Novel Anti-Corrosion and Anti-Fouling Coatings and Thin Films

Hari Murthy, PhD., finished his Ph.D. on novel anticorrosion materials at the University of Canterbury, New Zealand. He is an assistant professor in the Department of Electronics and Communication Engineering, CHRIST (Deemed to be University), Bangalore, India. His research interests include data engineering and material science. He has served as part of the program committee for several international conferences organized by the university. Vinay Jha Pillai, PhD., is an assistant professor in the Department of Electronics and Communication Engineering, CHRIST (Deemed to be University), Kengeri Campus, Bangalore, India. His primary research is in the early detection of breast cancer using optical imaging and holds two patents related in the subject. He is also exploring the domain of sensors for extracting coating parameters, especially for thermal barrier coatings which have a wide application in the field of corrosion and biofouling inhibitors. Kukatlapalli Pradeep Kumar, PhD., at an associate professor and data science program coordinator at Christ University, Bangalore, India. One of his research areas is in the field of data science for corrosion engineering where novel methods for corrosion inhibition based on data science techniques for correlating simulation predictions and molecular structures are in high demand. Matthew Cowan, PhD., is a faculty member in the Department of Chemical and Processing Engineering at the University of Canterbury, New Zealand. As a materials chemist, his main research interests are in the application of ionic liquids and ionic polymers for anti-fouling applications as well as efficient process designs for industrial gas separations. He is the author of more than 30 publications.

Preface xvii

Acknowledgements xix

1 Antifouling Nanoparticle Coatings for Post-Harvest Food Preservation 1
Gokuraju Thriveni, Hari Murthy and CH. Anusha

1.1 Introduction 2

1.2 Materials Support Post-Harvest 2

1.3 Computational Methods to Envision the Interaction of Food Residuals with Coated Nanolayers Through Sensing 5

1.4 Feasible Research Implications to Address the Shortcomings in Food Preservation 7

2 Toward Stable Electrochemical Water Splitting: Anticorrosive Properties of Transition Metal–Based Electrocatalytic Coatings 13
Kaushal Gavankar, Suchitra Sapakal and Anamika V. Kadam

2.1 Introduction 14

2.2 Corrosion Mechanisms 16

2.3 Methods to Prevent Corrosion 20

2.4 Anticorrosive Catalytic Coating 23

2.5 Carbon-Based Anticorrosive Catalytic Coatings 30

2.6 Discussion 31

2.7 Conclusion 34

3 Ionic Liquids in Marine Anti-Fouling Coatings 43
Samantha Taylor, Sajith K. Baiju, Madison K. McQuinlan and Matthew G. Cowan

3.1 Introduction 44

3.2 Current Anti-Fouling Design Strategies 50

3.3 Poly(Ionic Liquids) as Anti-Fouling Coatings 58

4 Inorganic Nanomaterial Coating to Prevent Biofouling 77
Anju T. R., Mariat George and Rose Mary Jose

4.1 Introduction 78

4.2 Major Industries Affected by Biofouling 80

4.3 Conventional Antifouling Coatings and their Demerits 81

4.4 Nanomaterials as Antifoulants: Properties and Mechanisms 83

4.5 Types of Nanomaterials Used as Antifoulants 85

4.6 Inorganic Nanomaterials as Antifoulant 85

4.7 Impact and Challenges of Inorganic Nanomaterials as Antifoulants 101

4.8 Conclusion 101

5 Thin Film Transparent Conducting Oxides and its Anticorrosion and Surface Protection Applications: A Review 109
Balaprakash V., Thangavel K., Mahitha Mohan, Gowrisankar P. and Sakthivel R.

5.1 About Transparent Conducting Oxides 110

5.2 Electrical Properties of TCOs 110

5.3 Optical Properties of TCO 112

5.4 Need of TCO for Solar Cells and Optoelectronic Devices 115

5.5 Requirements of TCO 116

5.6 Commonly Used TCO Materials 116

5.7 Application of TCOs 117

5.8 Anti-Corrosion and Surface Protection Application of Doped Zinc Oxide–Based TCO Materials 117

5.9 NZO Coating Over Stainless Steel 118

5.10 Conclusion 124

6 Integrated Anticorrosion and Antifouling Coatings 129
Ankita Kumari, Nirmala Kumari Jangid, Sudesh Kumar, Rekha Sharma and Navjeet Kaur

6.1 Introduction 130

6.2 Mechanisms of Corrosion and Biofouling 131

6.3 Recent Developments in Integrated Anticorrosion Coatings and Antifouling Coatings 133

6.4 PNCs Nanocoatings (Polymer Nanocomposites Coatings) 138

6.5 Marine Environment Durability Test of IAACs 140

6.6 Evaluation of Various IAACs and Difficulties 140

6.7 Conclusion and Outlook 141

7 EIS Study of Anticorrosive Nanocomposite Films 155
Vandana Shinde

7.1 Importance of Organic-Inorganic Nanocomposite Coatings 156

7.2 EIS: Brief Basic Principle and Introductions 160

7.3 EIS Data Analysis: Fitting the Equivalent Electronic Circuit, Introduction of the Various Circuit Parameters Its Physics 176

