Mesoscopic Thermodynamics for Scientists and Engineers (eBook)
336 Seiten
Wiley (Verlag)
978-1-394-24196-5 (ISBN)
Provides comprehensive coverage of the fundamentals of mesoscopic thermodynamics
Mesoscopic Thermodynamics for Scientists and Engineers presents a unified conceptual approach to the core principles of equilibrium and nonequilibrium thermodynamics. Emphasizing the concept of universality at the mesoscale, this authoritative textbook provides the knowledge required for understanding and utilizing mesoscopic phenomena in a wide range of new and emerging technologies.
Divided into two parts, Mesoscopic Thermodynamics for Scientists and Engineers opens with a concise summary of classical thermodynamics and nonequilibrium thermodynamics, followed by a detailed description of fluctuations and local (spatially-dependent) properties. Part II presents a universal approach to specific meso-heterogeneous systems, illustrated by numerous examples from experimental and computational studies that align with contemporary research and engineering practice.
- Bridges the gap between conventional courses in thermodynamics and real-world practice
- Provides in-depth instruction on applying thermodynamics to current problems involving meso- and nano-heterogeneous systems
- Contains a wealth of examples of simple and complex fluids, polymers, liquid crystals, and supramolecular equilibrium and dissipative structures
- Includes practical exercises and references to textbooks, monographs, and journal articles in each chapter
Mesoscopic Thermodynamics for Scientists and Engineers is an excellent textbook for advanced undergraduate and graduate students in physics, chemistry, and chemical, mechanical, and materials science engineering, as well as an invaluable reference for engineers and researchers engaged in soft-condensed matter physics and chemistry, nanoscience and nanotechnology, and mechanical, chemical, and biomolecular engineering.
Mikhail A. Anisimov is a Distinguished University Professor Emeritus and Research Professor in the Department of Chemical and Biomolecular Engineering and the Institute for Physical Science and Technology at the University of Maryland, College Park. Dr. Anisimov is an internationally recognized scientist who has been investigating phase transitions and critical phenomena in soft condensed matter for more than fifty years. He is a Fellow of the American Physical Society, American Institute of Chemical Engineers, and American Association for the Advancement of Science.
Thomas J. Longo is a Research Engineer at Barron Associates, Inc., focusing on machine learning applications to science and engineering. Dr. Longo completed a PhD in Chemical Physics from the University of Maryland, College Park in 2023, where he still serves as an Adjunct Research Associate. His research interests include theoretical and computational studies of thermodynamics and dynamics of phase transitions affected by chemical reactions, liquid polyamorphism, and dissipative mesoscopic strictures.
Provides comprehensive coverage of the fundamentals of mesoscopic thermodynamics Mesoscopic Thermodynamics for Scientists and Engineers presents a unified conceptual approach to the core principles of equilibrium and nonequilibrium thermodynamics. Emphasizing the concept of universality at the mesoscale, this authoritative textbook provides the knowledge required for understanding and utilizing mesoscopic phenomena in a wide range of new and emerging technologies. Divided into two parts, Mesoscopic Thermodynamics for Scientists and Engineers opens with a concise summary of classical thermodynamics and nonequilibrium thermodynamics, followed by a detailed description of fluctuations and local (spatially-dependent) properties. Part II presents a universal approach to specific meso-heterogeneous systems, illustrated by numerous examples from experimental and computational studies that align with contemporary research and engineering practice. Bridges the gap between conventional courses in thermodynamics and real-world practiceProvides in-depth instruction on applying thermodynamics to current problems involving meso- and nano-heterogeneous systemsContains a wealth of examples of simple and complex fluids, polymers, liquid crystals, and supramolecular equilibrium and dissipative structuresIncludes practical exercises and references to textbooks, monographs, and journal articles in each chapter Mesoscopic Thermodynamics for Scientists and Engineers is an excellent textbook for advanced undergraduate and graduate students in physics, chemistry, and chemical, mechanical, and materials science engineering, as well as an invaluable reference for engineers and researchers engaged in soft-condensed matter physics and chemistry, nanoscience and nanotechnology, and mechanical, chemical, and biomolecular engineering.
