Inorganic Syntheses, Volume 32 (eBook)

Dr. Marcetta York Darensbourg is an American inorganic chemist. She is a Distinguished Professor of Chemistry at Texas A&M University. Her current work focuses on iron hydrogenases and iron nitrosyl complexes.

Chapter One LIGANDS FOR WATER-SOLUBILIZING ORGANOMETALLIC COMPOUNDS.

1. (Meta-Sulfonatophenyl)Diphenylphosphine, Sodium Salt and Its Complexes with Rhodium(I), Ruthenium(II), Iridium(1).

2. Syntheses of Water-Soluble Phosphines and Their Transition Metal Complexes.

3. Tris[Tris(Sodium m-sulfonatophenyl)phosphino] Palladium(0)-Enneahydrate.

4. Sulfonated Phosphines.

5. (S,S)-2,3-Bis[Di(m-Sodiumsulfonatophenyl)phosphino]butane-(chiraphosTS) and (S,S)-2,4-Bis[di(m-Sodiumsulfonatophenyl)-phosphinolpentane (BDPPTS).

6. 1,3,5-Triaza-7-phosphatricyclo[3.3.1.1¯3,7]decane and Derivatives.

Chapter Two BIOMIMETIC AND SPECIAL PROPERTY LIGANDS.

7. 2.2':6',2"-Terpyridine.

8. Poly(1-pyrazolyl)alkane Ligands.

9 . Tris[N-(3-tert-butyl)pyrazolyl]methane.

10. Tris[2-(1,4-Diisopropylimidazolyl)]phosphine.

11. Tris[(2-pyridyl)methyl]amine (TPA) and (+)-Bis[(2-pyridyl)-methyl]-l-(2-pyridyl)ethylamine (a-MeTPA).

12. C2-Symmetric 1,4-Diisopropyl-7-R-l,4,7-Triazacyclononanes.

13. N-(2-hydroxyethyl)-3,5-Dimethylpyrazole, a Dinuclear Copper Complex, and N-(2-p-Toluenesulfonylethyl)-3,5-dimethy-pyrazole.

14. N-(2-Mercaptoethyl)-3,5-dimethylpyrazole.

15. 1,5-Diazacyclooctane, Pendant Arm Thiolato Derivatives and [N,N'-Bis(2-Mercaptoethyl)-1,5-Diazacyclooctanato]-nickel(II).

16. Polydentate Thiolate and Selenolate Ligands, RN(CH2,CH2,S(Se)¯-)2, and Their Dimeric and Mononuclear Ni(II) Complexes.

17. Poly[(methylthio)methyl]borates and Representative Metal Derivative.

18. Polyaza Binucleating Ligands: OBISTREN and OBISDIEN.

19. N,N'.bis(2-hydroxybyl.thylenediamine-N,N'-diacetic acid (HBED).

20. N-Tert-Alkyl-Anilides as Bulky Ancillary Ligands.

21. 1,2-Bis(Dichlorophosphino)-1,2-Dimethylhydrazine and Alkoxy/Aryloxy Derivatives.

22. Tris[(tert-butylamino)-dimethylsilyl]methylsilane and Its Precursors.

Chapter Three TRANSITION METAL COMPLEXES AND PRECURSORS.

23. Facile Synthesis of Isomerically Pure.

24. cis-Bis(benzeneacetonitrile)dichloroplatinum(II) and trans-Bis(benzeneacetonitrile)dichloroplatinum(II).

25. Platinum(II) Complexes of Dimethyl Sulfide.

26. (2,2' :6',2"-Terpyridine) Methylplatinurn(II) Chloride and (l,l0-Phenanthroline)methylchloroplatinum(II).

27. (N,N-Chelate)(olefin)platinum(0) Complexes.

28. Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes.

29. 2,4-Pentanedionatogold(I) Complexes and 2,4-Pentanedionatothallium.

30. Tetrakis(Pyridine)SiIver(2 + )Peroxydisulfate.

31. One-Pot Synthesis of Tetrahydronium Tris(4,4'-Dicarboxylato-2,2'-Bipyridine)ruthenium(II) Dihydrate.

32. Trichloro[2,2' :6,2"-Terpyridine]ruthenium(III) and Phosphine Ligand Derivatives.

33. Monomeric Tetrahydrofuran-Stabilized Molybdenum(III) Halides.

34. Facial Molybdenum(lI1) Triamine Complexes.

35. High-Valent Mono-(5-Pentamethylcyclopentadienyl)vanadium and Molybdenum Complexes.

36. Monoindenyltrichloride Complexes of Titanium(IV), Zirconium(IV), and Hafnium(IV).

37. Labile Copper(I) Chloride Complexes: Preparation and Handling.

Chapter Four MAIN GROUP AND TRANSITION METAL CLUSTER COMPOUNDS.

38. 7,8-Dicarbaundecaborane(13).

39. Borazine, Polyborazylene, B-Vinylborazine and Poly(B-Vinylborazine).

40. Transition Metal Complexes of the Lacunary Heteropolytungstate, [P2W17O61] ¯10-.

Chapter Six TITANIUM(1II) CHLORIDE.

(A Correction to Inorganic Syntheses, Vol. 24, pp. 181 (1986).

50. An Active Form of Titanium(II1) Chloride.

Contributor Index.

Subject Index.

Formula Index.

Chemical Abstracts Service Registry Number Index.