Organometallic Compounds

Group IV Silicon, Germanium, Tin, and Lead.- 1 Introduction.- 2 Silicon.- Tetra-alkyls and tetra-aryls of silicon.- Unsaturated organosilicon compounds.- Heterocyclic compounds of silicon and carbon.- Cyclic saturated organosilanes.- Cyclic unsaturated organosilanes.- Organosilicon(II) compounds and organosilicon radicals.- Organosilicon halogen compounds.- Monohalides, R3SiX.- Dihalides, R2SiX2.- Trihalides, RSiX3.- Organosilicon pseudohalides.- Organosilicon oxygen compounds.- Silanols.- Silanolates or siloxy-metal derivatives.- Alkoxides and aryloxides.- Siloxanes.- Silicones.- Short-lived R2Si=O intermediates.- Peroxides.- Ketones.- Organosilicon sulphur, selenium, and tellurium compounds.- Organosilicon nitrogen compounds.- Aminosilanes.- Disilazanes.- Cyclic silicon-nitrogen compounds.- Hydrazine derivatives.- Organosilylazenes.- Derivatives of hydroxylamine and amides.- Silatranes.- Organosilicon phosphorus, arsenic, antimony, and bismuth compounds.- Organosilicon hydrides.- Compounds containing silicon-silicon bonds.- Acyclic derivatives.- Cyclic derivatives.- Organosilicon-metal compounds.- Groups I and II.- Groups III and IV.- Transition-metal derivatives.- Silylmethyl-transition-metal derivatives.- 3 Germanium.- Tetra-alkyls and tetra-aryls of germanium.- Unsaturated organogermanium compounds.- Heterocyclic compounds of germanium and carbon.- Organogermanium(II) compounds and organogermanium radicals.- Organogermanium halogen compounds.- Monohalides, R3GeX.- Dihalides, R2GeX2.- Trihalides, RGeX3.- Alkylgermanes with halogenated side-chains.- Organogermanium pseudohalides.- Organogermanium oxygen compounds.- Oxides and hydroxides.- Alkoxides.- Peroxides.- Esters.- Ketones.- Organogermanium sulphur, selenium, and tellurium compounds.- Organogermanium nitrogen compounds.- Organogermanium phosphorus, arsenic, antimony, and bismuth compounds.- Organogermanium hydrides.- Compounds containing germanium-germanium bonds.- Organogermanium-metal compounds.- Alkali-metal and magnesium derivatives.- Derivatives of other main-group metals.- Transition-metal derivatives.- 4 Tin.- Tetra-alkyls and tetra-aryls of tin.- Unsaturated organotin compounds.- Heterocyclic compounds of tin and carbon.- Organotin(II) compounds and organotin radicals.- Organotin halogen compounds.- Monohalides, R3SnX.- Dihalides, R2SnX2.- Trihalides, RSnX3.- Complexes of organotin halides.- Organotin(II) halides.- Organotin pseudohalides.- Organotin oxygen compounds.- Monohydroxides and derivatives.- Alkoxy and aryloxy derivatives, R3SnOR1.- Dihydroxides and derivatives.- Tetra-alkyl distannoxanes, (XR2Sn)2O, and related derivatives.- Stannonic acids.- Peroxides.- Sn-O compounds in organic synthesis.- Organotin sulphur, selenium, and tellurium compounds.- Organotin nitrogen compounds.- Organotin phosphorus, arsenic, antimony, and bismuth compounds.- Organotin hydrides.- Hydrostannation.- Hydrostannolysis.- Use of organotin hydrides in synthesis.- Compounds containing tin-tin bonds.- Derivatives of distannane.- Derivatives of hexa-alkyl or -aryl-ditin compounds.- Derivatives of higher stannanes.- Derivatives of the type (R2Sn)n.- Organotin-metal compounds.- Alkali-metal derivatives.- Derivatives of other main-group elements.- Transition-metal derivatives.- 5 Lead.- Tetra-alkyls and tetra-aryls of lead.- Unsaturated organolead compounds.- Organolead(II) compounds and organolead radicals.- Organolead halogen compounds.- Monohalides, R3PbX.- Dihalides, R2PbX2.- Trihalides, RPbX3.- Organolead oxygen compounds.- Organolead sulphur, selenium, and tellurium compounds.- Organolead Group V compounds.- Organolead hydrides.- Compounds containing lead-lead bonds.- Dilead derivatives.- (R2Pb)x derivatives.- Organolead-metal compounds.- Alkali-metal derivatives.- Transition-metal derivatives.- References: Group IV.- V Arsenic, Antimony, and Bismuth.- 6 Introduction.- 7 Arsenic.- Tri-alkyls and tri-aryls of arsenic.- Unsaturated organoarsenic compounds.- Penta-alkyls and penta-aryls of arsenic.- Ylides of arsenic.- Organoarsenic halogen compounds.- Derivatives of arsenic(V).- Arsonium salts.- Dihalides, R3AsX2.- Trihalides, R2AsX3.- Tetrahalides, RAsX4.- Complexes of Arsenic(V) halides.- Derivatives or arsenic(III).- Monohalides, R2AsX.- Dihalides, RAsX2.- Organoarsenic oxygen, sulphur, and selenium compounds.- Oxygen derivatives of arsenic(V).- Tetraorgano hydroxides, R4AsOH.- Triorgano oxides, R3AsO.- Triorgano hydroxy-halides, R3As(OH)X.- Arsinic acids, R2AsO(OH).- Arsonic acids, RAsO(OH)2.- Sulphur and selenium derivatives of arsenic(V).- Derivatives of arsenic(III).- Arsonous acids, RAs(OH)2 and related derivatives.- Organoarsenic nitrogen compounds.- Derivatives of arsenic(V).- Derivatives of arsenic(III).- Organoarsenic hydrides.- Compounds containing arsenic-arsenic bonds.- Diarsines, R2AsAsR2.- Polyorganoarsines and related compounds.- Organoarsenic-metal compounds.- Alkali-metal derivatives.- Transition-metal derivatives.- 8 Antimony.- Tri-alkyls and tri-aryls of antimony.- Unsaturated organoantimony compounds.- Penta-alkyls and penta-aryls of antimony.- Ylides of antimony.- Organoantimony halogen compounds.- Derivatives of antimony(V).- Stibonium salts, R4SbX.- Dihalides, R3SbX2.- Trihalides, R2SbX3.- Tetrahalides, RSbX4.- Complexes of antimony(V) halides.- Derivatives of antimony(III).- Monohalides, R2SbX.- Dihalides, RSbX2.- Organoantimony oxygen, sulphur and selenium compounds.- Oxygen derivatives of antimony(V).- Tetraorgano hydroxides, R4SbOH, and alkoxy compounds, R5-xSb(OR)x.- Triorgano oxides, R3SbO.- Stibinic acids, R2SbO(OH).- Stibonic acids, RSbO(OH)2.- Sulphur and selenium derivatives of antimony(V).- Derivatives of antimony(III).- Organoantimony hydrides.- Compounds containing antimony-antimony bonds.- Organoantimony-metal compounds.- 9 Bismuth.- Tri-alkyls and tri-aryls of bismuth.- Unsaturated organobismuth compounds.- Penta-aryls of bismuth.- Organobismuth halogen derivatives.- Derivatives of bismuth(V).- Derivatives of bismuth(III).- Organobismuth-metal compounds.- References: Group V.