Inorganic Syntheses, Volume 13 (eBook)

F. ALBERT COTTON, PhD, is a professor in the Department of Chemistry at Texas A&M University.

Preface.

Notice to Contributors.

Chapter One Compounds of the Nontransition Elements.

1 Perbromic Acid and Potassium Prebromate.

2 alpha-Sulfanuric Chloride--Cyclic Trimer.

3 Arsine and Arsine-d3.

4 Ammonium Cyanate.

5 Phosphorus(III) Isocyanate.

6 Phosphoramidic Acid and Its Salts.

7 Diphenyl(trimethylsilyl)phosphine and
Dimethyl(trimethylsilyl)phosphine.

8 Exchange Reactions for the Syntheses of Phenylboron Chlorides
and Tetrafluoromethylphosphorane.

9 2,4,6-Trichloroborazine.

10 2,4,6-Trichloro-1,3,5-trimethylborazine.

Chapter Two Organometallic Compounds.

11 Cyclic-diolefin Complexes of Platinum and Palladium.

12 Cationic Diene Complexes of Palladium(II) and
Platinum(II).

13 Trichloro-, Trimethyl-, and Trifluorosilylcobalt
Tetracarbonyl.

14 Isoleptic Allyl Derivatives of Various Metals.

Chapter Three Compounds Containing Metal-to-Metal
Bonds.

15 Rhenium and Molybdenum Compounds Containing Quadruple
Bonds.

16 Tetrakis(acetato)dirhodium(II) and Similar Carboxylato
Compounds.

17 Dodecacarbonyltriruthenium and -triosmium.

18 Dodecacarbonyltetrairidium.

19 Disodium
Hexaalkoxy-octa-mu3-chloro-hexamolybdates.

Chapter Four Phosphine and Phosphite Complexes of Low-Valent
Metals.

20 Triaryl Phosphite Complexes of Cobalt, Nickel, Platinum, and
Rhodium.

21 Tetrakis(triethyl phosphite)nickel(0), Palladium (0), and
Platinum(0) Complexes.

22 Low-valent Metal Complexes of Diethyl Phenylphosphonite.

23 Tetrakis(triphenylphosphine)palladium(0).

24 Tetrakis(triphenylphosphine)nickel(0).

25 Carbonylhydridotris(triphenylphosphine)iridium(I).

26 Chlorohydridotris(triphenylphosphine)ruthenium(II).

Chapter Five Binary Compounds of the Transistion
Metals.

27 Single Crystals of Transition-metal Dioxides.

28 Molybdenum(V) Fluoride.

29 Tungsten(V) Chloride.

30 Anhydrous Nickel(II) Halides and Their Tetrakis(ethanol) and
1,2-dimethoxyethane Complexes.

Chapter Six Halo Complexes of Some Metals.

31 Tetraphenylarsonium Tetrachlorovanadate(III).

32 Tris(tetraethylammonium) Nonachlorodivanadate(III).

33 Ammonium, Rubidium, and Cesium Salts of the
Aquapentachloromolybdate(III) and Hexachloromolybdate(III)
Anions.

34 Disodium Hexachloropatinate(IV).

Chapter Seven Various Transition-Metal Compounds.

35 Dichlorotetrakis(2-propanol)vanadium(III) Chloride.

36 Trichorobis(trimethylamine)vanadium(III).

37 Vanadyl(IV) Acetate,
VO(CH3CO2)2.

38 Tris(diamine)chromium(III) Salts.

39 Bis[cis-1,2-dicyanoethene-1,2-dithialato(1 or
2-)] Complexes of Cobalt and Iron.

40 Resolution of the (Ethylenediamine)bis(oxalato)cobaltate(III)
Ion.

41 Nitrito Complexes of Nickel(II) and Cobalt(II).

42 Ruthenium Ammines.

43 Pentaamminechlororhodium(III) Dichloride and
Pentaamminehydridorhodium(III) Sulfate.

44 Dichloro(ethylenediamine)palladium(II) and
(2,2'-Bipyridine)dichloropalladium(II).

45 Nonahydridorhenate Salts.

46 Potassium Hexakis(isothiocyanato)niobate(V).

Corrections.

Index of Contributors.

Subject Index.

Formula Index.