Crystal Chemistry of High-Tc Superconducting Copper Oxides
Springer Berlin (Verlag)
978-3-642-83894-1 (ISBN)
1. Introduction: Superconductivity in Oxides Before 1986.- 2. Phases of the Systems A-La-Ca-Cu-O and A-Y-Ca-Cu-O (A = Ca, Sr, Ba): Structural Aspects.- 2.1 Copper Chemistry in Oxides: Oxidation States and Coordination.- 2.2 The Ternary Systems La-Cu-O and A-Cu-O (A = Ca,Sr,Ba).- 2.3 The Pseudoternary Systems A-La-Cu-O (A = Ca,Sr,Ba).- 2.4 The Pseudoternary System Y-Ba-Cu-O.- 2.5 The Systems Ln-Sr-Cu-O (Ln ? La).- 3. Electron Transport Properties Connected with Oxygen Nonstoichiometry.- 3.1 Electron Transport Properties in Cuprates Related to the Perovskite: General Considerations.- 3.2 Oxides with the K2NiF4-Type Structure.- 3.3 Oxides with the Oxygen-Deficient Sr3Ti2O7-Type Structure.- 3.4 Oxides with the Oxygen-Deficient Perovskite Structure.- 4. Substitutions in La2CuO4-Type and YBa2Cu3O7-Type Superconductors.- 4.1 Substitution on the Rare-Earth Sites.- 4.2 Substitution on the Copper Sites.- 4.3 Substitutions on Other Sites.- 5. Bismuth, Thallium and Lead Superconducting Cuprates.- 5.1 Bismuth Alkaline-Earth Superconducting Cuprates.- 5.2 Thallium Alkaline-Earth Superconducting Cuprates.- 5.3 Lead Alkaline-Earth Superconducting Cuprates.- 5.4 Layered Cuprates Involving Double Fluorite-Type Layers.- 5.5 Structural Relationships.- 6. Extended Defects in Superconducting Oxides: High-Resolution Electron Microscopy.- 6.1 YBa2Cu3O7-Type Superconductors: Ordering in the Perovskite Framework.- 6.3 Layer Interconnections.- 6.4 Extra Spots in ED Patterns: An Amazing Variety.- 6.5 Domains and Boundaries.- 7. Irradiation Effects in the High-Tc Superconducting Oxides.- 7.1 Radiation Damage in Solids.- 7.2 Radiation Damage by Electrons and Fast Neutrons in Copper Oxide Superconductors.- 7.3 Phase Transformations Induced by Fast Heavy Ions in the High-Tc Copper Oxides.- 7.4Conclusions.- 8. Concluding Remarks.- 8.1 Low Dimensionality of the Structure.- 8.2 Mixed Valence of Copper and Hole Delocalization.- 8.3 The Model of Copper Disproportionation.- 8.4 Role of the Lone Pair Cations and of the Alkaline Earth Elements.- References.
Erscheint lt. Verlag | 8.12.2011 |
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Reihe/Serie | Springer Series in Materials Science |
Zusatzinfo | X, 331 p. 158 illus. |
Verlagsort | Berlin |
Sprache | englisch |
Maße | 155 x 235 mm |
Gewicht | 521 g |
Themenwelt | Naturwissenschaften ► Physik / Astronomie |
Technik ► Elektrotechnik / Energietechnik | |
Technik ► Maschinenbau | |
Schlagworte | Chemistry • Copper Oxides • defects • Festkörperchemie • Layered Cuprate • Radiation damage • Superconductivity • Transport |
ISBN-10 | 3-642-83894-4 / 3642838944 |
ISBN-13 | 978-3-642-83894-1 / 9783642838941 |
Zustand | Neuware |
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