Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 12 4
Copyright Page 5
Contents 8
List of Contributors 6
Contents of Previous Volumes 10
Chapter 1. Some Recent Preparative Chemistry of Protactinium 18
I. Introduction 18
II. Metallic Protactinium 20
III. Halides arid Oxyhalides 20
IV. Halogeno Complexes 36
V. Halide Complexes with Donor Ligands 47
VI. Oxides 51
VII. Nitrates 57
VIII. Sulfates and Selenates 58
IX. Miscellaneous Compounds 59
X. Appendix 60
References 64
Chapter 2. Vibrational Spectra of Transition Metal Carbonyl Complexes 70
I. Introduction 70
II. Structure Determination 71
III. Assigninelit of Fundamental CO-Stretching Modes 86
IV. MC-Stretching and M—C—O— and C—M—C-Bending Vibrations 124
V. ”Complete” Force Constant Calculations 128
VI. Electron Distribution 129
References 141
Note Added in Proof 149
Chapter 3. The Chemistry of Complexes Containing 2, 2’-Bipyridyl, 1,10-Phenan - throline, or 2,2’, 6’,2”-Terpyridyl as Ligands 152
I. Introduction 152
II. Structural Information 153
III. Thermodynamic Data 155
IV. Kinetic Studies 166
V. Spectroscopic Studies 176
VI. Complexes of Nonmetals 190
VII. Complexes of Metals in “Normal” Oxidation States 192
VIII. Complexes of Metals in “Low” Oxidation States 206
IX. Complexes of Metals in “High” Oxidation States 211
References 213
Chapter 4. Olefin Complexes of the Transition Metals 234
I. Introduction 234
II. Group IVB: Titanium 235
III. Group VB: Vanadium 236
IV. Group VIB: Chromium, Molybdenum, and Tungsten 237
V. Group VIIB: Manganese and Rhenium 255
VI. Group VIIIA: Iron, Ruthenium, and Osmium 260
VII. Group VIIIB: Cobalt, Rhodium, and Iridium 298
VIII. Group VIIIC: Nickel, Palladium, and Platinum 322
IX. Group I B: Copper, Silver, and Gold 344
X. Group IIB: Mercury 366
XI. Discussion 368
References 372
Chapter 5. Cis and Trans Effects in Cobalt (III) Complexes 392
I. Introduction 392
II. Ground-State Effects 397
III. Thermodynamic Effects 409
IV. Kinetic Effects 420
V. Summary 432
References 439
Author Index 446
Subject Index 480