Hydrogen Materials Science and Chemistry of Carbon Nanomaterials (eBook)

Proceedings of the NATO Advanced Research Workshop on Hydrogen Materials Science an Chemistry of Carbon Nanomaterials, Sudak, Crimea, Ukraine, September 14-20, 2003
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2006 | 2004
XXIX, 660 Seiten
Springer Netherland (Verlag)
978-1-4020-2669-0 (ISBN)

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The 2003 International Conference 'Hydrogen Materials Science and Chemistry of Carbon Nanomaterials' was held in September 2003. In the tradition of the earlier ICHMS conferences, this meeting served as an interdisciplinary forum for the presentation and discussion of the most recent research on transition to hydrogen-based energy systems, technologies for hydrogen production, storage, utilization, materials, energy and environmental problems. The aim of the volume is to provide an overview of the latest scientific results on research and development in the different topics cited above. The representatives from industry, public laboratories, universities and governmental agencies have presented the most recent advances in hydrogen concepts, processes and systems, to evaluate current progress in these areas of investigations and to identify promising research directions for the future.
The 2003 International Conference "e;Hydrogen Materials Science and Chemistry of Carbon Nanomaterials"e; was held in September 2003. In the tradition of the earlier ICHMS conferences, this meeting served as an interdisciplinary forum for the presentation and discussion of the most recent research on transition to hydrogen-based energy systems, technologies for hydrogen production, storage, utilization, materials, energy and environmental problems. The aim of the volume is to provide an overview of the latest scientific results on research and development in the different topics cited above. The representatives from industry, public laboratories, universities and governmental agencies have presented the most recent advances in hydrogen concepts, processes and systems, to evaluate current progress in these areas of investigations and to identify promising research directions for the future.

Preface
International Advisory and Organizing Committee
Program Committee
Words of Welcome
Contents
Phase Transformations in Carbon Materials
ZA. Matysina, D. V. Schur, S. Yu. Zaginaichenko, V.B. Molodkin, A.P. Shpak
1
Hydrogen Solubility in FCC Fullerite D. V. Schur, ZA. Matysina, S. Yu. Zaginaichenko
25
Controlling Role of Electron Concentration in Plasma - Chemical Synthesis G.N. Churilov

Oxygen Source for Isolated Fuel Ceils R. Lou V. Shapovalov, E. Ve/csler
Microscopic Characteristics of H Diffusion and Diffuse Scattering of Radiations in H.C.P.-Ln-H (From the Data on Electrical-Resistivity Relaxation)
V.A. Tatarenko, T.M Radchenko, V.B. Molodkin
59
Investigation of Content of Endometallofulerenes Extracts LE. Kareev, Y.M. Shulga, V.P. Bubnov, VI. Kozlovski, A.F. Dodonov, M. V. Marlynenko, K.B. Zhogova, EB. Yagubskii
67
An Overview of Hydrogen Storage Methods V.A. Yartys, M V. Lototsky
Alumo- and Borohydrides ofMetals: History, Properties, Technology, App!ication B.M Bulychev
105
Structural - Phase Transformations in Titanium - Fullerene Films at Implantation ofBoron lons
L. V. Baran, E.M. Shpilevsky, G. P. Okatova
