfactants 538
Chapter 5. Environmental processes 554
5.1 Aerobic biodegradation of surfactants 554
5.2 Anaerobic biodegradation of surfactants 606
5.3 Biodegradation of linear alkylbenzene sulfonates in the marine environment 620
5.4 Surfactant sorption on natural sediments 636
5.5 Fate of organosilicone surfactants 656
Chapter 6. Occurrence of surfactants in the environment 684
6.1 Concentrations of surfactants in wastewater treatment plants 684
6.2 Occurrence of surfactants in surface waters and freshwater sediments„I. Alkylphenol ethoxylates and their degradation products 704
6.3 Occurrence of surfactants in surface waters and freshwater sediments„II. Linear alkylbenzene sulfonates and their carboxylated degradation products 724
6.4 Non-ionic surfactants in marine and estuarine environments 748
6.5 Anionic surfactants in marine and estuarine environments 778
6.6 Surfactants in drinking water occurrence and treatment 792
6.7 Occurrence and fate of surfactants in soil, subsoil, and groundwater 816
Chapter 7. Toxicity of surfactants 856
7.1 Toxicity of surfactants for aquatic life 856
7.2 Bioconcentration 898
7.3 Estrogenicity of surfactants 916
7.4 Risk assessment of surfactants 942
Chapter 8. Recommendations and future trends 956
8.1 Monitoring 956
8.2 Analytical aspects 958
8.3 Legislative regulations force action 959
8.4 Final remarks and perspectives of a continuously changing market 963
Glossary 966
Index 972
Erscheint lt. Verlag | 22.8.2003 |
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Sprache | englisch |
Themenwelt | Naturwissenschaften ► Biologie ► Biochemie |
Naturwissenschaften ► Chemie ► Analytische Chemie | |
Naturwissenschaften ► Chemie ► Organische Chemie | |
Technik ► Umwelttechnik / Biotechnologie | |
ISBN-10 | 0-08-054833-4 / 0080548334 |
ISBN-13 | 978-0-08-054833-3 / 9780080548333 |
Informationen gemäß Produktsicherheitsverordnung (GPSR) | |
Haben Sie eine Frage zum Produkt? |

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