Primary Photoexcitations In Conjugated Polymers: Molecular Exciton Versus Semiconductor Band Model
World Scientific Publishing Co Pte Ltd (Verlag)
978-981-02-2880-4 (ISBN)
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This volume concentrates on the controversy within the scientific community over how to explain, understand and describe the photophysics/photochemistry of this class of materials.This controvery is of such a fundamental nature that the solution of the problem might be in a unification of the semiconductor and metal physics with the molecular quantum chemistry. Thus, a wide-ranging and comprehensive discussion of this very crucial issue has not been written down yet.This volume brings together the most prominent scientists specializing in this controversial topic. Each contributor addresses the opponents' arguments. After short introductory chapters, the contributors discuss their own speciality area and compare the results with both models and explain their position on why one of the models is more appropriate. Special emphasis is given to comparative discussions with other conjugated molecular systems as well as inorganic semiconductors.
Correlations in conjugated polymers, Z.G. Soos et al; nature of the primary photoexcitations in poly(arylene-vinylenes) - bound neutral excitons or charged polaron pairs, A.J. Heeger; excitons in conjugated polymers, H. Bassler; intramolecular excitons and intermolecular polaron pairs as primary photoexcitation in PPV and derivatives, E. Conwell; excitonic effects on the linear and nonlinear optical properties of conjugated polymers, S. Abe; bound-polaron pair formation in polyphenylene-vinylenes, L. Rothberg; luminescence efficiency and time-dependence - insights into the nature of emitting species in conjugated polymers, I.D.W. Samuel; mechanism of carrier generation in the class of low mobility materials - transient photoconductivity and photoluminescence at high electric fields, D. Moses; photoluminescence spectroscopy as a probe for disorder and coulomb interaction in organic and inorganic semiconductors, U. Lemmer and E.O. Gobel; spectroscopy on conjugated polymer devices, V. Dyakonov; spin dependent studies of photoexcitations in conjugated polymers, Z.V. Vardeny and P.A. Lane; electroabsorption spectroscopy on conjugated polymers, G. Weiser; the role of excitons in charge carrier generation in polysilanes, R.G. Kepler and Z.G. Soos; theory of excitons and biexcitons in pi-conjugated polymers, S. Mazumdar; ultrafast relaxation in conjugated polymers, T. Kobayashi; ultrafast photoinduced absorption in non-degenerate ground-state conjugated polymers, D. McBranch; are bipolarons photogenerated in PPV, E. Conwell; do bipolarons exist in doped conjugated polymers? an analysis based on the experimental studies of model oligomers, Y. Furukawa; photoexcitations in conjugated oligomers, R. Janssen; excited states in polyparaphenylene vinylene and related oligomers - theoretical investigation of their relation to electrical and optical properties, D. Beljonne et al; linear polyene electronic structure - what the oligomers tell us about the polymers, B.E. Kohler.
Erscheint lt. Verlag | 5.1.1998 |
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Verlagsort | Singapore |
Sprache | englisch |
Themenwelt | Naturwissenschaften ► Chemie ► Physikalische Chemie |
Naturwissenschaften ► Physik / Astronomie ► Festkörperphysik | |
Technik | |
ISBN-10 | 981-02-2880-5 / 9810228805 |
ISBN-13 | 978-981-02-2880-4 / 9789810228804 |
Zustand | Neuware |
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