Chemical Thermodynamics of Selenium (eBook)

Front Cover 1
Chemical Thermodynamics of selenium 4
Copyright Page 5
Contents 16
Preface 6
Acknowledgements 10
Note from the Chairman 12
Editor's Note 14
How to contact the NEA-TDB project 15
CHAPTER I. INTRODUCTION 46
I.1 Background 46
I.2 Focus of the review 47
I.3 Review procedure and results 49
CHAPTER II. STANDARDS, CONVENTIONS, AND CONTENTS OF THE TABLES 52
II.1 Symbols, terminology and nomenclature 52
II.2 Units and conversion factors 70
II.3 Standard and reference conditions 73
II.4 Fundamental physical constants 78
II.5 Uncertainty estimates 79
II.6 The NEA-TDB system 79
II.7 Presentation of the data 81
CHAPTER III. SELECTED SELENIUM DATA 84
CHAPTER IV. SELECTED AUXILIARY DATA 112
CHAPTER V. DISCUSSION OF DATA SELECTION FOR SELENIUM 132
V.1 Elemental selenium 132
V.2 Selenium oxides and hydrides 163
V.3 Selenium oxides and hydrides In aqueous solution. solid selenious acid and selenic acid 178
V.4 Group 17 compounds and complexes 205
V.5 Group 16 compounds and complexes 223
V.6 Group 15 compounds and complexes 231
V.7 Group 14 compounds and complexes 249
V.8 Group 13 compounds and complexes 271
V.9 Group 12 compounds and complexes 300
V.10 Group 11 compounds and complexes 333
V.11 Group 10 To group 3 compounds and complexes 355
V.12 Lanthanide compounds and complexes 402
V.13 Actinide compounds and complexes 429
V.14 Group 2 compounds and complexes 437
V.15 Ammonium and group 1 compounds and complexes 454
CHAPTER VI. DISCUSSION OF AUXILIARY DATA SELECTION 476
VI.1 Group 17 auxiliary species 476
VI.2 Group 14 auxiliary species 478
Appendices 482
APPENDIX A. DISCUSSION OF SELECTED REFERENCES 482
APPENDIX B. IONIC STRENGTH CORRECTIONS 632
B.1 The specific ion Interaction equations 634
B.2 Ion interaction coefficients versus equilibrium constants for ion pairs 646
APPENDIX C. ASSIGNED UNCERTAINTIES 660
C.1 The general problem 660
C.2 Uncertainty estimates in the selected thermodynaniic data 662
C.3 One source datum 663
C.4 Two or more independent source data 664
C.5 Several data at different ionic strengths 668
C.6 Procedures for data handling 672
APPENDIX D. SELENIUM MINERALS 678
APPENDIX E. ADDITIONAL VALUES OF THERMODYNAMIC PROPERTIES FOR SE COMPOUNDS 684
APPENDIX F. SOLUBILITY OF METAL SELENATES AND ALKALI METAL SELENITES IN WATER 694
BIBLIOGRAPHY 698
LIST OF AUTHORS 844