Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 5 4
Copyright Page 5
Contents 8
List of Contributors 6
Contents of Previous Volumes 10
Chapter 1. Organosulfur Derivatives of Silicon Germanium Tin and Lead 14
I Introduction 15
II Synthetic Methods 16
III Chemical Properties 36
IV Physical Properties 51
V Theoretical Considerations 57
VI Industrial Interests 62
VII Appendix: Tabular Survey (Tables 1–12) 64
References 96
Chapter 2. The Structural Chemistry of Organo-Transition Metal Complexes: Some Recent Developments 106
I Introduction 106
II The Bonding of Cyclic Conjugated Ligands to Transition Metal Ions 107
III Conjugated Diolefin Complexes 113
IV Three-Membered Carbon Skeletons 118
V Organometallic Molecules Derived from Acetylenes 127
VI Alkyl and Fluoroalkyl Complexes of Transition Metal Ions 138
VII Metal Carbonyls and Substituted Carbonyls 141
References 144
Chapter 3. Structural Aspects of Organotin Compounds 150
I Introduction 150
II Configurations 152
III Representative Results 159
IV Organostannoxanes 172
References 178
Chapter 4. Organometallic Pseudohalides 182
I Introduction 182
II Methods of Preparation 184
III Structure and Physical Properties 188
IV Structural Isomerism and Chemical Bonding 188
V Chemical Properties 206
VI Tables of Properties 213
References 232
Chapter 5. Insertion Reactions of Compounds of Metals and Metalloids Involving Unsaturated Substrates 238
I Introduction 238
II Classification of Insertion Reactions and General Considerations 239
III 1,2-Addition of Metal Complexes to Unsaturated Substrates 250
IV 1,1-Addition of Metal Complexes to Unsaturated Substrates 266
V Tabular Survey 270
References 323
Chapter 6. Olefin Oxidation with Palladium (II) Catalyst in Solution 334
I Introduction 334
II Metal - Olefin Complexes 337
III The Reaction in Aqueous Solutions 341
IV The Reaction in Nonaqueous Solvents 356
References 362
Author lndex 366
Subject Index 389
Cumulative Subject Index: Volumes 1–5 394