Advances in Organometallic Chemistry (eBook)

Front Cover 1
Advances in Organometallic Chemistry, Volume 14 4
Copyright Page 5
Contents 6
List of Contributors 10
Preface 12
Chapter 1. On the Way to Carbene and Carbyne Complexes 16
I. Introduction 16
II. Transition Metal–Carbene Complexes 18
III. Other Syntheses of Carbene Complexes 21
IV. Reaction Possibilites of Carbene Complexes 23
V. Transition Metal–Carbyne Complexes 36
VI. Reaction of Other Pentacarbonylcarbene Complexes With Boron Trihalides 39
VII. Reaction of Pentacarbonlcarbene Complexes With Halides of Aluminum And Gallium 42
VIII. Reaction of Lithium Benzoylpentacarbonyltungstate With Triphenyldibromophosphorane 42
IX. Reactivity of The Carbyne Ligand 43
References 44
Chapter 2. Coordination of Unsaturated Molecules to Transition Metals 48
I. Introduction 48
II. Theoretical Modles 50
III. Structural Results 52
IV. Summary 74
References 75
Chapter 3. Methyltin Halides and Their Molecular Complexes 78
I. Introduction 78
II. Methods of Study 79
III. Structures of Methyltin Halides 83
IV. Molecular Complexes of Methyltin Halides 91
V. Conclusion 106
References 107
Chapter 4. Chemistry of Carbon-Functionul Alkylidynetricobalt Nonucarbonyl Cluster Complexes 112
I. Introduction General Properties of Alkylidyneticobalt Nonacarbonyl Complexes
II. Synthesis of Alkylidynetricobalt Nonacarbonyl Complex 115
III. Chemistry of The Tricobaltacarbon Decacarbonyl Cation 125
IV. Highly Stable Nonacarbonyl Tricobaltcarbon-Substituted Carbonium Ions 134
V. Decomposition Reactions And Derived Synthetic Applications of Alkylidynetricobalt Nonacarbonyl Complexes 150
VI. Concluding Remarks 153
References 156
Chapter 5. Ten Years of Metallocarboranes 160
I. Introduction 160
II. Metallocarboranes: Synthetic Methods 165
III. Twelve-Vertex Metallocarboranes 170
IV. Thirteen-Vertex Metallocarboranes 182
V. Fourteen-Vertex Metallocarboranes 186
VI. Eleven-Vertex Metallocarboranes 186
VII. Ten-Vertex Metallocarboranes 190
VIII. Nine-Vertex Metallocarboranes 193
IX. Oxidative Addition To B—H Bonds 195
X. Metallocarboranes in Homogeneous Catalysis 197
References 198
Chapter 6. Recent Advances in Organoantimony Chemistry 202
I. Introduction 202
II. Hexacoordinate Mono-And Diorganoantimony Compounds 203
III. Triorganostibine Sulfide 207
IV. Tertiary Stibines 212
References 217
Chapter 7. Pentaalkyls and Alkylidene Trialkyls of the Group V Elements 220
I. Introduction 220
II. Simple Nitrogen Ylides 222
III. Phosphorus Ylides And Pentaalkylphoshoranes 224
IV. Arsenic Ylides And Pentaalkylarsoranes 239
V. Antimony Ylides And Pentaalkylstiboranes 246
VI. Bismuth Compounds 251
VII. Related Compounds of Vanadium,Niobium,And Tantalum 251
References 255
Chapter 8. Acetylene and AIlene Complexes: Their Implication in Homogeneous Catalysis 260
I. Introduction 260
II. Acetylene Complexes 261
III. Allene Complexes 280
References 294
Chapter 9. High Nuclearity Metal Carbonyl Clusters 300
I. Introduction 300
II. Structural Data in the Solid State 301
III. Structural Data in Solution 321
IV. Syntheses 326
V. Methods of Separation 331
VI. Reactivity 332
VII. Iron Derivatives 338
VIII. Ruthenium Derivatives 339
IX.Osmium Derivatives 340
X. Cobalt Derivatives 340
XI. Rhodium Derivatives 342
XII.Iridium Derivatives 347
XIII. Nickel Derivatives 348
XIV. Platinum Derivatives 349
XV. Bonding Theories 351
References 356
Chapter 10. Free Radicals in Organometallic Chemistry 360
I. Introduction 360
II. Metal-Centered Organometallic Radicals 364
III. Other Organometallic Radicals 382
IV. Bimolecular Homolytic Substitution(sH2)At the Metal Center of an Organometallic Substrate 385
V. Addition or Elimination Radical Reactions 396
VI. Appendix 405
References 407
Subject Index 416
Cumulative List of Confribufors 425
Cumulative List of Titles 427