Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 16 4
Copyright Page 5
Contents 6
List of Contributors 8
Chapter 1. The Chemistry of Bis(trifluoromethyl)amino Compounds 10
I. Introduction 10
II. Mercurials Containing the Hg–N(CF3) Bond 11
III. N-Halogenobis(trifluoromethyl)amines and Derivatives 16
IV. Bis(trifluoromethyl)amino-Substituted Organic Compounds 29
V. Bis(trifluoromethyl)carbamyl Fluoride, (CF3)2NCOF 37
VI. Bis(trifluoromethyl)amino-Substituted Inorganic Compounds 38
VII. Bis(trifluoromethyl)nitroxyl and Its Derivatives 39
VIII. Spectroscopic Properties 64
References 70
Chapter 2. Vacuum Ultraviolet Photoelectron Spectroscopy of Inorganic Molecules 74
I. Introduction 75
II. Theory 76
III. Some Experimental Points 82
IV. Assignment of Bands 86
V. Compilation of Photoelectron Spectra 92
VI. Discussion of Selected Results 96
VII. Conclusion 109
References 110
Chapter 3. FIuorinated Peroxides 118
I. Introduction 119
II. Oxygen Fluorides 120
III. Bis(fluorosulfuryl) Peroxide, FSO2OOSO2F (Peroxodisulfuryl Difluoride) 124
IV. Peroxide Derivtitives of S2O4F2 134
V. Bis(pentafluorosulfur) Peroxide, SF5OOSF5 136
VI. Peroxide Derivatives of S2O2F10 139
VII. Other Inorganic Peroxides 142
VIII. Fluoroperoxides 147
IX. Bis(perfluoroalkyl) Peroxides 156
X. Fluoroxy-Containing Peroxides 162
XI. Perfluoroacyl-Containing Peroxides 165
XII. Polyoxides 172
References 178
Chapter 4. Fluorosulfuric Acid, Its Salts, and Derivatives 186
I. Fluorosulfuric Acid 186
II. Fluorosulfates 194
III. Pyrosulfuryl Fluoride and Peroxydisulfuryl Difluoride 200
References 206
Chapter 5.The Reaction Chemistry of Diborane 210
I. Introduction 210
II. Addition Reactions 212
III. Substitution 222
IV. Reactions Effecting Reduction 234
V. Reaction with Hydrogen and Hydrogen Compounds 243
VI. Reaction with Metals and Metal Compounds 246
VII. Reaction with Nonmetals, Metalloids, and Their Compounds 250
VIII. Reactions Forming Carboranes 287
References 288
Chapter 6. Lower Sulfur Fluorides 306
I. Introduction 306
II. The Isomers of Disulfur Difluoride 308
III. Sulfur Difluoride and Difluorodisulfane Difluoride 322
IV. Difluoropolysulfanes 334
V. Sulfenyl Fluorides 336
References 340
Author Index 344
Subject Index 369
Contents of Previous Volumes 377