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Transition Metal Organometallics in Organic Synthesis
Pergamon (Verlag)
978-0-08-042319-7 (ISBN)
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This is a completely new volume, which comprehensively treats the use of transition metals in organic synthesis, with real emphasis on synthetically useful transformations on highly functionalized substrates. It is complete through to mid-1993 and each section has been written by an author who was responsible for the development of the chemistry involved.
Introduction and Fundamentals (L.S. Hegedus). Transition Metal Hydrides: Hydrocarboxylation, Hydroformylation and Asymmetric Hydrogenation (I. Ojima, E. Eguchi, M. Tzarmarioudaki). Transition Metal Alkyl Complexes from Hydrometallation (J.M. Takacs). Transition Metal Alkyl Complexes from RLi and MX (B.H. Lipshutz). Transition Metal Alkyl Complexes: Main-group Transmetallation and Insertion Chemistry (W. Leong, R.C. Larock). Transition Metal Alkyl Complexes: Oxidative Addition and Transmetallation (V. Farina). Transition Metal Alkyl Complexes: Oxidative Addition and Insertion (B. Soderberg). Transition Metal Alkyl Complexes: Multiple Insertion Cascades (R. Grigg, V. Sridharan). Transition Metal Alkyl Complexes: Reductive Dimerization of Alkenes and Alkynes (R.D. Broene, S. Buchwald). Transition Metal Carbonyl Complexes (R. Bates). Transition Metal Carbene Complexes: Cyclopropanation (M.P. Doyle). Transition Metal Carbene Complexes: Diazodecomposition, Ylide and Insertion (M.P. Doyle). Transition Metal Carbene Complexes: Alkyne and Vinyl Ketene Chemistry (W.D. Wulff). Transition Metal Carbene Complexes: Photochemical Reactions of Carbene Complexes (L.S. Hegedus). Transition Metal Carbene Complexes: Tebbe's Reagent and Related Nucleophilic Carbenes (J.R. Stille). Transition Metal Alkene, Diene and Dienyl Complexes: Nucleophilic Attack on Alkene Complexes (K.F. McDaniel). Transition Metal Alkene, Diene and Dienyl Complexes: Complexation of Dienes for Protection (W.A. Donaldson). Transition Metal Alkene, Diene and Dienyl Complexes: Nucleophilic Attack on Diene and Dienyl Complexes (A.J. Pearson). Transition Metal Alkyne Complexes: Transition Metal Stabilized Propargyl Systems (J.M. Caffyn, K. Nicholas). Transition Metal Alkyne Complexes: Pauson--Khand Reaction (N.E. Schore). Transition Metal Alkyne Complexes: Transition Metal Catalyzed Cyclotrimerization (D.B. Grotjahn). Transition Metal Alkyne Complexes: Zirconium--Benzyne Complexes (S. Buchwald, R.D. Broene). Transition Metal Allyl Complexes: Telomerization of Dienes (J.M. Takacs). Transition Metal Allyl Complexes: Pd, W, Mo, Fe-assisted Nucleophilic Attack (P.J. Harrington). Transition Metal Allyl Complexes: Allylic Cyclizations via Multiple Insertions (W. Oppolzer). Transition Metal Allyl Complexes: Trimethylene Methane Complexes (P.J. Harrington). Transition Metal Allyl Complexes: &Sgr;3 Allylnickel Halides and Other Allyl Complexes Excluding Palladium (D. Krysan). Transition Metal Arene Complexes: Nucleophilic Addition (M.F. Semmelhack). Transition Metal Arene Complexes: Ring Lithiation (M.F. Semmelhack). Transition Metal Arene Complexes: Side-chain Activation and Control of Stereochemistry (S.G. Davies, T.D. McCarthy). Synthetically Useful Coupling Reactions Promoted by Titanium, Vanadium, Niobium, Tungsten and Molybdenum Reagents (R.G. Dushin). Transition Metal Catalyzed Oxidations: Asymmetric Epoxidation (E.N. Jacobsen). Transition Metal Catalyzed Oxidations: Asymmetric Hydroxylation (I.E. Marko, J.S. Svendsen). Transition Metal Catalyzed Oxidations: Other Oxidations (S-I. Murahashi, T. Naota). Transition Metals in Polymer Synthesis: Ziegler--Natta Reaction (R. Waymouth, G.W. Coates). Transition Metals in Polymer Synthesis: Ring-opening Metathesis Polymerization and Other Transition Metal Polymerization Techniques (J. Moore).
Erscheint lt. Verlag | 10.9.2002 |
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Reihe/Serie | Comprehensive Organometallic Chemistry II S. |
Verlagsort | Amsterdam |
Sprache | englisch |
Themenwelt | Naturwissenschaften ► Chemie ► Anorganische Chemie |
Naturwissenschaften ► Chemie ► Organische Chemie | |
ISBN-10 | 0-08-042319-1 / 0080423191 |
ISBN-13 | 978-0-08-042319-7 / 9780080423197 |
Zustand | Neuware |
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