Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 32 4
Copyright Page 5
Contents 6
Chapter 1. Formation and Reactions of Organosulfur and Organoselenium Organometallic Compounds 8
I. Introduction 8
II. Rearrangements of Free and Coordinated Organosulfur and Organoselenium Reactants in the Coordination Sphere of Transition Metals 10
III. Rearrangements Induced by Deprotonation of Organosulfur Ligands 34
IV. Reactions of Organosulfur Compounds with Organometallic Complexes 39
V. Reactions of Chalcogen Atom Donors and Small Chalcogen Units with Organometallic Complexes 58
VI. Reactions of Coordinated Organosulfur and Organoselenium Compounds with Electrophiles and Nucleophiles 79
VII. Reactions of Inorganic Sulfide, Selenide, and Thiol Complexes with Organic Compounds 103
VIII. Addendem 110
References 116
Chapter 2. Hydroformylation Catalyzed by Ruthenium Complexes 128
I. Introduction 128
II. Hydroformylation with Mononuclear Ruthenium Complexes 129
III. Catalysis Initiated by Clusters 136
IV. Photochemical Activation and Supported Catalysis 147
V. Conclusion 150
References 151
Chapter 3. X-Ray Structural Analyses of Organomagnesium Compounds 154
I. Introduction 154
II. Structures of Organomagnesium Compounds in the Gas Phase 164
III. Structures of Organomagnesium Compounds in the Solid State 166
IV. Compounds without a Magnesium–Carbon Bond 218
V. Appendix 224
References 229
Related Reviews 232
Chapter 4. Recent Advances in the Chemistry of Metal–Carbon Triple Bonds 234
I. Introduction 234
II. Physical and Theoretical Studies of Alkylidyne Metal Complexes 235
III. Synthesis of Metal–Carbon Triple Bonds 250
IV. Reactions of Transition Metal Alkylidyne Complexes 266
V. Concluding Remarks 324
References 325
Chapter 5. Chemistry of Cationic Dicyclopentadienyl Group 4 Metal-Alkyl Complexes 332
I. Introduction and Scope of Review 332
II. Historical Interest in the Role of Cationic Species in Ziegler–Natta Olefin Polymerization 334
III. Synthesis of Cp2M(R)(L)+ and Cp2M(R)+ Complexes 336
IV. Structures 344
V. Reactivity 356
VI. Applications 377
VII. Summary 388
References 389
Index 396
Cumulative List of Contributors 412