Mechanistic Bioinorganic Chemistry

Understanding the Mechanisms in Bioinorganic Chemistry ; Insights into the Role of Nickel in Hydrogenase ; Modeling Phenoxyl Radical Metalloenzyme Active Sites ; Reactivity Models for Dinuclear Iron Metalloenzymes: Oxygen Atom Transfer Catalysis and Dioxygen Activation ; Electronic Structures of Active Sites in Copper Proteins and Their Contributions to Reactivity ; Biomimetic Copper-Dioxygen Chemistry: Reversible O[2-Binding and Mechanistic Insights into Cu(I)/O[2-Mediated Arene Hydroxylation and Amide Hydrolysis ; Synthetic Modeling of the Interactions of Nitrogen Oxides with Copper Proteins: Copper Nitrosyl Complexes Relevant to Putative Denitrification Intermediates ; Structural Characterization of Manganese Redox Enzymes: Results from X-Ray Absorption Spectroscopy ; Structure and Function of Manganese in Photosystem II ; Reactivity and Mechanism of Manganese Enzymes: A Modeling Approach ; Application of NMR Spectroscopy to Studies of Aqueous Coordination Chemistry of Vanadium(V) Complexes ; Modeling Vanadium Bromoperoxidase: Oxidation of Halides by Peroxovanadium(V) Complexes ; Magnetic Circular Dichroism Spectroscopy as a Probe of the Active Site Structures of Iron Chlorin- and Formylporphyrin-Containing Green Heme Proteins ; Mechanistic Aspects of the Chemistry of Iron N-Alkyl Porphyrins ; Mechanisms of DNA Cleavage by High-Valent Metal Complexes ; Metal Ion Macrocyclic Complexes as Artificial Ribonucleases ; Metallointercalators as Probes of the DNA pi-way ; Donor-Acceptor Electronic Coupling in Rutheniuim-Modified Heme Proteins