Inorganic Syntheses

Fred Basolo was an American inorganic chemist. He received his Ph.D. at the University of Illinois at Urbana-Champaign in 1943, under Prof. John C. Bailar, Jr. Basolo spent his professional career at Northwestern University.

Preface.
Notice to Contributors.


Chapter One Metal Nitrosyl Complexes.


1 Tetranitrosylchromium and Carbonyltrinitrosylmanganese.


2 Dithiocarbamate Complexes of Iron and Cobalt Nitrosyls.


3 Ammine Complexes of Osmium, Including Amminenitrosyls.


4 Nitrosylammineruthenium Complexes.


5 Dinitrosylcobalt Complexes.


6 Bis(triphenylphosphine)chlorodinitrosylruthenium(1+)
Tetrafluoroborate.


7 Dicarbonyl-?-cyclopentadienylnitrosylmolybdenum
and Bis(dihalo-?- cyclopentadienylnitrosylmolybdenum)
Derivatives.


8 Bis(methyldiphenylphosphine)dichloronitrosylcobalt.


9 Tris(triphenylphosphine)nitrosylcobalt and
Tris(triphenylphosphine)nitrosylrhodium.


10 Carbonylchloronitrosylrhenium Compounds.


11 Decacarbonyldi-?-nitrosyl-trimetal Compounds.


12 trans-Bis(triphenylphosphine)chloronitrosyliridium(1+)
Tetrafluoroborate.


Chapter Two Metal Carbonyl Compounds.


13 Dodecacarbonyltriruthenium.


14 Dodecacarbonyltriruthenium.


15 Hexadecacarbonylhexarhodium.


16
Di-?-chloro-bis[tricarbonylchlororuthenium(II)].


17
Dicarbonyl(?-cyclopentadienyl)(thiocarbonyl)manganese(I).


18 Transition Metal Carbonyl Derivatives of Magnesium.


19 Tris(pentacarbonylmanganese)thalium(III).


20 (Alkylamino)difluorophosphine- and
Halodifluorophosphinetetracarbonyliron Complexes.


21 Tris[bis(2-methoxyethyl)ether]potassium and
Tetraphenylarsonium Hexacarbonylmetallates(1?) of Niobium and
Tantalum.


Chapter Three Werner Type Metal Complexes.


22 (Dinitrogen oxide)pentaammineruthenium(II) Salts.


23 Tetrakis(isothiocyanato)bis(2.2'-bipyridine)niobium(IV).


24 Malonato Complexes of Chromium(III).


25 Selenoureametal Complexes.


26 Nickel Tetrafluorooxovanadate(IV) Heptahydrate.


27 Polymeric Chromium(III)-bis(phosphinates).


28 Resolution of the
cis-Bromoamminebis(ethylenediamine)cobalt(III) Ion.


29 Bis(alkylphosphine)trichlorotitanium(III) Complexes.


Chapter Four Other Transition Metal Complexes.


30 Reagents for the Synthesis of ?-Diene Complexes
of Tricarbonyliron and Tricarbonylruthenium.


31 Bis(?)-cyclopentadienylniobium Complexes.


32 Dichloro(1,3-propanediyl)platinum and
trans-Dicholorobis(pyridine)(1,3-propane-diyl)platinum
Derivatives.


33 Olefin(?)silver(I) Compounds.


34 Trichloromethyltitanium and Tribromomethyltitanium.


35 Ethylenebis(triphenylphosphine)palladium(0) and Related
Complexes.


Chapter Five Main-Group and Actinide Compounds.


36 Tetraethylammonium, Tetraphenylarsonium, and Ammonium
Cyanates and Cyanides.


37 Diindenylmagnesium.


38 Fluoromethylsilanes.


39 Uranium Hexachloride.


40 Cholorotris(?-cyclopentadienyl) Complexes of
Uranium(IV) and Thorium(IV).


Chapter Six Ligands Used to Prepare Metal Complexes.


41 Trimethylphosphine.


42 Tertiary Phosphines.


43 Diphenylphosphine.


44 Tri(phenyl-d3)phosphine.


45 Methyl Difluorophosphite.


46 Bi-, Tri-, and Tetradentate Phosphorus-Sulfur Ligands.


47 Tetradentate Tripod Ligands Containing Nitrogen, Sulfur,
Phosphorus, and Arsenic as Donor Atoms.


48 Dimethyl(pentafluorophenyl)phosphine and
Dimethyl(pentafluorophenyl)arsine Ligands.


49 Tris(?-dimethylarsinophenyl)arsine and
Tris(?-dimethylarsinophenyl)stibine.


50 cis-2-Diphenylarsinovinyldiphenylphosphine and
2-Diphenylarsinoethyldiphenylphosphine.


51 [2-(Isopropylphenylphosphino)ethyl]diphenylphosphine.


52 [(Phenylisopropylphosphino)methyl]diphenylphosphine
Sulfide.


53
N,N,N',N'-Tetrakis(diphenylphosphinomethyl)ethylenediamine.


54 Ethylenebis(nitrilodimethylene)tetrakis(phenylphosphinic
acid).


55 [2-(Phenylphosphino)ethyl]diphenylphosphine.


56 1,1,1-Trifluoro-4-mercapto-4-(2-thienyl)-3-buten-2-one.


Chapter Seven Compounds of Biological Interest.


57 Metalloporphyrins.


58 (1,4,8,11-Tetraazacyclotetradecane)nickel(II) Perchlorate and
1,4,8,11-Tetraazacyclotetradecane.


59 N,N'-Ethylenebis(monothiacetylacetoniminato)cobalt(II)
and Related Metal Complexes.


60 Metallatranes.


61
cis-Bis(diethyldithiocarbamato)dinitrosylmolybdenum.


62 Some ?-Cyclopentadienyl Complexes of
Titanium(III).


Index of Contributors.


Subject Index.


Formula Index.