Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 12 4
Copyright Page 5
Contents 6
List of Contributors 10
Erratum 12
Chapter 1. The Organic and Hydride Chemistry of Transition Metals 14
I. Preliminaries 15
II. Olefin and Acetylene Complexes 19
III. Alkyl and Aryl Complexes 28
IV. Hydride Complexes 34
References 40
Chapter 2. Insertion Reactions of Transition Metal–Carbon a-Bonded Compounds II. Sulfur Dioxide and Other Molecules 44
List of Abbreviations 45
I. Introduction 46
II. Sulfur Dioxide Insertion. General Considerations and Background 46
III. Kinetics and Mechanism of Sulfur Dioxide Insertion 51
IV. Kinetics and Mechanism of Desulfination 63
V. Reactions of Sulfur Dioxide with a-Allyl, Propargyl, Cyclopropyl, and Cyclopropylmethyl Complexes of Transition Metals 65
VI. Survey of Reactions Involving Sulfur Dioxide 72
VII. Insertion of Other Unsaturated Molecules 83
VIII. Conclusion 89
References 90
Chapter 3. Organozinc Compounds in Synthesis 96
I. Introduction 96
II. Reactions of Zinc Carbenoids 97
III. Grignard-Type Addition Reactions of Organozinc Compounds 116
IV. Coupling Reactions of Organozinc Compounds 125
V. Miscellaneous Synthetic Reactions with Organozinc Compounds 127
VI. Polymerizations by Organozinc Compounds 129
References 132
Chapter 4. 13C NMR Chemical Shifts and Coupling Constants of OrganometalIic Compounds 148
I. Introduction 148
II. Recent Experimental Techniques of Relevance to Organometallic Chemistry 149
III. 13C Chemical Shifts of a-Bonded Carbon Atoms 153
IV. 13C Chemical Shifts of p-Bonded Carbon Atoms 165
V. 13C Coupling Constants 168
References 219
Chapter 5. The Organic Chemistry of Copper 228
I. Introduction 228
II. Preparation of Organocopper Reagents 229
III. Nature of Organocopper Reagents 244
IV. Reduction 266
V. Oxidation and Dimerization 267
VI. Substitution Reactions 272
VII. Addition Reactions 303
VIII. Organocopper Compounds as Intermediates in Organic Syntheses 314
IX. Organocopper (II) Compounds 325
References 326
Chapter 6. Compounds Derived from Alkynes and Carbonyl Complexes of Cobalt 336
I. Introduction 336
II. Reactions Involving CO2(CO)8 and Related Compounds 337
III. Reactions Involving (p- C5H5)CO(CO)2 and Related Compounds 371
IV. The Formation of Organic Compounds from Alkynes and Carbonylcobalt Complexes 379
References 384
Chapter 7. The Literature of Organo-Transition Metal Chemistry 1972 392
A. Textbooks 393
B. Reviews 397
C. Primary Journals 399
D. Abstract Journals 399
E. Conference Reports 400
F. Synthesis and Techniques 400
G. Data Compilations 401
References 401
Appendix 401
Author Index: Reviews of Organo-Transition Metal Chemistry 418
Author Index 421
Subject Index 459
Cumulative List of Contributors 467
Cumulative List of Titles 469