Advances in Inorganic Chemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 30 4
Copyright Page 5
Contents 6
Chapter 1. Catenated Nitrogen Ligands Part I. Transition Metal Derivatives of Triazenes, Tetrazenes, Tetrazadienes, and Pentazadienes 8
I. Introduction 8
II. Triazenide Complexes 9
III. Tetrazane, Tetrazene, and Tetrazadiene Complexes 48
IV. Pentazadiene Complexes 67
References 69
Chapter 2. The Coordination Chemistry of 2,2':6',2"-Terpyridine and Higher Oligopyridines 76
I. Introduction 76
II. The Complexes—Types of Bonding 79
III. Coordination Compounds of 2.2':6'.2"-Terpyridine 83
IV. Coordination Compounds of Higher Oligopyridines 111
V. Coordination Compounds of Macrocyclic Derivatives 113
References 116
Chapter 3. High-Nuclearity Carbonyl Clusters: Their Synthesis and Reactivity 130
I. Introduction 130
II. Synthesis of High-Nuclearity Carbonyl Clusters 148
III. Reactions of High-Nuclearity Carbonyl Clusters 168
IV. Concluding Remarks 214
References 215
Chapter 4. Inorganic Chemistry of Hexafluoroacetone 230
I. Introduction 230
II. Reactions of HFA with Compounds of Group IV Elements 231
III. Reactions of HFA with Compounds of Group V Elements 240
IV. Reactions of HFA with Compounds of Nitrogen and Group VI Elements 269
V. Metal Complexes of HFA 286
VI. Miscellaneous 306
VII. Summary 310
References 310
Index 320