Molecular Orbitals and Organic Chemical Reactions (eBook)

(Autor)

eBook Download: EPUB
2011 | 1. Auflage
526 Seiten
Wiley (Verlag)
978-1-119-96467-4 (ISBN)

Lese- und Medienproben

Molecular Orbitals and Organic Chemical Reactions -  Ian Fleming
Systemvoraussetzungen
135,99 inkl. MwSt
  • Download sofort lieferbar
  • Zahlungsarten anzeigen
Winner of the PROSE Award for Chemistry & Physics 2010 Acknowledging the very best in professional and scholarly publishing, the annual PROSE Awards recognise publishers' and authors' commitment to pioneering works of research and for contributing to the conception, production, and design of landmark works in their fields. Judged by peer publishers, librarians, and medical professionals, Wiley are pleased to congratulate Professor Ian Fleming, winner of the PROSE Award in Chemistry and Physics for Molecular Orbitals and Organic Chemical Reactions. Molecular orbital theory is used by chemists to describe the arrangement of electrons in chemical structures. It is also a theory capable of giving some insight into the forces involved in the making and breaking of chemical bonds the chemical reactions that are often the focus of an organic chemist's interest. Organic chemists with a serious interest in understanding and explaining their work usually express their ideas in molecular orbital terms, so much so that it is now an essential component of every organic chemist's skills to have some acquaintance with molecular orbital theory. Molecular Orbitals and Organic Chemical Reactions is both a simplified account of molecular orbital theory and a review of its applications in organic chemistry; it provides a basic introduction to the subject and a wealth of illustrative examples. In this book molecular orbital theory is presented in a much simplified, and entirely non-mathematical language, accessible to every organic chemist, whether student or research worker, whether mathematically competent or not. Topics covered include: Molecular Orbital Theory Molecular Orbitals and the Structures of Organic Molecules Chemical Reactions How Far and How Fast Ionic Reactions Reactivity Ionic Reactions Stereochemistry Pericyclic Reactions Radical Reactions Photochemical Reactions This expanded Reference Edition of Molecular Orbitals and Organic Chemical Reactions takes the content and the same non-mathematical approach of the Student Edition, and adds extensive extra subject coverage, detail and over 1500 references. The additional material adds a deeper understanding of the models used, and includes a broader range of applications and case studies. Providing a complete in-depth reference for a more advanced audience, this edition will find a place on the bookshelves of researchers and advanced students of organic, physical organic and computational chemistry. The student edition of Molecular Orbitals and Organic Chemical Reactions presents molecular orbital theory in a simplified form, and offers an invaluable first textbook on this important subject for students of organic, physical organic and computational chemistry. Further information can be viewed here. "e;These books are the result of years of work, which began as an attempt to write a second edition of my 1976 book Frontier Orbitals and Organic Chemical Reactions. I wanted to give a rather more thorough introduction to molecular orbitals, while maintaining my focus on the organic chemist who did not want a mathematical account, but still wanted to understand organic chemistry at a physical level. I'm delighted to win this prize, and hope a new generation of chemists will benefit from these books."e; Professor Ian Fleming

Professor Ian Fleming, Department of Chemistry, University of Cambridge Ian Fleming is an Emeritus Professor in the Department of Chemistry in the University of Cambridge, and an Emeritus Fellow of Pembroke College. He is the author of five textbooks: Spectroscopic Methods in Organic Chemistry (McGraw Hill, now in its 6th edition), Spectroscopic Problems in Organic Chemistry (McGraw Hill); Selected Organic Syntheses (Wiley), Frontier Orbitals and Organic Chemical Reactions (Wiley) and Pericyclic Reactions (OUP Oxford Chemistry Primer series).

