Nanocatalysis (eBook)

Synthesis and Applications
eBook Download: PDF
2013 | 1. Auflage
736 Seiten
Wiley (Verlag)
978-1-118-61093-0 (ISBN)

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Exhibiting both homogeneous and heterogeneous catalytic properties, nanocatalysts allow for rapid and selective chemical transformations, with the benefits of excellent product yield and ease of catalyst separation and recovery. This book reviews the catalytic performance and the synthesis and characterization of nanocatalysts, examining the current state of the art and pointing the way towards new avenues of research. Moreover, the authors discuss new and emerging applications of nanocatalysts and nanocatalysis, from pharmaceuticals to fine chemicals to renewable energy to biotransformations. Nanocatalysis features contributions from leading research groups around the world. These contributions reflect a thorough review of the current literature as well as the authors first-hand experience designing and synthesizing nanocatalysts and developing new applications for them. The book s nineteen chapters offer a broad perspective, covering: Nanocatalysis for carbon-carbon and carbon-heteroatom coupling reactions Nanocatalysis for various organic transformations in fine chemical synthesis Nanocatalysis for oxidation, hydrogenation, and other related reactions Nanomaterial-based photocatalysis and biocatalysis Nanocatalysts to produce non-conventional energy such as hydrogen and biofuels Nanocatalysts and nano-biocatalysts in the chemical industry Readers will also learn about the latest spectroscopic and microscopy tools used in advanced characterization methods that shed new light on nanocatalysts and nanocatalysis. Moreover, the authors offer expert advice to help readers develop strategies to improve catalytic performance. Summarizing and reviewing all the most important advances in nanocatalysis over the last two decades, this book explains the many advantages of nanocatalysts over conventional homogeneous and heterogeneous catalysts, providing the information and guidance needed for designing green, sustainable catalytic processes.

VIVEK POLSHETTIWAR, PhD, is Reader heading the Nanocatalysis Laboratory in the Department of Chemical Sciences at the Tata Institute of Fundamental Research. His research examines advanced nanomaterials, catalysis, and green chemistry. TEWODROS ASEFA, PhD, is Associate Professor in the Department of Chemistry and Chemical Biology and the Department of Chemical and Biochemical Engineering at Rutgers University. Dr. Asefa is also Interim Director of the Rutgers Catalysis Research Center.

Foreword vii

Graham Hutchings

Preface ix

List of Contributors xiii

1 INTRODUCTION TO NANOCATALYSIS 1

Vivek Polshettiwar and Tewodros Asefa

2 NANOCATALYSTS FOR THE HECK COUPLING REACTIONS 11

T. Asefa, A. V. Biradar, S. Das, K. K. Sharma, and R.
Silva

3 NANOCATALYSTS FOR THE SUZUKI COUPLING REACTIONS 51

Liane M. Rossi, Natalia J. S. Costa, Jones Limberger, and
Adriano L. Monteiro

4 SONOGASHIRA REACTIONS USING NANOCATALYSTS 89

Rafael Chinchilla and Carmen N´ajera

5 NANOCATALYSTS FOR HIYAMA, STILLE, KUMADA, AND NEGISHI
C-C COUPLING REACTIONS 133

Abhinandan Banerjee and Robert W. J. Scott

6 ARYL CARBON-HETEROATOM COUPLING REACTIONS USING
NANOMETAL CATALYST 189

Brindaban C. Ranu, Debasree Saha, Debasish Kundu, and Nirmalya
Mukherjee

7 NANOSTRUCTURED CATALYSTS FOR THE ALDOL, KNOEVENAGEL, AND HENRY
REACTIONS 221

T. Asefa, A. V. Biradar, S. Das, and R. Silva

8 NANOCATALYSTS FOR REARRANGEMENT REACTIONS 251

Joaqu´yn Garc´ya-A´lvarez, Sergio E.
Garc´ya-Garrido, and Victorio Cadierno

9 OXIDATION OF ALCOHOLS USING NANOCATALYSTS 287

Takato Mitsudome and Kiyotomi Kaneda

10 TUNING THE MORPHOLOGY OF METAL OXIDES FOR CATALYTIC
APPLICATIONS 333

Yong Li and Wenjie Shen

11 NANOCATALYSTS FOR HYDROGENATION REACTIONS 405

Radha Narayanan

12 HYDROGENOLYSIS REACTIONS USING NANOCATALYSTS 443

Aziz Fihri and Vivek Polshettiwar

13 NANOMATERIAL-BASED PHOTOCATALYSTS 469

Biswajit Mishra and Deepa Khushalani

14 NANOCATALYSTS FOR WATER SPLITTING 495

Xu Zong, Gaoqing Lu, and Lianzhou Wang

15 PROPERTIES OF NANOCATALYTIC MATERIALS FOR HYDROGEN PRODUCTION
FROM RENEWABLE RESOURCES 561

Zhong He and Xianqin Wang

16 NANOCATALYSTS FOR BIOFUELS 595

Vitaliy Budarin, Peter S. Shuttleworth, Brigid Lanigan, and
James H. Clark

17 NANOMATERIAL-BASED BIOCATALYST 615

Jin Hyung Lee, Soo Youn Lee, Zhi-Kang Xu, and Jeong Ho
Chang

18 ROLE OF NANOCATALYSIS IN CHEMICAL INDUSTRY 643

Anirban Ghosh, K. S. Nagabhushana, Debabrata Rautaray, and Rajiv
Kumar

19 NANOCATALYSIS: ACTIVATION OF SMALL MOLECULES AND CONVERSION
INTO USEFUL FEEDSTOCK 679

Suresh Babu Kalidindi and Balaji R. Jagirdar

Index 713

Erscheint lt. Verlag 9.9.2013
Vorwort Graham Hutchings
Sprache englisch
Themenwelt Naturwissenschaften Chemie Physikalische Chemie
Naturwissenschaften Chemie Technische Chemie
Technik Maschinenbau
Schlagworte catalysis • chemical engineering • Chemie • Chemische Verfahrenstechnik • Chemistry • Katalyse • Nanomaterialien • nanomaterials • Nanotechnologie • nanotechnology
ISBN-10 1-118-61093-8 / 1118610938
ISBN-13 978-1-118-61093-0 / 9781118610930
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