Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 1 4
Copyright Page 5
Contents 10
List of Contributors 6
Preface 8
Chapter 1. Diene-Iron Carbonyl Complexes and Related Species 14
I. Introduction 14
II. Structural Considerations 17
III. Preparation and Properties of Diene-Iron Tricarbonyl Complexes 26
IV. Related Iron Carbonyl Complexes 43
V. Iron Carbonyl Complexes Derived from Acetylenes 50
References 56
Chapter 2. Reactions of Organotin Hydrides with Organic Compounds 60
I. Introduction 60
II. Reactions with Organic Compounds 65
References 98
Chapter 3. Orgunic Substituted Cyclosilanes 102
I. Introduction 103
II. Nomenclature 106
III. Structure and Properties of the Cyclosilanes 107
IV. Formation of the Cyclosilanes 123
V. General Reactions of the Cyclosilanes 128
VI. Reactions of Octaphenylcyclotetrasilane 130
VII. Reactions of Decaphenylcyclopentasilane 138
VIII. Reactions of Compound “C” 143
IX. Reactions of Dodecamethylcyclohexasilane 145
X. Organopolysilanes 146
XI. Summary and Conclusions 149
References 150
Chapter 4. Fluorocarbon Derivatives of Metals 156
I. Introduction 156
II. Lithium Derivatives 158
III. Magnesium Derivatives 163
IV. Derivatives of Group IIIb Elements 166
V. Derivatives of Group IVb Elements 174
VI. Transition Metal Derivatives 187
VII. Derivatives of Group IIb Elements 213
VIII. Spectroscopic Studies 219
References 229
Chapter 5. Conjugate Addition of Grignard Reagents to Aromatic Systems 234
I. Early Examples 234
II. Polycyclic Ketones 236
III. Hindered Ketones 241
IV. Heterocyclic Compounds 245
V. Phenolic Ketones 248
References 250
Chapter 6. Infrared and Raman Spectral Studies of p Complexes Formed Between Metals and Cn Hn Rings 252
I. Introduction 253
II.Theoretical Considerations in the Analysis of Vibrational Spectra 255
III. Techniques of Infrared and Raman Spectroscopy 264
IV. General Aspects of the Analysis of Spectra of p Complexes of Cyclic Systems, CnHn 267
V. Experimental Results for Three-Membered Rings 270
VI. Experimental Results for Four-Membered Rings 271
VII. Experimental Results for Five-Membered Rings 275
VIII. Experimental Results for Six-Membered Rings 304
IX. Experimental Results for Seven-Membered Rings 315
X. Experimental Results for Eight-Membered Rings 317
XI. Some Quantities Derived from Vibrational Spectra 320
References 324
Supplementary References 328
Author Index 330
Subject Index 343