Advances in Heterocyclic Chemistry (eBook)

Cover 1
Advances in Heterocyclic Chemistry, Volume 66 4
Copyright Page 5
Contents 6
Contributors 8
Preface 10
Chapter 1. Recent Developments in Ring–Chain Tautomerism II. Intramolecular Reversible Addition Reactions to the C=N, C=N, C=C, and C=C Groups 12
I. Introduction 13
II. Intramolecular Reversible Addition Reactions to the C=N Group 13
III. Intramolecular Reversible Addition Reactions to Other Groups 65
IV. Conclusions and Prospects 71
References 74
Chapter 2. Palladium(0)-Catalyzed Allylation of Ambident Nucleophilic Aromatic Heterocycles 84
I. Introduction 85
II. Five-Membered Heterocyclic Rings 90
III. Six-Membered Heterocyclic Rings 107
IV. Imidazole Fused to a Second Heterocyclic Ring 128
References 138
Chapter 3. Chemistry of 1,3-Thiazin-4-ones and Their Derivatives 142
I. Introduction 143
II. Syntheses 144
III. Reactivity 179
IV. Applications 196
References 196
Chapter 4. Synthesis, Chemistry, and Biological Properties of Thienopyrimidines 204
I. Introduction 205
II. Thieno[2,3-d]pyrimidines 206
III. Thieno[3,2-d]pyrimidines 247
IV. Thieno[3,4-d]pyrimidines 266
References 284
Chapter 5. Tropones, Tropolones, and Tropylium Salts with Fused Heterocyclic Rings1 Part 2: Structure, Reactivity, and Application 296
III. Structure 297
IV. Reactivity 338
V. Applications 399
VI. Addendum to Part 1, Section II: Recent Synthetic Work 403
References 408