Microporous and Mesoporous Solid Catalysts, Volume 4 (eBook)

éric Gérard Joseph Derouane was a French-speaking Belgian catalyst scientist. In 1968 he obtained his MSc in Chemistry at Princeton University and his PhD at the University of Liège. He then became a Research Associate of FNRS. Stanley M. Roberts is the editor of Microporous and Mesoporous Solid Catalysts, Volume 4, published by Wiley.

Series Preface.

Preface to Volume 4.

Abbreviations.

1 An Overview of Zeolite, Zeotype and Mesoporous Solids
Chemistry: Design, Synthesis and Catalytic Properties
(Thomas Maschmeyer and Leon van de Water).

1.1 Zeolites, zeotypes and mesoporous solids: synthetic
aspects.

1.2 Design of extra-large pore zeolites and other micro- and
mesoporous catalysts.

1.3 Potential of post-synthesis functionalized micro- and
mesoporous solids as catalysts for fine chemical synthesis.

2 Problems and Pitfalls in the Applications of Zeolites and
other Microporous and Mesoporous Solids to Catalytic Fine Chemical
Synthesis (Michel Guisnet and Matteo Guidotti).

2.1 Introduction.

2.2 Zeolite catalysed organic reactions.

2.3 General conclusions.

References.

3 Aromatic Acetylation (Michel Guisnet and Matteo
Guidotti).

3.1 Aromatic acetylation.

3.2 Procedures and protocols.

References.

4 Aromatic Benzoylation (Patrick Geneste and Annie
Finiels).

4.1 Aromatic benzoylation.

4.2 Acylation of anisole over mesoporous aluminosilicates.

References.

5 Nitration of Aromatic Compounds (Avelino Corma and Sara
Iborra).

5.1 Introduction.

5.2 Reaction mechanism.

5.3 Nitration of aromatic compounds using zeolites as
catalysts.

5.4 Conclusions.

References.

6 Oligomerization of Alkenes (Avelino Corma and Sara
Iborra).

6.1 Introduction.

6.2 Reaction mechanisms.

6.3 Acid zeolites as catalysts for oligomerization of
alkenes.

6.4 Mesoporous aluminosilicates as oligomerization
catalysts.

6.5 Nickel supported aluminosilicates as catalysts.

References.

7 Microporous and Mesoporous Catalysts for the Transformation
of Carbohydrates (Claude Moreau).

7.1 Introduction.

7.2 Hydrolysis of sucrose in the presence of H-form
zeolites.

7.3 Hydrolysis of fructose and glucose precursors.

7.4 Isomerization of glucose into fructose.

7.5 Dehydration of fructose and fructose-precursors.

7.6 Dehydration of xylose.

7.7 Synthesis of alkyl-D-glucosides.

7.8 Synthesis of alkyl-D-fructosides.

7.9 Hydrogenation of glucose.

7.10 Oxidation of glucose.

7.11 Conclusions.

References.

8 One-pot Reactions on Bifunctional Catalysts (Michel
Guisnet and Matteo Guidotti).

8.1 Introduction.

8.2 Examples.

References.

9 Base-type Catalysis (Didier Tichit, Sara Iborra,
Avelino Corma and Daniel Brunel).

9.1 Introduction.

9.2 Characterization of solid bases.

9.3 Solid base catalysts.

9.4 Conclusions.

References.

10 Hybrid Oxidation Catalysts from Immobilized Complexes on
Inorganic Microporous Supports (Dirk De Vos, Ive Hermans,
Bert Sels and Pierre Jacobs).

10.1 Introduction and scope.

10.2 Oxygenation potential of heme-type complexes in
zeolite.

10.3 Oxygenation potential of zeolite encapsulated nonheme
complexes.

10.4 Conclusions.

Acknowledgements.

References.

Subject Index.