115
Field Emission Investigation of Carbon Nanotubes Doped by Different Metals
K.N. Nikoiski, A.S Baturin, VS. Bormashov, AS. Ershov, L.D. Kvacheva,
D.A. Kurnosov, V.E. Muradyan, A.A. Rogozinskiy, D. V. Schur,
E.P. Sheshin, A. P. Simanovskiy, Yu. M. Shulga, R. G. Tchesov,
S Yu. Zaginaichenko
123
Development of Methods of Deposition of Discontinuous Nickel Coatings on
Powders ofAB5 Type Alloys
1. Slys, L. Shcherbakova, A. Rogozinskaya, D. Schur, A. Rogozinskii
131
vi
XRD Patterns of Cathode Deposits Formed in Electric are Sputtering Zr-Me Graphite Electrodes
Yu.M Shulga, D. V. Schur, S.A. Baskakov, A.P.Simanovskiy, A.A. Rogozinskaya, A.A. Rogozinskiy, A.P. Mukhachev
137
Metal Hydride Accumulators of Hydrogen on the Basis ofAlloys of Magnesium and Rare-Earth Metals with Nickel
B.P. Tarasov, S.N. Klyamkin, V.N. Fokin, D.N. Borisov, D. V. Schur, V.A. Yariys
143
Synthesis ofNanotubes in the Liquid Phase
D. V. Schur, A. G. Dubovoy, E.A. Lysenko, T.N. Golovchenko, S. Yu. Zaginaichenko, AF. Savenko, V.M Adeev, S.N. Kaverina
147
Mossbauer Study of Carbon Nanostructures Obtained on Fe-Ni Catalyst T Yu. Kiseleva, A.A. Novakova, B.P. Tarasov, V.E. Muradyan
153
Determination of an Optimum Performance of PEM Fuel Celi Based on its
Limiting Current Density
Ayoub Kazim
159
Photoinduced Modifications ofthe Structure and Microhardness of Fullerite C 1. Manika, J Maniks, 1. Kalnacs
167
Investigation on the Carbon Special Form Graphitic Nanofibres as a Hydrogen
Storage Materials
Bipin Kumar Gupta, O.N. Srivastava
177
Heterometallic Fullerides ofTransition Metals with the Composition K V.A. Kulbachinskli, B.M Bulychev, R.A. Lunin, A. V. Krechetov, V.G. Kytin, K. V. Poholok, K. Lips, J. Rappich
185
Characterization ofNanoparticles Processed by arc-Discharge between Carbon
Electrodes Containing Ni Catalyst
M Leonowicz, Yu.M. Shulga, V.E. Muradyan, M Wozniak, WeiXie
193
Protection of Securities by the Application of Fullerenes
D. V. Schur, N.S. Astratov, A.P. Pomytkin, AD. Zolotarenko, TI. Shaposhnikova
203
Spectrophotometric Analysis of C and C Fullerenes in Toluene Solutions NS. Anikina, S. Yu. Zaginaichenko, MI. Maistrenko, AD. Zolotarenko, GA. Sivak, D. 17. Schur, L. 0. Teslenko
207
Effect ofthe Nature ofthe Reactor Wall Material on Morphology and Structure
of Products Resulted from are Graphite Sputtering
AD. Zolotarenko, AF. Savenko, A.N. Antropov, Iv!.!. Maystrenko,
R.N. Nikulenko, A. Yu. Vlasenko, V.K Pishuk, V. V. Skorokhod,
D. V. Schur, A.N. Stepanchuk, P.A. Boyko
2 i 7
Study of Thermodynamic Parameters of Hydrogen Gas by Grapho-Analytic
Method
B. Ibrahimoglu, T.N. Veziroglu, A. Huseynov, D. V. Schur
225
vii
Simulation ofOperation Heat or Cold-Making Unit with Hydride Heat Pump Yu. 1. Shanin
233
Quantum-Chemical Investigations of Single Wall Carbon Nanotube
Hydrogenation Processes
N.G. Lebedev, 1. V. Zaporotskova, LA. Chernozatonskii
243
Quantum Chemical Investigations ofthe Growth Models ofSingle Wall Carbon
Nanotubes on Polyhen Rings, Fullerenes and Diamond Surface
N. G. Lebedev, 1. V. Zaporotskova, LA. Chernozatonskii
259
Covalent-Binding Carbon Nanotube: Simulation of Formation Mechanisms and
Energy Characteristics
E.E. Mikheeva, LA. Chernozatonskii, T Yu. Astahova
279
To the Theory of Formation in Cast Iron of Spherical Graphite A.A. Baranov, D.A. Baranov
283
Modelling ofDehydration and Dehydrogenation in Pure and Ba-, Ca-, Sr- or
