Organotin Chemistry (eBook)

Alwyn Davies did his Ph.D. work in physical organic chemistry at University College London under the supervision of Sir Christopher Ingold, then worked for four years at Battersea Polytechnic in close association with Joseph Kenyon. He then returned to UCL where he has been successively Lecturer, Reader, and Professor. He has held visiting professorships at Indiana, Bordeaux, Freiburg, Deakin, and the Australian National University, and at the National Research Council (Ottawa). His work has covered the interconnecting themes of organic peroxides, organometallic chemistry, free radical chemistry, and the organic and organometallic applications of ESR spectroscopy, and his published work includes a book on Organic Peroxides (1961), and the first edition of Organotin Chemistry (1997).

1 Introduction

2 Physical Methods and Physical Data

3 The Stannyl Group as a Substituent

4 Formation of the Carbon-Tin Bond

5 Alkylstannanes

6 Functionally-substituted Alkylstannanes

7 Aryl- and Heteroaryl-stannanes

8 Alkenyl- and Alkynyl-stannanes, and Stannacyclopentadienes

9 Allyl-, Allenyl-, Propargyl, and Cyclopentadienyl-stannanes

10 Stannacycloalkanes

11 Organotin Halides

12 Organotin Hydroxides and Oxides

13 Organotin Carboxylates and Other Oxyesters

14 Organotin Alkoxides, Phenoxides, and Peroxides

15 Organotin Hydrides

16 Compounds with Sn-N Bonds

17 Compounds with Sn-S Bonds

18 Compounds with Sn-Sn Bonds

19 Compounds with Tin-metal Bonds

20 Organotin Radicals and Radical Ions

21 Stannylenes, Distannenes, and Stannenes

22 Organic Synthesis: Tin/Lithium Transmetallation, the Stille Reaction, and the Removal of Tin Residues

23 Applications, Environmental Issues, and Analysis

"This monograph gives an impressive overview, which concentrates mainly on the preparative aspects of organotin chemistry... One must also mention the well-structured tables and the abundance of clear formula schemes. Which enable the reader to quickly grasp the essence of each chapter."
Manfred Weidenbruch
Angewandte Chemie - IE

"Completely rewritten in order to reflect the developments that have characterized these specific areas."

Applied Organometallic Chemistry, Vol 18 No. 9 September 2004