7.4 EIS in Anticorrosive Modern Nanocomposite Coatings and Assessment of Corrosion Protection Performance 198

7.5 Conclusions 202

8 Graphene-Based Coating on Mild Steel for Improving Anticorrosion and Microhardness Behavior: A Review 211
Sunita Dhar, Tapan Dash, Ashok Kumar Sahu, Sushree Subhadarshinee Mohapatra, Nibedita Mohanty, Shubhra Bajpai, Tapan Kumar Rout and Surendra Kumar Biswal

8.1 Introduction of Graphene 212

8.2 Synthesis Mechanism of Graphene Derivatives 215

8.3 Typical Characterizations of Graphene Derivatives 217

8.4 Anticorrosion Mechanisms of Graphene Derivatives and Their Composites 224

8.5 Anticorrosion Behavior of Graphene Derivative Coating on Mild Steel 229

8.6 Microhardness Behavior of Graphene Derivative Coating on Mild Steel 236

8.7 Conclusions 237

9 Bioinspired Strategies for Corrosion Protection and Antifouling Coatings 251
K. R. C. Soma Raju, Aarti Gautam, Ramay Patra, K. Srinivasa Rao, K.V. Gobi and R. Subasri

9.1 Introduction 252

9.2 Conclusions 278

10 Implementation of Nanotechnology in Anticorrosion Material Development for Food Packaging 287
Aparna Ray Sarkar, Dwaipayan Sen and Pramita Sen

10.1 Introduction 288

10.2 Synthesis of Nanoclay-Based Composites for Food Packaging 288

10.3 Metal Nanoparticle-Based Composites 294

10.4 Synthesis of Biopolymer-Based Packaging Material 296

10.5 Structural Features of Different Nanocomposites 298

10.6 Application of Different Nanomaterials in Canned Food Packaging 307

10.7 Concluding Remark 314

11 Development and Characterization of Nanostructured Thin Films for Corrosion Control Applications 323
M. Geetha Devi, R. Senthilkumar and Hebatallah Al Jabri

11.1 Introduction 324

11.2 Various Forms of Corrosion in the Petroleum Industry 326

11.3 Corrosion’s Effects on Various Equipment Used in the Petrochemical Industry 329

11.4 Conventional Corrosion Control Techniques 333

11.5 The Role of Nanotechnology in Corrosion Control 337

11.6 Application of Nanocomposite Thin Films in Corrosion Control 340

11.7 Results and Discussion 342

11.8 Conclusion 346

11.9 Future Scope 346

11.10 Challenges 347

12 Anticorrosion and Antifouling Coating Materials 353
N. Haridharan and R. V. Shiva Kumar

12.1 Introduction 354

12.2 Key Issues in the Formulation of Anticorrosive Materials 366

12.3 Formulating a Good Model for Leaching 375

12.4 The Advent of Nanotechnology 390

12.5 Summary of the Current Developments 393

12.6 Conclusion 396

13 Metal(II) Complexes as Potential Anticorrosion and Antifouling Agents—A Review 399
Asha M. S., Zabiulla, Othbert Pinto, Arjun S. R., Alen Eldose and Sangamesha M. A.

13.1 Introduction 400

13.2 Outline and Mechanism of Metal(II) Complexes as Corrosion Inhibitors 401

13.3 Outline of Metal Complexes as Antifouling Agents 409

13.4 Conclusion 415

14 Thermodynamic Modeling of Carbonaceous Coating of Oxides and Sulfides Thin Films Grown by CVD for Enhancing Surface Quality 425
Kranthi Kumar Vaidyula, Sukanya Dhar, Anjali Lalithambika and S. A. Shivashankar

14.1 Introduction 426

14.2 Experimental 426

14.3 Results and Discussion 428

14.4 Conclusions 432

15 Metal Nanoparticles: Biosynthesis Approach and Bio-Packaging Application 435
Priti Chaware, Amol Nande, J. D. Punde, K. G. Rewatkar and S. J. Dhoble

15.1 Introduction 436

15.2 Synthesis of NPs 438

15.3 Characterization of Nanoparticles 441

15.4 Concluding Remarks 449

16 Statistical Data Analysis of Anticorrosion and Antifouling: Unveiling Insights from Performance and Trends 459
Preetham Noel P., Kukatlapalli Pradeep Kumar, Mani Joseph P. and Vinay Jha Pillai

16.1 Introduction 460

16.2 Literature 460

16.3 Results and Discussion 466

16.4 Conclusion 471

17 Comprehensive Data Analysis of Anticorrosion, Antifouling Agents, and the Efficiency of Corrosion Inhibitors in CO2 Pipelines 475
Vineeth Simhadri, Kukatlapalli Pradeep Kumar, Vijaya P. and Vinai George Biju

17.1 Introduction 476

17.2 Literature Review 477

17.3 Results and Discussion 486

17.4 Conclusion 494

References 495

Index 497