Preface

1. Molecular Orbital Theory

1.1 The Atomic Orbitals of a Hydrogen Atom

1.2 Molecules Made from Hydrogen Atoms

1.3 C--H and C--C Bonds

1.4 Conjugation--Hückel Theory

1.5 Aromaticity

1.6 Strained s Bonds--Cyclopropanes and Cyclobutanes

1.7 Heteronuclear Bonds, C--M, C--X and C=O

1.8 The Tau Bond Model

1.9 Spectroscopic Methods

2. Molecular Orbitals and the Structures of Organic
Molecules

2.1 The Effects of p-Conjugation

2.2 Hyperconjugation--p-Conjugation

2.3 The Configurations and Conformations of Molecules

2.4 The Effect of Conjugation on Electron Distribution

2.5 Other Non-covalent Interactions

3 Chemical Reactions--How Far and How Fast

3.1 Factors Affecting the Position of an Equilibrium

3.2 The Principle of Hard and Soft Acids and Bases (HSAB)

3.3 Transition Structures

3.4 The Perturbation Theory of Reactivity

3.5 The Salem-Klopman Equation

3.6 Hard and Soft Nucleophiles and Electrophiles

3.7 Other Factors Affecting Chemical Reactivity

4 Ionic Reactions--Reactivity

4.1 Single Electron Transfer (SET) in Ionic Reactions

4.2 Nucleophilicity

4.3 Ambident Nucleophiles

4.4 Electrophilicity

4.5 Ambident Electrophiles

4.6 Carbenes

5 Ionic Reactions--Stereochemistry

5.1 The Stereochemistry of the Fundamental Organic Reactions

5.2 Diastereoselectivity

6 Pericyclic Reactions

6.1 The Four Classes of Pericyclic Reactions

6.2 Evidence for the Concertedness of Bond Making and
Breaking

6.3 Symmetry-allowed and Symmetry-forbidden Reactions

6.4 Explanations for the Woodward-Hoffmann Rules

6.5 Secondary Effects

7 Radical Reactions

7.1 Nucleophilic and Electrophilic Radicals

7.2 The Abstraction of Hydrogen and Halogen Atoms

7.3 The Addition of Radicals to p-Bonds

7.4 Synthetic Applications of the Chemoselectivity of
Radicals

7.5 Stereochemistry in some Radical Reactions

7.6 Ambident Radicals

7.7 Radical Coupling

8 Photochemical Reactions

8.1 Photochemical Reactions in General

8.2 Photochemical Ionic Reactions

8.3 Photochemical Pericyclic Reactions and Related Stepwise
Reactions

8.4 Photochemically-Induced Radical Reactions

8.5 Chemiluminescence

References

Index

Erscheint lt. Verlag 24.8.2011
Sprache englisch
Themenwelt Naturwissenschaften Chemie Organische Chemie
Naturwissenschaften Chemie Physikalische Chemie
Technik
Schlagworte Chemie • Chemistry • Organic Chemistry • Organische Chemie • Physical Chemistry • Physical Organic Chemistry • Physikalische Chemie • Physikalische Organische Chemie
ISBN-10 1-119-96467-9 / 1119964679
ISBN-13 978-1-119-96467-4 / 9781119964674
Haben Sie eine Frage zum Produkt?
EPUBEPUB (Adobe DRM)
Größe: 9,6 MB

Kopierschutz: Adobe-DRM
Adobe-DRM ist ein Kopierschutz, der das eBook vor Mißbrauch schützen soll. Dabei wird das eBook bereits beim Download auf Ihre persönliche Adobe-ID autorisiert. Lesen können Sie das eBook dann nur auf den Geräten, welche ebenfalls auf Ihre Adobe-ID registriert sind.
Details zum Adobe-DRM

Dateiformat: EPUB (Electronic Publication)
EPUB ist ein offener Standard für eBooks und eignet sich besonders zur Darstellung von Belle­tristik und Sach­büchern. Der Fließ­text wird dynamisch an die Display- und Schrift­größe ange­passt. Auch für mobile Lese­geräte ist EPUB daher gut geeignet.

Systemvoraussetzungen:
PC/Mac: Mit einem PC oder Mac können Sie dieses eBook lesen. Sie benötigen eine Adobe-ID und die Software Adobe Digital Editions (kostenlos). Von der Benutzung der OverDrive Media Console raten wir Ihnen ab. Erfahrungsgemäß treten hier gehäuft Probleme mit dem Adobe DRM auf.
eReader: Dieses eBook kann mit (fast) allen eBook-Readern gelesen werden. Mit dem amazon-Kindle ist es aber nicht kompatibel.
Smartphone/Tablet: Egal ob Apple oder Android, dieses eBook können Sie lesen. Sie benötigen eine Adobe-ID sowie eine kostenlose App.
Geräteliste und zusätzliche Hinweise

Buying eBooks from abroad
For tax law reasons we can sell eBooks just within Germany and Switzerland. Regrettably we cannot fulfill eBook-orders from other countries.

Mehr entdecken
aus dem Bereich
Das Basiswissen der Chemie

von Charles E. Mortimer; Ulrich Müller

eBook Download (2019)
Georg Thieme Verlag KG
84,99