Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 13 4
Copyright Page 5
Contents 6
List of Contributors 10
Chapter 1. Organometallic Chemistry: A Historical Perspective 12
I. Introduction 12
II. u-Bonded Organometals 15
III. Metal Carbonyls 27
IV. Metal Complexes with Unsaturated Hydrocarbons 30
V. Ferrocene. 31
VI. Biological Effects of Organometals 33
VII. Coalescence of a Discipline 38
VIII. Conclusion 48
References 49
Chapter 2. Arene Transition Metal Chemistry 58
I. Introduction 59
II. Some General Aspects of Arene Transition Metal Chemistry 59
III. Structure and Bonding 62
IV. Titanium and Zirconium Complexes 68
V. Vanadium, Niobium, and Tantalum Complexes 69
VI. Chromium, Molybdenum, and Tungsten Complexes 72
VII. Manganese, Technetium, and Rhenium Complexes 101
VIII. Iron, Ruthenium, and Osmium Complexes 104
IX. Cobalt, Rhodium, and Iridium Complexes 122
X. Nickel, Platinum, and Palladium Complexes 128
XI. Copper and Silver Complexes 131
References 136
Chapter 3. OrganometalIic Benzheterocycles 150
I. Introduction 150
II. Heterocycloalkenes, -dienes, and -trienes 155
III. Benzheterocycles 187
IV. Dibenzheterocycles 207
V. Tribenzometallepins and Tetrabenzometallonins 232
VI. Structure, Stereochemistry, and Spectra 234
References 272
Chapter 4. OrganometalIic Reactions Involving Hydro-Nickel, -Palladium, and -Platinum CompIexes 284
I. Introduction 285
II. Synthetic Methods 287
III. Structure and Reactions 303
IV. Hexadiene Synthesis 318
V. Catalyzed HX Addition to Multiple Bonds 325
VI. Homogeneous Hydrogenation and Isomerization 338
VII. Spectroscopic Studies 347
References 365
Chapter 5. Palladium-Catalyzed Organic Reactions 374
I. Introduction and Scope 374
II. Complexes of Palladium 375
III. Reactions of Monoolefins 389
IV. Reactions of Diolefins 436
V. Reactions of Acetylenes 445
VI. Stereochemistry of Addition of Pd(I1) and Nucleophiles to Unsaturated Substrates 452
References 455
Chapter 6. The Organometallic Chemistry of the Main Group Elements-A Guide to the Literature 464
A. Textbooks 465
B. Review–Periodic Surveys 480
C. Reviews–Continuing Series 482
D. Abstracting and Primary Journals 485
E. Conference Reports 487
F. Synthesis 493
G. Compound and Formulae Registers 495
References 497
Appendix 497
Author Index: Reviews of Organo-Transtion Metal Chemistry 554
Subject Index 562
Cumulative List of Contributors 570
Cumulative List of Titles 572