Advances in Inorganic Chemistry and Radiochemistry (eBook)

Front Cover 1
Advances in Inorganic Chemistry and Radiochemistry, Volume 8 4
Copyright Page 5
Contents 8
List of Contributors 6
Chapter 1. Substitution Products of the Group VIB Metal Carbonyls 12
I. Introduction 12
II. Derivatives of Coordinately Bonded Ligands 13
III. Anionic Derivatives 56
IV. p–Bonded Derivatives 57
V. Prospects 81
References 81
Chapter 2. Transition Metal Cyanides and Their Complexes 94
I. Introduction 95
II. Scandium, Yttrium, Lanthanum, and Actinium Lanthanides and Actinides
III. Titanium, Zirconium, and Hafnium 101
IV. Vanadium, Niobium, and Tantalum 102
V. Chromium, Molybdenum, and Tungsten 105
VI. Manganese, Technetium, and Rhenium 114
VII. Iron, Ruthenium, and Osmium 123
VIII. Cobalt, Rhodium, and Iridium 137
IX. Nickel, Palladium, and Platinum 155
X. Copper, Silver, and Gold 163
XI. Zinc, Cadmium, and Mercury 169
References 173
Chapter 3. Perchloric Acid 188
I. Introduction 189
II. Preparation 189
III. Perchloric Acid Hydrates 193
IV. Structure 195
V. Thermochemical Data 202
VI. Physical Properties 208
VII. Chemical Properties 209
VIII. Thermal Decomposition 212
IX. Radiation Chemistry 219
X. Perchloric Acid Flames 223
XI. Uses 228
References 229
Chapter 4. Neutron Diffraction and Its Applications in Inorganic Chemistry 236
I. Introduction 236
II. Heavy Element Compounds 238
III. Hydrogen Bonds 253
IV. Miscellaneous Compounds 259
V. Inelastic Scattering 262
VI. Conclusion 265
References 265
Chapter 5. Nuclear Quadrupole Resonance and Its Application in Inorganic Chemistry 268
I. Introduction 268
II. Phase Transition in Solids 273
III. Nature of Metal–Ligand Bonds 275
IV. Effect of Cations and Temperature 284
List of Symbols 290
References 291
Chapter 6. The Chemistry of Complex Aluminohydrides 294
I. Introduction 294
II. Historical 295
III. Lithium Aluminum Hydride 296
IV. Sodium Aluminum Hydride 325
V. Potassium Aluminum Hydride 333
VI. Cesium Aluminum Hydride 334
VII. Beryllium Aluminum Hydride 334
VIII. Magnesium Aluminum Hydride 336
IX. Calcium Aluminum Hydride 338
X. Analysis of Complex Aluminohydrides 340
XI. Summary 340
References 341
Author index 348
Subject index 372