Mesoscopic Thermodynamics for Scientists and Engineers -  Mikhail A. Anisimov,  Thomas J. Longo

Mesoscopic Thermodynamics for Scientists and Engineers (eBook)

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2024 | 1. Auflage
336 Seiten
Wiley (Verlag)
978-1-394-24196-5 (ISBN)
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Provides comprehensive coverage of the fundamentals of mesoscopic thermodynamics

Mesoscopic Thermodynamics for Scientists and Engineers presents a unified conceptual approach to the core principles of equilibrium and nonequilibrium thermodynamics. Emphasizing the concept of universality at the mesoscale, this authoritative textbook provides the knowledge required for understanding and utilizing mesoscopic phenomena in a wide range of new and emerging technologies.

Divided into two parts, Mesoscopic Thermodynamics for Scientists and Engineers opens with a concise summary of classical thermodynamics and nonequilibrium thermodynamics, followed by a detailed description of fluctuations and local (spatially-dependent) properties. Part II presents a universal approach to specific meso-heterogeneous systems, illustrated by numerous examples from experimental and computational studies that align with contemporary research and engineering practice.

  • Bridges the gap between conventional courses in thermodynamics and real-world practice
  • Provides in-depth instruction on applying thermodynamics to current problems involving meso- and nano-heterogeneous systems
  • Contains a wealth of examples of simple and complex fluids, polymers, liquid crystals, and supramolecular equilibrium and dissipative structures
  • Includes practical exercises and references to textbooks, monographs, and journal articles in each chapter

Mesoscopic Thermodynamics for Scientists and Engineers is an excellent textbook for advanced undergraduate and graduate students in physics, chemistry, and chemical, mechanical, and materials science engineering, as well as an invaluable reference for engineers and researchers engaged in soft-condensed matter physics and chemistry, nanoscience and nanotechnology, and mechanical, chemical, and biomolecular engineering.

Mikhail A. Anisimov is a Distinguished University Professor Emeritus and Research Professor in the Department of Chemical and Biomolecular Engineering and the Institute for Physical Science and Technology at the University of Maryland, College Park. Dr. Anisimov is an internationally recognized scientist who has been investigating phase transitions and critical phenomena in soft condensed matter for more than fifty years. He is a Fellow of the American Physical Society, American Institute of Chemical Engineers, and American Association for the Advancement of Science.

Thomas J. Longo is a Research Engineer at Barron Associates, Inc., focusing on machine learning applications to science and engineering. Dr. Longo completed a PhD in Chemical Physics from the University of Maryland, College Park in 2023, where he still serves as an Adjunct Research Associate. His research interests include theoretical and computational studies of thermodynamics and dynamics of phase transitions affected by chemical reactions, liquid polyamorphism, and dissipative mesoscopic strictures.


Provides comprehensive coverage of the fundamentals of mesoscopic thermodynamics Mesoscopic Thermodynamics for Scientists and Engineers presents a unified conceptual approach to the core principles of equilibrium and nonequilibrium thermodynamics. Emphasizing the concept of universality at the mesoscale, this authoritative textbook provides the knowledge required for understanding and utilizing mesoscopic phenomena in a wide range of new and emerging technologies. Divided into two parts, Mesoscopic Thermodynamics for Scientists and Engineers opens with a concise summary of classical thermodynamics and nonequilibrium thermodynamics, followed by a detailed description of fluctuations and local (spatially-dependent) properties. Part II presents a universal approach to specific meso-heterogeneous systems, illustrated by numerous examples from experimental and computational studies that align with contemporary research and engineering practice. Bridges the gap between conventional courses in thermodynamics and real-world practiceProvides in-depth instruction on applying thermodynamics to current problems involving meso- and nano-heterogeneous systemsContains a wealth of examples of simple and complex fluids, polymers, liquid crystals, and supramolecular equilibrium and dissipative structuresIncludes practical exercises and references to textbooks, monographs, and journal articles in each chapter Mesoscopic Thermodynamics for Scientists and Engineers is an excellent textbook for advanced undergraduate and graduate students in physics, chemistry, and chemical, mechanical, and materials science engineering, as well as an invaluable reference for engineers and researchers engaged in soft-condensed matter physics and chemistry, nanoscience and nanotechnology, and mechanical, chemical, and biomolecular engineering.

