Physical Chemistry (eBook)

Paul M. S. Monk received his PhD in the electrochemistry of novel electrochromic viologen species at Exeter University in 1989. A postdoctoral research fellow position - 1989-91 - at the University of Aberdeen, in Scotland, was followed by lecturing positions in Physical Chemistry at Manchester Polytechnic - 1991-2 - then Manchester Metropolitan University - 1992-2007 -. He is currently employed as a Vicar in an inner-city parish in Oldham, Greater Manchester, UK.

Preface.

Etymological Introduction.

List of Symbols.

Powers of Ten: Standard Prefixes.

1. Introduction to physical chemistry .

1.1 What is physical chemistry? Variables, relationships and
laws.

1.2 The practice of thermodynamic measurement.

1.3 Properties of gases and the gas laws.

1.4 Further thoughts on energy.

2. Introducing interactions and bonds.

2.1 Physical and molecular interactions.

2.2 Quantifying the interactions and their influence.

2.3 Creating formal chemical bonds.

3. Energy and the first law of thermodynamics.

3.1 Introduction to thermodynamics: internal energy.

3.2 Enthalpy.

3.3 Indirect measurement of enthalpy.

4. Reaction spontaneity and the direction of thermodynamic
change.

4.1 The direction of physicochemical change: entropy.

4.2 The temperature dependence of entropy.

4.3 Introducing the Gibbs function.

4.4 The effect of pressure on thermodynamic variables.

4.5 Thermodynamics and the extent of reaction.

4.6 The effect of temperature on thermodynamic variables.

5. Phase equilibria.

5.1 Ene rgetic introduction to phase equilibria.

5.2 Pressure and temperature changes with a single-component
system: qualitative discussion.

5.3 Quantitative effects of pressure and temperature change for
a single-component system.

5.4 Phase equilibria involving two-component systems:
partition.

5.5 Phase equilibria and colligative properties.

5.6 Phase equilibria involving vapour pressure.

6. Acids and bases.

6.1 Properties of Lowry-Brønsted acids and bases.

6.2 'Strong' and 'weak' acids and
bases.

6.3 Titration analyses.

6.4 pH buffers.

6.5 Acid-base indicators.

7. Electrochemistry.

7.1 Introduction to cells: terminology and background.

7.2 Introducing half cells and electrode potentials.

7.3 Activity.

7.4 Half cells and the Nernst equation.

7.5 Concentration cells.

7.6 Transport phenomena.

7.7 Batteries.

8. Chemical kinetics.

8.1 Kinetics definitions.

8.2 Qualitative discussion of concentration changes.

8.3 Quantitative concentration changes: integrated rate
equations.

8.4 Kinetic treatment of complicated reactions.

8.5 Thermodynamic considerations: activation energy, absolute
reaction rates and catalysis.

9. Physical chemistry involving light: spectroscopy and
photochemistry.

9.1 Introduction to photochemistry.

9.2 Photon absorptions and the effect of wavelength.

9.3 Photochemical and spectroscopic selection rules.

9.4 Photophysics: emission and loss processes.

9.5 Other optical effects.

10. Adsorption and surfaces, colloids and micelles.

10.1 Adsorption and definitions.

10.2 Colloids and interfacial science.

10.3 Colloid stability.

10.4 Association colloids: micelles.

Answers to SAQs.

Bibliography.

"...a physical chemistry textbook that is interesting, easy to
read, and makes the subject comprehensible is overdue...[this
book] achieves this goal and does so quire well." (Journal of
Chemical Education, May 2006)

"...Monk has a deep understanding of many of the thorny
issues in physical chemistry and is able to avoid the unnecessary
mystery that plagues other texts." (Clinical Chemistry, June
2005)

"...an original, refreshing and valuable approach to a
complicated subject." (Chemistry and Industry, No.17,
6th September 2004)