Inorganic Syntheses, Volume 15 (eBook)

George W. Parshall is an organometallic chemist who made notable contributions to homogeneous catalysis. He was a senior scientist at E. I. du Pont de Nemours and Company for many years.

Preface.

Notice to Contributors.

Chapter One Metal Complexes of Olefins.

1 Bis(1.3.5 7-cyclooctatetraene)iron(0).

2 Bis(1,4-cyclooctadiene)nickel(0).

3 Ethylenebis(tri-o-tolyl phosphite)nickel(0) andTris(tri-o-tolyl phosphite)nickel(0).

4 Di-µ-chlorotetrakis(ethylene)dirhodium(I),2,4-Pentanedionatobis(ethylene)rhodium(I), andDi-µ-chlorotetracarbonyldirhodium(I).

5 Cyclooctene and 1,5-Cyclooctadiene Complexes ofIridium(I).

Chapter Two Metal Complexes of Dinitrogen and ofHydrogen.

6trans(Dinitrogen)bis[ethylenebis(diethylphosphine)]hydridoiron(II).

7trans-Bis(dinitrogen)bis[ethylenebis(diphenylphosphine)]molybdenum(0).

8(µ-Dinitrogen-N,N')bis[bis(tricyclohexylphosphine)nickel(0)].

9 Dinitrogen and Hydrogen Complexes of Ruthenium.

10 Pentahydridobis(trimethylphosphine)iridium(V).

11 Hydride Complexes of Iron(II) and Ruthenium(II).

12Tetrahydridotetrakis(methyldiphenylphosphine)molybdenum(IV).

Chapter Three Triphenylphosphine Complexes of TransitionMetals.

13 Complexes of Ruthenium, Osmium, Rhodium, and IridiumContaining Hydride, Carbonyl, or Nitrosyl Ligands.

14 Fluoro Complexes of Rhodium(I) and Iridium(I).

15 Covalent Perchlorato Complexes of Iridium and Rhodium.

16trans-Carbonyl(cyanotrihydridoborato)bis(triphenylphosphine)rhodium(I).

Chapter Four Other Transition-Metal Compounds.

17 p-Allyl Complexes of Palladium and Platinum.

18 Dicarbonylchloro(p-toluidine)iridium(I).

19µ-Nitrido-bis(triphenylphosphorus)(1+)("PPN")Salts with Metal.

20Dicarbonyl-h¯5-cyclopentadienylnitrosylmanganese(1+)Hexafluorophosphate (1-).

21 Hexammineplatinum(IV) Chloride.

22Bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)nickel(II)and-cobalt(II).

23 Ammonium Pentahalooxomolybdates(2-).

24 13-Vanadomanganate(IV) and Nickelate(IV).

Chapter Five Boron Compounds.

25Octahydrotriborate(1-)([B3H8]¯-)Salts.

26 Pentaborane(9)([B5H9]).

27 Dimethylamine-Borane.

28 Dimethylamine-Tribromoborane.

29 Methyldiphenylphosphine-Borane andDimethylphenylphosphine-Borane.

30 Triphenylborane.

31 Sodium Triethylhydroborate, Sodium Tetraethylborate, andSodium Triethyl-1-propynylborate.

32 Tetraalkyldiboranes and 9-Borabicyclo[3.3.1]nonane Dimer.

33 Chlorodiethylborane and Chlorodiphenylborane.

Chapter Six Germanium Hydride Derivatives.

34 Bromogermane and Dibromogermane.

35 Chlorogermane and Iodogermane.

36 Fluorogermane and Digermylcarbodiimide.

37 Iododigermane and Methyldigermane.

38 Pentacarbonylgermylmanganese.

39 Germylphosphine.

40 Digermyl Sulfide(Digermthiane).

Chapter Seven Phosphorous Compounds.

41Ethylenebis(dimethylphosphine)[1,2-bis(Dimethylphosphino)ethane],Tetramethyldiphosphane Disulfide, and Tetramethyldisphosphane.

42 Dimethylphosphinothioic Chloride and DimethylphosphinousChloride.

43 Phosphoric Trihalides.

44 µ-Nitrido-bis[amidodiphenylphosphorus](1+)Chloride.

Chapter Eight Main Group and Actinide Compounds.

45 Trimethylgallium.

46 Hexamethyldisilthiane and Hexamethylcyclotrisilthiane.

47 Polyatomic Cations of Sulfur, Selenium, and Tellurium.

48 Tetraethylammonium Trichlorogermanate(1-) andTetrachlorostannate(1-).

49 Weak and Unstable Anionic Bromo and Iodo Complexes.

50 Hexahalouranate Salts.

51 Pentachloro(trichloroacrylyl chloride)uranium(V).

Index of Contributors.

Subject Index.

Formula Index.