Advances in Organometallic Chemistry (eBook)

Cover 1
Contents 6
Contributors 10
Chapter 1. Element Derivatives of Sterically Encumbering Terphenyl Ligands 12
I. Introduction 12
II. Terphenyl Derivatives of s-Block Elements 17
III. Terphenyl Derivatives of d-Block and Group 12 Elements 26
IV. Terphenyl Derivatives of p-Block Elements 30
References 69
Chapter 2. Hydrogen Donor Abilities of the Group 14 Hydrides 78
I. Introduction 78
II. Bond Dissociation Energies and Kinetic Methods 79
III. Reactions of Radicals with Silicon Hydrides 84
IV. Reactions of Radicals with Germanium Hydrides 96
V. Reactions of Radicals with Tin Hydrides 101
VI. Kinetic Isotope Effects 114
VII. Comparisons of Reactivities of Group 14 Hydrides 115
VIII. Conclusion 117
References 120
Chapter 3. Doubly Bonded Derivatives of Germanium 124
I. Introduction 125
II. Germenes (> Ge=C<
III. Digermenes (> Ge=Ge<
IV. Germasilenes (> Ge=Si<
V. Stannagermene (> Sn=Ge<
VI. Germanimines (> Ge=N–)
VII. Germaphosphenes (> Ge=P–)
VIII. Germanones (> Ge=O)
IX. Germanethiones (> Ge=S), Germaneselones (>
X. Germaallenes (> Ge=C=X)
XI. Conclusion 179
References 180
Chapter 4. The Chemistry of Phosphinocarbenes 186
I. Introduction 186
II. Theoretical Studies 188
III. Synthesis 190
IV. Spectroscopic Data and X-Ray Analysis 195
V. Reactivity of Phosphinocarbenes R2P–C–X. 197
VI. Ligand Properties of Phosphinocarbenes 220
VII. Conclusion 226
References 227
Chapter 5. Zwitterionic Pentacoordinate Silicon Compounds 232
I. Introduction 232
II. Acyclic .5Si-Silicates with an SiF4C or SiF3C2 Skeleton 234
III. Spirocyclic 5Si-Silicates with an SiO4C Skeleton 239
IV. Spirocyclic .5Si-Silicates with an SiO2N2C Skeleton 267
V. Spirocyclic .5Si-Silicates with an SiO2S2C Skeleton 270
VI. Spirocyclic .5Si-Silicates with an SiO5 Skeleton. 272
VII. Monocyclic .5Si-Silicates with an SiO2FC2 Skeleton 276
VIII. Conclusions 281
References 282
Chapter 6. Transition Metal Complexes of Vinylketenes 286
I. Introduction 287
II. .4-(Vinylketene)Chromium(0) Complexes 289
III. .4-(Vinylketene)Molybdenum and Tungsten Complexes 298
IV. .4-(Vinylketene)Manganese(I) and .4-(Vinylketene)Vanadium(I) Complexes 307
V. .4-(Vinylketene)Cobalt(I) Complexes 309
VI. .4-(Vinylketene)Iron(0) Complexes 319
VII. Conclusion 361
References 362
Subject Index 368
Cumulative List of Contributors for Volumes 1–36 378