Y-Modified Zirconia Nanolayer
N. V. Tokiy, T Ye. Konstantinova, D.L. Savina, V. V. Tokly
291
Metailcontaining Nanoparticles in Carbochain Polymeric Matrixes s.P. Gubin, V.M J3uznik, G. Yu. Yurkov, M.S. Korobov, A. V. Kozinkin, A. K. Tsvetnikov, 1. P. Dotsenko
299
X-ray Structural Study ofDeposit Formed on Electric arc Sputtering of Me
Composites
A.A. Rogozinskaya, D. V. Schur, 1.1. Timofeeva, LA. Klochkov, AP. Simanovski),
A.A. Rogozinski)
307
Effect of Hydrogen on Delayed Fracture of HCP c -Steels Based on Fe-Mn Solid
Solution
B.M Efros, V. V. Berezovskaya, S. V. Gladkovskii, L. V. Loladze
313
System Combined Automobile Feed on Carbon Nanostructures with Hydrogen
Adsorbate Application
Al. Zakharov, V.J. Kostikov, AS. Kotosonov, TA. Ivankova, O.A. Milovanova
319
T-Nanoconstructions on the (000 1) - Surface of Graphite Based on Carbon
(6,6) - Nanotubes
A.P. Popov, I.V. Bazhin
325
Three - Dimensional Polymerized Cubic Phase ofFullerenes C AP. Popov, 1. V. Bazhin
329
Nanostructure and Electronic Spectra of Cu-C Films
0. P. Dmytrenko, M P. Kulish, L. V. Poperenko, Yu. 1. Prylutskyy, E. Al. Shpilevskyy,
1. V Yurgelevich, M. Hietschold, F.S. Schulze, J. Ulansk P. Scharff
viii
Hydrogenated Amorphous Silicon Carbide Films as Perspective Tribological Coatings and Semiconductor Layers
v.I. Ivashchenko, O.K. Porada, L.A. Ivashchenko, G. V. Rusakov, S.M. Dub, V.M. Popov
Vibrational Spectra and Molecular Structure ofthe Hydrofullerenes C
C and C as Studied by IR and Raman Spectroscopy and First-Principle
Calculations
A.A. Popov, V.M Senyavin, A.A. Granovsky, A.S. Lobach
Hydrogen Segregation in the Residual Stresses Field N.M Vlasov., 1.1. Fedik
Nanoparticles of Metals and Oxides on Surface of Carbon Fibers are Effective Catalysts of Chemical Transformations of Epoxy Oligomers
v.I. Dubkova
363
Theory of Transport Phenomena on Plasma — Metal Hydride Interface S VN. Borisko, S. V. Borisko, D. V. Zynov ‘ev, Ye. V. Klochko
The Ultradisperse Formations of Free Carbon in Alloys of Iron D.A. Baranov, A.A. Baranov, 1. V. Leirich
383
Simulation of Fullerene Irradiation and Fragmentation by Particle Beams N. V. Makarets, V. V. Moskalenko, Yu. 1. Prylutskyy., 0. V. Zaloyilo
387
Lithium in Nanoporous Carbon Materials Produced from SiC I.M. Kotina, V. M. Lebedev, A.G. Jives, G. V. Patsekina, L.M. Tuhkonen, A.M. Danishevskii, S.K Gordeev, MA. Yagovkina
391
Scientific-Technical Prerequisites in Ukraine for Development ofthe Wind-
Hydrogen Plants
V.A. Glazkov, AS. Kirichenko, BI. Kushnir, V. V. Solovey, A.S. Zhirov,
D.V.Schur S
399
Synthesis and Structural Peculiarities ofthe Exfoliated Graphite Modified by Carbon Nanostructures
Yu.I. Sementsov, G.P. Prikhodko, S.L. Revo, A. V. Melezhyk, ML. Pyatkovskiy, v.v. Yanchenko
405
Modeling of TDS-Spectra of Dehydrating Yu. V. Zaika, JA. Chernov
415
Some Schematics ofUse ofHydride Devices in the Automobile Yu.I. Shanin
427
Electronic-Microscopic Investigation ofNanoscale Products of Catalytic Pyrolysis of Toluene S P.M Sylenko, A.M Shiapak, S.M. Kaverina, D. V. Schur, S. 0. Firstov,
v. v. Skorokhod
437
ix
Application ofthe Metal Hydride Activation Effect ofHydrogen Isotopes for
Plasma Chemical Technologies
Yu.F. Shmal’ko, Ye. V. Klochko
447
Vibrational Spectra of C Polymers: Experiment and First-Principle Assignment v. M. Senyavin, A. A. Popov, A. A. Granovsky
