New Fluorinated Carbons: Fundamentals and Applications

Olga Boltalina, PhDSenior Research Associate and Co-Principal Investigator, Department of Chemistry, Colorado State UniversityDr. Boltalina received her M.S. (1982) and Ph.D. (1990) degrees in Physical Chemistry from Moscow State University (MSU), Russia, working with Lev Sidorov. She earned her D.Sci. degree (i.e. Doctor Nauk [aka Habilitation]) from MSU in 1998. She retired as Professor of Physical Chemistry from MSU in 2005 after having supervised 11 Ph.D. and 10 M.S. students. She is now a Senior Research Scientist at Colorado State University where she works with Dr. Steven Strauss; shares contracts, grants, and laboratories; and co-advises their joint graduate and undergraduate research students. Dr. Boltalina is an author of ca. 250 publications, several book chapters, and several patents and patent applications. She has received the MSU Lomonosov Prize, an Alexander von Humboldt (AvH) Freidrich Bessel Award, two additional AvH Research Fellowships, a Japan Society for the Promotion of Science Fellowship, and a Royal Society of Chemistry Research Award. Her current research interests include the rational design of fluorinated and perfluoroalkylated fullerenes and related carbon materials for specific optoelectronic, energy conversion, energy storage, and biomedical applications. Tsuyoshi Nakajima is Professor in the Department of Applied Chemistry, Aichi Institute of Technology in Japan. He has worked on fluorine chemistry and electrochemistry (that is, fluorinated materials) for primary and rechargeable lithium batteries, and fluorine-, fluoride-, or oxyfluoride-graphite intercalation compounds. Li/(CF)n battery is the first primary lithium battery commercialized on the basis of the research on graphite fluoride which was performed in his laboratory at Kyoto University. His research was on the discharge mechanism of Li/(CF)n battery and synthesis of graphite fluoride, (CF)n with excellent discharge performance. The importance of carbon-fluorine compounds as battery materials was first recognized by graphite fluoride cathode of Li/(CF)n battery. Furthermore, new graphite anode for electrolytic production of fluorine gas was developed on the basis of his work on fluorine-graphite intercalation compound with high electrical conductivity. Recently. his research interest is on the application of fluorine chemistry to rechargeable lithium batteries. Fluorination techniques were applied to surface modification of graphite anode which increases the capacities of graphite anode and enables the low temperature operation of lithium ion battery. For the application of lithium ion battery using flammable organic solvents to electric sources of hybrid and electric vehicles, high safety is the most important issue. He has found that organo-fluorine compounds are excellent new solvents with high oxidation stability (that is, high safety for rechargeable lithium batteries). He published about 230 papers and 24 books. In academic societies, he served as chairman of JSPS 155th Committee on Fluorine Chemistry; The Society of Fluorine Chemistry, Japan; Executive Committee of Carbon Society of Japan; and Regional Editor and Editorial Board of J. Fluorine Chemistry. Alain Tressaud is Emeritus Research Director at ICMCB-CNRS, Bordeaux University. He is President of the European Academy of Science in Brussels and member of several European academies. He founded and chaired the French Network on Fluorine Chemistry, sponsored by CNRS, until 2008. He has received several awards, including the CEA Award of French Academy of Sciences (2008), the Fluorine Award of the American Chemical Society (2011), and the International Henri Moissan Prize (2013). His scientific interest covers various fields, including synthesis, physical chemical characterizations, applications in fluorine chemistry, solid state chemistry, and materials sciences. His work also deals with surface modification of materials and intercalation chemistry. Professor Tressaud’s scientific production includes more than 360 papers in international journals, 20 book chapter contributions, and 12 internationalized patents. He has also edited several books in his role as editor-in-chief of the series “Advances in Fluorine Science” (2006) and “Progress in Fluorine Science” (2016) with Elsevier.

1. Electronic Properties and Applications of Fluorofullerenes

2. Synthesis and Isolation of Trifluoromethylfullerenes

3. Thirteen Decakis(trifluoromethyl)decahydro(C60-Ih)[5,6]fullerenes (C60(CF3)10): Structures and Structure-Related Properties of the Largest Set of Fullerene(X)n Isomers

4. Trifluoromethylated Corannulene Derivatives: Thermodynamic Stability and Electron-Accepting Properties

5. Fluorination–Defluorination and Fluorine Storage Properties of Single-Wall Carbon Nanotubes and Carbon Nanohorns

6. Synthesis and Characterization of Fluorinated Carbon Fibers and Nanotubes

7. Perfluoroalkylated PAH n-Type Semiconductors: Theory and Experiment

8. Electronic Structure of Fluorinated Graphene

9. Nature of C–F Bonds in Fluorinated Carbons

10. Preparation and Application of Fluorine–Carbon and Fluorine–Oxygen–Carbon Materials

11. Intercalation Chemistry and Application of B/C/N Materials to Secondary Batteries

12. Structures of Highly Fluorinated Compounds of Layered Carbon

13. Lithium–Graphite Fluoride Battery—History and Fundamentals

14. Fluorinated Nanocarbons for Lubrication

15. Perfluoropolyether-Functionalized Carbon-Based Materials and Their Applications

16. Nanoelectronics Based on Fluorinated Graphene