Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 35 4
Copyright Page 5
Contents 6
Contributors 8
Chapter 1. Chemistry at Diplatinum Centers 10
I. Introduction 10
ll. Complexes with Unsupported Platinum–Platinum Bonds 10
lll. Halide- and Hydride-Bridged Complexes 11
IV. Complexes Containing Organic Bridging Groups 14
V. Complexes Containing Orthometalated Phosphine Ligands 16
VI. Complexes Bridged by dppm or Related Ligands 20
VII. Complexes Bridged dppc Ligands 41
VIII. Summary 44
References 44
Chapter 2. Transition Metal Clusters in Homogenous Catalysis 50
I. Introduction 50
ll. Catalytic Reactions Involving CO 53
lll. Catalytic Reactions Involving H2 58
IV. Catalytic Reactions Involving CO and H2 83
V. Catalytic Reactions Involving CO and H2O 104
VI. Other Catalytic Reactions 116
VII. Conclusions 131
References 131
Chapter 3. The Interplay of Alkylidyne and Carbaborane Ligands at Metal Centers II: Proton-Mediated Reactions 144
I. Introduction 144
II. Protonations with HBF4.Et2O in the Presence of Monodentate Lewis Bases 151
III. Protonations with HBF4.Et2O in the Presence of Bidentate Phosphines 158
IV. Protonations with HX (X = Cl or I) 161
V. Formation of Dimetal Compounds 166
VI. Exo-nido Metallacarbaboranes 181
VII. Spectroscopic and X-Ray Diffraction Analysis 185
VIII. Conclusions 192
References 192
Chapter 4. Di- and Trinuclear Metal Complexes of Diboraheterocycles 196
I. Introduction 196
ll. 1,4-Diboracyclohexadiene Metal Complexes 200
Ill. 1,4-Dihydro-1,4-diboranaphthalene Metal Complexes 203
IV. 9,10-Dihydro-9,10-diboraanthracene Metal Complexes 206
V. 2,3-Dihydro-1,3-diborolyl Metal Complexes 211
VI. 1, 3-Diborafulvene Metal Complexes 214
VII. Concluding Remarks 217
References 218
Chapter 5. Trifluoromethyl-Containing Transition Metal Complexes 220
I. Scope of the Review 220
ll. Early Studies 221
lll. Transition Metal Trifluoromethyl Chemistry of the Past Decade 227
IV. Synopsis of Trifluoromethyl Metal Structural Data 243
V. Prospects 244
References 246
Chapter 6. Intramolecular Coordination in Organotin Chemistry 250
I. Introduction 251
Il. Divalent Organotin Compounds Containing a C,Y-Chelating Ligand 256
lll. Tetravalent Organotin Compounds Containing a C,Y-Chelating Ligand 265
IV. Concluding Remarks 297
References 299
Index 304
Cumulative List of Contributors 312