Low-Frequency Vibrations of Inorganic and Coordination Compounds

John R. Ferraro (Autor)

Buch | Softcover

310 Seiten

2012
Springer-Verlag New York Inc.
978-1-4684-1811-8 (ISBN)

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During the course of far-infrared investigations of inorganic and coordina tion compounds at Argonne National Laboratory in the years 1962-1966, it became apparent that no suitable book existed which correlated and dis cussed the important vibrations occurring in this region for these molecules. Early in 1967 the initial steps were taken to write such a book. Then, in 1968, an excellent text by Professor David M. Adams entitled Metal-Ligand and Related Vibrations was published. At this point serious consideration was given to discontinuing work on this book. However, upon examination of Adams' book, it became clear that the references covered only the period to 1966. This field of research is accelerating so tremendously, and the period 1966-1969 has seen so many new studies, that upon reconsideration it was decided to continue writing this text. The references in this book, particularly in the last several chapters, include many papers published in 1969. However, the proliferation of the far-infrared literature has made it impossible to present all the published material that has any bearing on the subject. Many titles do not pertain primarily to the far-infrared region as such, and some of this research has been omitted for this reason. Organometallic compounds have been neglected since the author feels that adequate reviews of that subject are available. Other studies may be missing simply because, owing to space limitations, only the more important researches could be considered. Of course, "importance" may, in this case, reflect the author's interest and prejudices.

1 Introduction.- 1.1. History.- 1.2. Usefulness of the Far-Infrared Region.- 1.3. Problems and Remedies.- 2 Far-Infrared Instrumentation.- 2.1. Introduction.- 2.2. Present Commercial Grating/Prism Instruments.- 2.3. Present Commercial Interferometric Instruments.- 2.4. Comparison of the Interferometer with the Conventional Spectrometer.- 2.5. Trends in Far-Infrared Instrumentation.- 3 Sampling Techniques and Instrument Calibration in the Far-Infrared Region.- 3.1. Introduction.- 3.2. Window Materials for Cells.- 3.3. Far-Infrared Solvents.- 3.4. Sampling Techniques.- 3.5. Calibration of Far-Infrared Instruments.- 4 New Techniques Used with Far-Infrared Measurements.- 4.1. Introduction.- 4.2. The Slow-Neutron Scattering (SNS) Technique.- 4.3. High-Pressure Techniques in the Far-Infrared Region.- 5 Metal-Oxygen Vibrations.- 5.1. Metal-Oxygen Vibrations in Hydrates.- 5.2. Metallic Oxides.- 5.3. Metal-Oxygen Vibrations in Hydroxyl-Bridged Complexes.- 5.4. Metal-Oxygen Vibrations in Salts Involving Oxygenated Polyatomic Anions.- 5.5. ?-Diketone Complexes.- 5.6. Complexes of Organic Acids.- 5.7. Complexes of Organic Oxide Ligands.- 5.8. Miscellaneous Complexes.- 5.9. Nature of the Metal-Oxygen Vibration.- 5.10. Raman Spectroscopic Studies.- 6 Metal-Halide Vibration.- 6.1. Introduction.- 6.2. Hepta- and Octacoordinated Molecules—MX7, MX8 (CN = 7, 8).- 6.3. Hexacoordinated Molecules—Oh Symmetry (CN = 6).- 6.4. Pentacoordinated Molecules—MX5, MX5n- (CN = 5).- 6.5. Tetracoordinated Molecules—MX4, MX4n- (CN = 4).- 6.6. Tricoordinated Molecules—MX3 (CN = 3).- 6.7. Dicoordinated Molecules—MX2 (CN = 2).- 6.8. MX-Type Metal Halides.- 6.9. Miscellaneous Metal Halide Vibrations.- 6.10. Complexes Involving Organic Ligands.- 6.11. Bridged Metal Halide Vibrations.- 6.12.Summary.- 7 Metal-Nitrogen Vibration.- 7.1. Introduction.- 7.2. Metal Ammine Complexes.- 7.3. Complexes of 2,2?-Bipyridyl, 2,2?,2?-Terpyridyl, 1,10-Phenanthroline, Aniline, and 8-Aminoquinoline.- 7.4. Metal-Imidazole Complexes and Complexes with Substituted Imidazoles.- 7.5. Metal-Pyridine and Related Complexes.- 7.6. Metal-Ethylenediamine and Related Complexes.- 7.7. Metal-Hydrazine Complexes.- 7.8. Metal Complexes Containing Nitrile Groups.- 7.9. Metal Isothiocyanate and Related Complexes.- 7.10. Metal-Amino Acid Complexes.- 7.11. Metal-Nitro Complexes.- 7.12. Metal-Azide Complexes.- 7.13. Metal-Nitrosyl Complexes.- 7.14. Summary.- 8 Miscellaneous Metal-Ligand Vibrations.- 8.1. Introduction.- 8.2. Metal-Sulfur Vibrations.- 8.3. Metal-Selenium Vibrations.- 8.4. Metal-Tellurium Vibrations.- 8.5. Metal-Phosphorus Vibrations.- 8.6. Metal-Arsenic Vibrations.- 8.7. Metal-Metal Vibrations.- 8.8. Summary of the ?MC and ?MCX Vibrations.- 9 Other Low-Frequency Vibrations.- 9.1. Ion-Pair Vibrations.- 9.2. Low-Frequency Vibrations of Molecules Trapped in Clathrates.- 9.3. Electronic Transitions.- 9.4. Lattice Vibrations.- 9.5. Miscellaneous Vibrations.- Appendixes.- Appendix 1. Selection Rules and Correlation Charts.- Site Symmetries for the 230 Space Groups.- Correlation Tables for the Species of a Group and Its Subgroups.- Appendix 2. Procedure Used for Factor Group Analysis of Solids.

Zusatzinfo	XIV, 310 p.
Verlagsort	New York, NY
Sprache	englisch
Maße	152 x 229 mm
Themenwelt	Sachbuch/Ratgeber ► Natur / Technik ► Garten
Themenwelt	Naturwissenschaften ► Chemie ► Anorganische Chemie
ISBN-10	1-4684-1811-4 / 1468418114
ISBN-13	978-1-4684-1811-8 / 9781468418118
Zustand	Neuware