Mass Spectrometry Imaging in Food Analysis

Leo M. L. Nollet earned an MS (1973) and PhD (1978) in biology from the Katholieke Universiteit Leuven, Belgium. He is an editor and associate editor of numerous books. He edited for M. Dekker, New York—now CRC Press of Taylor & Francis Publishing Group—the first, second, and third editions of Food Analysis by HPLC and Handbook of Food Analysis. The last edition is a two-volume book. Dr. Nollet also edited the Handbook of Water Analysis (first, second, and third editions) and Chromatographic Analysis of the Environment, third and fourth editions (CRC Press). With F. Toldrá, he coedited two books published in 2006, 2007, and 2017: Advanced Technologies for Meat Processing (CRC Press) and Advances in Food Diagnostics (Blackwell Publishing— now Wiley). With M. Poschl, he coedited the book Radionuclide Concentrations in Foods and the Environment, also published in 2006 (CRC Press). Dr. Nollet has also coedited with Y. H. Hui and other colleagues on several books: Handbook of Food Product Manufacturing (Wiley, 2007), Handbook of Food Science, Technology, and Engineering (CRC Press, 2005), Food Biochemistry and Food Processing (first and second editions; Blackwell Publishing—now Wiley—2006 and 2012), and the Handbook of Fruits and Vegetable Flavors (Wiley, 2010). In addition, he edited the Handbook of Meat, Poultry, and Seafood Quality, first and second editions (Blackwell Publishing—now Wiley—2007 and 2012). From 2008 to 2011, he published five volumes on animal product-related books with F. Toldrá: Handbook of Muscle Foods Analysis, Handbook of Processed Meats and Poultry Analysis, Handbook of Seafood and Seafood Products Analysis, Handbook of Dairy Foods Analysis, and Handbook of Analysis of Edible Animal By-Products. Also, in 2011, with F. Toldrá, he coedited two volumes for CRC Press: Safety Analysis of Foods of Animal Origin and Sensory Analysis of Foods of Animal Origin. In 2012, they published the Handbook of Analysis of Active Compounds in Functional Foods. In a collaboration with Hamir Rathore, Handbook of Pesticides: Methods of Pesticides Residues Analysis was marketed in 2009; Pesticides: Evaluation of Environmental Pollution in 2012; Biopesticides Handbook in 2015; and Green Pesticides Handbook: Essential Oils for Pest Control in 2017. Other finished book projects include Food Allergens: Analysis, Instrumentation, and Methods (with A. van Hengel; CRC Press, 2011) and Analysis of Endocrine Compounds in Food (Wiley-Blackwell, 2011). Dr. Nollet’s recent projects include Proteomics in Foods with F. Toldrá (Springer, 2013) and Transformation Products of Emerging Contaminants in the Environment: Analysis, Processes, Occurrence, Effects, and Risks with D. Lambropoulou (Wiley, 2014). In the series Food Analysis & Properties, he edited (with C. Ruiz-Capillas) Flow Injection Analysis of Food Additives (CRC Press, 2015) and Marine Microorganisms: Extraction and Analysis of Bioactive Compounds (CRC Press, 2016). With A.S. Franca, he coedited Spectroscopic Methods in Food Analysis (CRC Press, 2017), and with Horacio Heinzen and Amadeo R. Fernandez-Alba he coedited Multiresidue Methods for the Analysis of Pesticide Residues in Food (CRC Press, 2017). Further volumes in the series Food Analysis & Properties are Phenolic Compounds in Food: Characterization and Analysis (with Janet Alejandra Gutierrez-Uribe, 2018), Testing and Analysis of GMO-Containing Foods and Feed (with Salah E. O. Mahgoub, 2018), Fingerprinting Techniques in Food Authentication and Traceability (with K. S. Siddiqi, 2018), Hyperspectral Imaging Analysis and Applications for Food Quality (with N.C. Basantia and Mohammed Kamruzzaman, 2018), Ambient Mass Spectroscopy Techniques in Food and the Environment (with Basil K. Munjanja, 2019), and Food Aroma Evolution: During Food Processing, Cooking, and Aging (with M. Bordiga, 2019).

Contents

Series Preface vii

About the Editor ix

List of Contributors xi

Introduction xiii

SECTION 1 MASS SPECTROMETRY IMAGING

Chapter 1 Mass Spectrometry Imaging 3

Leo M.L. Nollet

Chapter 2 Imaging Mass Spectrometry for Small Molecules 13

Fangbiao Li

SECTION 2 DIFFERENT METHODOLOGIES

Chapter 3 Matrix-Assisted Laser Desorption Ionization (MALDI)

and Atmospheric Pressure-MALDI (AP-MALDI) 37

Nrusingha Charan Basantia

Chapter 4 MALDI IMS for Proteins and Biomarkers 51

Michelle L. Reyzer and Richard M. Caprioli

Chapter 5 Secondary-Ion Mass Spectrometry 73

Leo M.L. Nollet

Chapter 6 Desorption Electrospray Ionization Mass Spectrometry

Imaging in Food Applications 81

Semih Ötleş and Vasfiye Hazal Özyurt

Chapter 7 Liquid Extraction Surface Analysis 91

Leo M.L. Nollet

Chapter 8 Laser Ablation Inductively Coupled Plasma Mass

Spectrometry 95

Leo M.L. Nollet

Chapter 9 Different Mass Spectrometry Imaging Methods 103

Sadaf Jamal Gilani, Chandrakala, and Md. Taleu Zzaman

SECTION 3 AMBIENT MASS SPECTROMETRY TECHNIQUES

Chapter 10 Introduction to Ambient Mass Spectrometry Techniques 119

Raquel Sero, Maria Teresa Galceran, Encarnacion Moyano, and

Leo M.L. Nollet

Chapter 11 Use of an “Intelligent Knife” (iknife), Based on the Rapid

Evaporative Ionization Mass Spectrometry Technology, for

Authenticity Assessment of Pistachio Samples 159

Francesca Rigano, Sara Stead, Domenica Mangraviti, Renata

Jandova, Davy Petit, Nino Marino, and Luigi Mondello

SECTION 4 DATA HANDLING

Chapter 12 Comparison of Machine Learning Algorithms for Predictive

Modeling of Beef Attributes Using Rapid Evaporative

Ionization Mass Spectrometry (REIMS) Data 181

Devin A. Gredell, Amelia R. Schroeder, Keith E. Belk, Corey D.

Broeckling, Adam L. Heuberger, Soo-Young Kim, D. Andy King,

Steven D. Shackelford, Julia L. Sharp, Tommy L. Wheeler, Dale R.

Woerner, and Jessica E. Prenni

Index 195