Notations, Acronyms, and Units


General Notations


Symbols Designates (units)
surface area ()
total Helmholtz energy ()
or Helmholtz energy per mole or per molecule ()
, , , , , asymptotic critical amplitudes of weak susceptibility, spontaneous order parameter, strong susceptibility, ordering field, correlation length, and surface tension, respectively
and van der Waals constants () and ()
, , , , coefficients of the Landau expansion in the meanfield theory of phase transitions
monomer random step (vector)
second virial coefficient ()
mobility of a Brownian particle ()
molar concentration (); also, speed of light ()
gradient‐term coefficient in the Landau‐Ginzburg functional
third virial coefficient ()
isobaric molar or molecular heat capacity ()
isochoric molar or molecular heat capacity ()
spatial correlation function
temporal correlation function
mutual diffusion coefficient in a binary solution ()
thermal diffusion coefficient ()
number of dimensions (dimensionality) of space
total energy ()
kinetic energy ()
potential energy ()
force (vector) ()
total Gibbs energy ()
or Gibbs energy per mole or per molecule ()
free‐fall acceleration ()
total enthalpy ()
or enthalpy per mole or per molecule
magnetic field (vector) ()
generalized field variable
reduced (by ) Planck's constant
mutual diffusion flux ()
heat flux ()
Krichevskiĭ parameter
generalized Krichevskiĭ parameter
reaction equilibrium constant
Boltzmann's constant per molecule ()
baro‐diffusion ratio
thermo‐diffusion ratio
length ()
magnetization (vector) ()
molecular weight ()
mass ()
number of moles
number of moles for species
number of molecules
Avogadro's number
( molecules per mole)
number of molecules for species
degree of polymerization
refractive index
Ginzburg number
pressure (; ; )
probability
heat
components of a tensor order parameter
wave number (vector)
gas constant
radius of gyration
hydrodynamic radius of a Brownian particle
distance
average intermolecular distance
molecular radius
total entropy
or entropy per mole or per molecule
temperature
time
total Internal energy
or internal energy per mole or per molecule
velocity (speed)
thermodynamic speed of sound
total volume
(or ) volume per mole or per molecule
work
probability density
mole or molecular fraction of solute
in a binary mixture
mole or molecular fraction of species
effective “activity” of species
vertical coordinate
molecular coordination number
dynamic critical exponent

Greek Notations


isobaric or volumetric expansivity
Joule–Thompson coefficient ()
sound attenuation ()
, , , , , , critical exponents of weak susceptibility, spontaneous order parameter, strong susceptibility, ordering field, correlation length, surface tension, and correlation function, respectively
Onsager's molar transport coefficient
Onsager's cross transport coefficient
Onsager's heat transport coefficient
activity coefficient of species
Reaction kinetic coefficient
Tolman's length
dielectric constant
energy of intermolecular interactions ()
bulk viscosity
interfacial thickness ; also, extent of reaction
dynamic shear viscosity
scattering angle
Theta (Flory) temperature
thermal conductivity ()
isothermal compressibility
osmotic compressibility
wavelength ; also, a coupling constant
sound wavelength ()
chemical potential of a pure substance , equal to the Gibbs energy per molecule in a single‐component system
chemical potential along phase coexistence
chemical potential in zero‐field ( for fluids for )
chemical potential of species
exchange chemical potential
correlation length of order‐parameter fluctuations
de Gennes correlation length of polymer‐chain fluctuations
osmotic pressure
or molecular or molar density
partial molar density (molar concentration)
of species
density of Helmholtz energy
density of entropy
surface tension ;)
relaxation time
volume of a molecule
volume fraction of species
volume fraction of polymers in a polymer solution
order parameter; generalized density
...
spontaneous order parameter (in zero ordering field)

Erscheint lt. Verlag 2.7.2024
Sprache englisch
Themenwelt Naturwissenschaften Chemie
ISBN-10 1-394-24196-8 / 1394241968
ISBN-13 978-1-394-24196-5 / 9781394241965
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