50th Anniversary of Electron Counting Paradigms for Polyhedral Molecules -

50th Anniversary of Electron Counting Paradigms for Polyhedral Molecules

Historical and Recent Developments

D. Michael P. Mingos (Herausgeber)

Buch | Softcover
IX, 247 Seiten
2022 | 1st ed. 2021
Springer International Publishing (Verlag)
978-3-030-84865-1 (ISBN)
320,99 inkl. MwSt

The 50 Year Anniversary of the development of electron counting paradigms for polyhedral molecules is celebrated in two volumes of Structure and Bonding.  Volume 1 covers the historical development, theoretical models and applications to boranes and metalloboranes.


lt;b>Michael Mingos was born in Basra, Iraq in 1944 and was educated in England (Manchester, B.Sc. in Chemistry 1965) and University of Sussex (D.Phil, 1968). He has held academic posts at QMC, Oxford (Keble College), Imperial College, St Edmund Hall (Principal,1999-2009). His theoretical research has resulted in generalisations which have greatly influenced the development and teaching of modern inorganic chemistry. Specifically the Wade-Mingos Rules which rationalise the structures of polyhedral inorganic molecules and the Green-Davies-Mingos Rules, which account for some of the nucleophilic reactions of organometallic compounds. His group has experimentally verified some of his theoretical predictions, for example an icosahedral molecule containing gold atoms -which is relevant for understanding the metal's nano-technological possibilities. He has also contributed to the understanding of the bonding properties of nitric oxide, an important cellular signalling molecule involved in many physiological processes and pioneered the acceleration of chemical reactions using microwave energy. He was elected the Royal Society in 1992 and the European Academy of Sciences in 2017. He holds honorary doctorates from Sussex and Manchester Universities and received many prizes - the most recent was the Blaise Pascal Medal in 2017.

Historical introduction to Polyhedral Bonding Models leading to Professor Ken Wade's Contribution.- Introduction to Tensor Surface Harmonic Theory.- Polyhedra beyond the icosahedron.- Non-sphericity in metalloboranes.- Bis(carboranes) and Related Species.- Borane and carborane clusters meet coordination polymers and networks: In the hole or in the backbone?

Erscheinungsdatum
Reihe/Serie Structure and Bonding
Zusatzinfo IX, 247 p.
Verlagsort Cham
Sprache englisch
Maße 155 x 235 mm
Gewicht 400 g
Themenwelt Naturwissenschaften Chemie Anorganische Chemie
Naturwissenschaften Chemie Physikalische Chemie
Naturwissenschaften Physik / Astronomie Atom- / Kern- / Molekularphysik
Schlagworte Bis(carboranes) • Electron Transfer • Fullerenes • Metalloboranes • Polyhedral Bonding Models • Wade Clusters • Wade-Mingos rules • Zintl Clusters
ISBN-10 3-030-84865-5 / 3030848655
ISBN-13 978-3-030-84865-1 / 9783030848651
Zustand Neuware
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