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Hybrid Organic Polymer-Inorganic Nanoparticles
Royal Society of Chemistry (Verlag)
978-0-85404-173-2 (ISBN)
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This state-of-the-art book gives a comprehensive overview of the investigation of hybrid nanoparticles coated with organic, polymeric and dendritic ligands - from molecules, macromolecules and dendrimers. The functional organic ligands fulfil both passive and active roles in nanoparticle (metal, semiconductor, oxides) behaviour and properties. However true hybrid character not only combines the properties of both components but results in a new property or phenomena. The book is a thorough examination and differentiation of the class of ligands/shell and hosts that have been used for the synthesis and stabilization of these nanoparticles. It covers several aspects of these interesting materials - the introduction focuses on the unique properties of nanoparticles and its importance in nanoscience and colloidal phenomena. Then follows a focus on inorganic nanoparticle synthesis, characterization, and properties (metal, semiconductor/chalcogenide, and oxide nanoparticles. Following this is a series of chapters focusing on the organic shell/ligands or capping agents with the following classification: small molecule ligands, polymeric ligands, and dendrimeric ligands and hosts.
These chapters focus on the methods of stabilizing, hosting, coating, and exchange reactions with the use of organic molecules and macromolecules which are important divisions, given the variety of investigations that have been carried out through the years. While previous books have focused on inorganic nanoparticles, this book emphasizes the important contribution of the organic and polymer ligands/shell themselves in achieving a true hybrid character. The chapter on characterization methods is important since it describes methods for investigating colloidal phenomena, functional group properties, stability, and finally true hybrid behaviour. Then follows a full chapter on applications which shows the potential of these systems for: model systems and studies, photochemical properties, electro-optical properties, catalytic properties and sensing properties. Finally there is a conclusions and future outlook chapter. The applications and emerging applications for these materials are very relevant to medical, commercial and military applications.
Professor Rigoberto Advincula is at the Department of Chemistry, University of Houston, Houston, USA. He has been involved with materials and nanoscience research for the last 10 years. More specifically, he investigated the synthesis of dendrimers and dendrons used as host and ligands for the synthesis of metal and semi-conductor nanoparticles and also investigated the synthesis of metal nanoparticles using star-block copolymers and polyelectrolyte hosts. In addition he has researched the synthesis and functionalization of oxide nanoparticles with polymer brushes via surface initiated polymerization. Previously he has written three reviews on grafting of polymer brushes by SIP and investigated the applications of these hybrid materials in photovoltaic effects, catalysis, and sensing.
Introduction Nanoparticles Small Molecule Ligands Polymeric Ligands Dendrimeric Ligands and hosts Characterization Methods Applications Conclusions
Reihe/Serie | RSC Nanoscience & Nanotechnology ; v. 18 |
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Mitarbeit |
Herausgeber (Serie): Harry Kroto, Paul O'Brien, Harold G. Craighead |
Verlagsort | Cambridge |
Sprache | englisch |
Maße | 156 x 234 mm |
Themenwelt | Naturwissenschaften ► Chemie ► Anorganische Chemie |
Naturwissenschaften ► Chemie ► Organische Chemie | |
Technik | |
ISBN-10 | 0-85404-173-7 / 0854041737 |
ISBN-13 | 978-0-85404-173-2 / 9780854041732 |
Zustand | Neuware |
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