457
Feasibility of Hydrogen Energy Production Through Natura! Gas Steam
Reformation Process in the UAE
A. Kazim .
467
Isotope Effects in the Quasielastic Mössbauer Absorption of 57 in NbH and
NbD
R. Wordel, F.E. Wagner
473
Electrica! Resistance of Binary Ordered Alloys with HCP Structure in the
Presence of Impurity Atoms or Thermal Vacancies
ZA. Malysina, S. Yu. Zaginaichenko, D. V. Schur, A. Yu. Vlasenko
481
Hydriding Properties ofMagnesium-Sa!t Mechanical Alloys E. Yu. Ivanov, 1. G. Konstanchuk, V. V. Boldyrev
489
Hydrogen Sorption and Electrochemical Properties oflntermetallic Compounds
La and La
E.E. Levin, P.A. Donskoy, S.A. Lushnikov, VN. Verbetsky,
T. Ya. Safonova, O.A. Petrii
503
Hydride Phases in Sm —NH System VN. Fokin, Yu.M. Shul B.P. Tarasov, E.E. Fokina,
1.1. Korobov, A.G. Burlakova, S.P. Shilkin .
511
Optical Investigation of Hydrogen Intercalation-Deintercalation Processes in
Layered Semiconductor ‘y-InSe Crystals
Yu.J. Zhirko., Z.D. Kovalyuk., MM. Pyrija., V.B. Boledzyuk
19
Quantum Topology and Computer Simulation of Confined Hydrogen Atom Inside Spherical-Form Gap
gA. Beznosyuk, D.A. Mezentsev, M.S. Zhukovsky, TM Zhukovsky
531
Calorimetric Investigation ofthe Hydrogen Interaction with Ti E. Yu.Anikina, VN. Verbetsky
539
Interaction in NbVCo-H and NbVFe-H Systems under Hydrogen Pressure up to
2000 atm.
SA. Lushnikov., VN. Verbetsky
547
Effect of Hydrogenation on Spin-Reorientation Phase Transitions in R
(R = Y, Ho, Er) Compounds
I.s. Tereshina., G.S. Burkhanov., O.D. Chistyakov., N.B. Kol’chugina.,
S.A Nikitin., H. Drulis
553
x
The Cluster Growth Mechanism of Nanostructured Diamond v. Melnikova
Specific Features in Thermal Expansion of YFe 1 Single Crystals E. Tereshina., K. Skokov., L. Folcik, S. Nikitin., H. Drulis
563
Study of Structure, Hydrogen Absorption and Eleetrochemical Properties of
Tio Substoichiometric Laves Phase Alloys
T.A. Zotov, VN. Verbetsky, O.A. Petrii, T. Y. Safonova
569
Effect of Stress on Accumulation ofHydrogen and Microstructure of Silicon co-Implanted with Hydrogen and Helium
A. Misiuk, .1. Ratajczak, A. Barcz, J. Bak-Misiuk, A. Shalimov, B. Surma, A. Wnuk, J. Jagielski, 1. V. Antonova
579
Hydrogen Storage Materials and their Maximum Ability on Reversible Hydrogen
Sorption
N.M Vlasov, A.J. Solovey, II. Fedik, AS. Chernikov
593
The Study of Changes of Physico - Mechanical Properties of Materials in a
Condensed State under Hydrogen lnfluence Using Fault Detection Acoustic
Microscopy Methods
A. V. Budanov., A.I.Kustov., I.A. Migel
603
Diffusion of Hydrogen in Amorphous, High Deformed and Nanocrystalline
Alloys
N.I. Timofeyev, V.K. Rudenko, V. V. Kondratyev, A. V.Gapontsev,
A.N. Voloshinskii
617
Diffusion of Hydrogen in Binary and Ternary Disordered Alloys Nl. Timofeyev, V.K. Rudenko, V. V. Kondratyev, A. V.Gapontsev, AN. Voloshinskii
.
635
Author Index
653
Subject Index
657

Erscheint lt. Verlag 4.4.2006
Reihe/Serie Nato Science Series II:
NATO Science Series II: Mathematics, Physics and Chemistry
NATO Science Series II: Mathematics, Physics and Chemistry
Zusatzinfo XXIX, 660 p.
Verlagsort Dordrecht
Sprache englisch
Themenwelt Naturwissenschaften Chemie Anorganische Chemie
Naturwissenschaften Chemie Physikalische Chemie
Naturwissenschaften Physik / Astronomie
Sozialwissenschaften
Technik Maschinenbau
Schlagworte alloy • Environment • liquid • Modeling • Nanomaterial • Nanoparticle • Natur • Polymer • Raman spectroscopy • Simulation • spectroscopy • Transport • Vibration
ISBN-10 1-4020-2669-2 / 1402026692
ISBN-13 978-1-4020-2669-0 / 9781402026690
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