Notations, Acronyms, and Units
General Notations
Symbols | Designates (units) |
---|
surface area () |
total Helmholtz energy () |
or | Helmholtz energy per mole or per molecule () |
, , , , , | asymptotic critical amplitudes of weak susceptibility, spontaneous order parameter, strong susceptibility, ordering field, correlation length, and surface tension, respectively |
and | van der Waals constants () and () |
, , , , | coefficients of the Landau expansion in the meanfield theory of phase transitions |
monomer random step (vector) |
second virial coefficient () |
mobility of a Brownian particle () |
molar concentration (); also, speed of light () |
gradient‐term coefficient in the Landau‐Ginzburg functional |
third virial coefficient () |
isobaric molar or molecular heat capacity () |
isochoric molar or molecular heat capacity () |
spatial correlation function |
temporal correlation function |
mutual diffusion coefficient in a binary solution () |
thermal diffusion coefficient () |
number of dimensions (dimensionality) of space |
total energy () |
kinetic energy () |
potential energy () |
force (vector) () |
total Gibbs energy () |
or | Gibbs energy per mole or per molecule () |
free‐fall acceleration () |
total enthalpy () |
or | enthalpy per mole or per molecule |
magnetic field (vector) () |
generalized field variable |
reduced (by ) Planck's constant |
mutual diffusion flux () |
heat flux () |
Krichevskiĭ parameter |
generalized Krichevskiĭ parameter |
reaction equilibrium constant |
Boltzmann's constant per molecule () |
baro‐diffusion ratio |
thermo‐diffusion ratio |
length () |
magnetization (vector) () |
molecular weight () |
mass () |
number of moles |
number of moles for species |
number of molecules |
Avogadro's number |
( molecules per mole) |
number of molecules for species |
degree of polymerization |
refractive index |
Ginzburg number |
pressure (; ; ) |
probability |
heat |
components of a tensor order parameter |
wave number (vector) |
gas constant |
radius of gyration |
hydrodynamic radius of a Brownian particle |
distance |
average intermolecular distance |
molecular radius |
total entropy |
or | entropy per mole or per molecule |
temperature |
time |
total Internal energy |
or | internal energy per mole or per molecule |
velocity (speed) |
thermodynamic speed of sound |
total volume |
(or ) | volume per mole or per molecule |
work |
probability density |
mole or molecular fraction of solute |
in a binary mixture |
mole or molecular fraction of species |
effective “activity” of species |
vertical coordinate |
molecular coordination number |
dynamic critical exponent |
Greek Notations
isobaric or volumetric expansivity |
Joule–Thompson coefficient () |
sound attenuation () |
, , , , , , | critical exponents of weak susceptibility, spontaneous order parameter, strong susceptibility, ordering field, correlation length, surface tension, and correlation function, respectively |
Onsager's molar transport coefficient |
Onsager's cross transport coefficient |
Onsager's heat transport coefficient |
activity coefficient of species |
Reaction kinetic coefficient |
Tolman's length |
dielectric constant |
energy of intermolecular interactions () |
bulk viscosity |
interfacial thickness ; also, extent of reaction |
dynamic shear viscosity |
scattering angle |
Theta (Flory) temperature |
thermal conductivity () |
isothermal compressibility |
osmotic compressibility |
wavelength ; also, a coupling constant |
sound wavelength () |
chemical potential of a pure substance , equal to the Gibbs energy per molecule in a single‐component system |
chemical potential along phase coexistence |
chemical potential in zero‐field ( for fluids for ) |
chemical potential of species |
exchange chemical potential |
correlation length of order‐parameter fluctuations |
de Gennes correlation length of polymer‐chain fluctuations |
osmotic pressure |
or | molecular or molar density |
partial molar density (molar concentration) |
of species |
density of Helmholtz energy |
density of entropy |
surface tension ;) |
relaxation time |
volume of a molecule |
volume fraction of species |
volume fraction of polymers in a polymer solution |
order parameter; generalized density |
spontaneous order parameter (in zero ordering field) |
Erscheint lt. Verlag | 2.7.2024 |
---|---|
Sprache | englisch |
Themenwelt | Naturwissenschaften ► Chemie |
ISBN-10 | 1-394-24196-8 / 1394241968 |
ISBN-13 | 978-1-394-24196-5 / 9781394241965 |
Informationen gemäß Produktsicherheitsverordnung (GPSR) | |
Haben Sie eine Frage zum Produkt? |
Größe: 34,4 MB
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