Electron Spin Resonance
Royal Society of Chemistry (Verlag)
978-0-85404-355-2 (ISBN)
Chapter 1: What is ESR Spectroscopy;
The ESR Experiment;
Sensitivity;
Saturation;
Nuclear Hyperfine Interaction;
Operation of an ESR Spectrometer;
Optimization of Operating Parameters;
Applications of ESR Spectroscopy;
Electronic Structure Determination;
Analytical Applications;Determination of Rates;References;
Chapter 2: Isotropic ESR Spectra;
Line Positions in Isotropic Spectra;Hyperfine Coupling Parameters;
Second-order Splittings;
Spin Hamiltonian Parameters from Spectra;
Interpretation of Isotropic Parameters;
Linewidths in Isotropic Spectra;
Incomplete Averaging of Anisotropies;
Rates of Fluxionality from Linewidths;
Organic Radical Reactions;
Analysis of Isotropic ESR Spectra;
Preliminary Examination of the Spectrum;
What do you expect to see?;
Are the Gross Features of the Spectrum Consistent with the Model?;
An Example;
Detailed Analysis for Determination of Parameters;
Computation of Multiplet Intensity Ratios;
Multiplet Patterns Due to Isotopomers;
Second-order Shifts in Line Positions;
Related Techniques (ENDOR);
References;
Chapter 3: Second-order Effects on Line Positions;
Understanding the Variation in Line Widths;
Puzzling Line Shapes;
Use of ESR Spectra to Determine Formation Constants;
References;
Chapter 4: Introduction: Solid-State ESR Spectra;
Spectra of Dilute Single Crystals;
Analysis of Frozen Solution Spectra;
Interpretation of the g-Matrix;
Interpretation of the Hyperfine Matrix;
Organometallic Examples;
A Low-spin Manganese(II) Complex;
Some Cobalt(0) Radical Anions;
Organic Examples of Solid-State ESR Spectra;
Irradiated Single Crystal Of Glycylglycine;
X-irradiated Single Crystal of Methylene Diphosphonic Acid;
Non-Coincident Matrix Axes;
Symmetry Considerations;
Experimental Determination of Matrix Axis Orientations;
Organometallic Examples of Non-Coincident Matrix Axes;
A Chromium Nitrosyl Complex;
Iron Pentacarbonyl Ions;
Another Low-Spin Manganese(II) Complex;
Chromium(I) Piano-Stool Complex;
[(RCCR')Co2(CO)6]- and [SFeCo2(CO)9]-;
(o-xylylene)-Mn(dmpe)2;
Cobalt Dithiolene Complexes;
"g-Strain";
References;
Chapter 5: Bloch's Phenomenological Model;
Derivation of the Bloch Equations;
Steady-State Solution;
Chemical Exchange-The Modified Bloch Equations;
Further Discussion of Line Shapes;
Applications of the Modified Bloch Equations;
Alternating Linewidth Effects;
Spin Labels;
References;
Chapter 6: Biradicals;
Exchange Coupling;
Organic Triplet-State Molecules and the Dipolar Interaction;
Organic Triplet-State Molecules;
Transition Metal Complexes with S>1/2;
Spin-Orbit Coupling;
High-Spin Transition Metal Ions;
Examples: K3Cr(CN)6 and K4V(CN)6;
References;
Chapter 7;
Second-order Perturbation Theory Treatment of Spin Hamiltonian with;
Non-Coincident g- and A-Axes;
The Electron Zeeman Term;
Nuclear Hyperfine Interaction;
Perturbation Theory Treatment of Hyperfine Term;Example of Application of These Results;
Quadrupole Coupling;
Perturbation Theory Treatment of Quadrupole Term;
Example of Application of Analysis of Quadrupole Effects;
References
Erscheint lt. Verlag | 30.7.2007 |
---|---|
Mitarbeit |
Sonstige Mitarbeit: Philip H Rieger Trust |
Verlagsort | Cambridge |
Sprache | englisch |
Maße | 156 x 234 mm |
Gewicht | 449 g |
Themenwelt | Naturwissenschaften ► Physik / Astronomie ► Elektrodynamik |
ISBN-10 | 0-85404-355-1 / 0854043551 |
ISBN-13 | 978-0-85404-355-2 / 9780854043552 |
Zustand | Neuware |
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