Synthesis, Characterization and Reactivity of Ylidyne and μ-Ylido Complexes Supported by Scorpionato Ligands
Springer International Publishing (Verlag)
978-3-030-02624-0 (ISBN)
In this book, readers will find more about the synthesis, full characterization and reactivity studies of these novel complexes that uncovered a plethora of exceptional products, including a novel m3-silicido complex, the first dimetallasilacumulene with a linear, two-coordinated single silicon atom and the first compounds of planar tetracoordinated silicon (ptSi) (Anti-van't Hoff-Le Bell Silicon). Readers will also learn about the isolation and full characterization of the first room-temperature stable disilavinylidene, a silicon analogue of the very reactive vinylidenes (R2C=C:), and the first intermetallic plumbylidyne ligand transfer reactions.
Dr. Priyabrata Ghana obtained his Bachelor of Science (B.Sc.) degree in chemistry from Ramakrishna Mission Residential College, Narendrapur, University of Calcutta, India, in 2009. This was followed by his Master of Science (M.Sc.) degree from the Indian Institute of Technology, Kanpur (IITK) in 2011. After completing his M.Sc., he moved to Germany and joined the group of Prof. Alexander C. Filippou at the Rheinische Friedrich-Wilhelms-Universität Bonn for his doctoral studies. Currently, he is a postdoctoral fellow in the group of Prof. Jun Okuda at the RWTH Aachen.
Introduction.- Closed shell heavier tetrylidyne complexes of group 6 metals.- Open-shell heavier tetrylidyne complexes of group 6 transition metals.- Germylidyne mediated C-C coupling reaction of isonitriles - formation of an N-heterocyclic germylene.- A new method for the synthesis of manganese tetrylidyne complexes.- An open-shell manganese stannylidyne comprising of a tin-centered unpaired electron.- µ-Ylido complexes.- Chemistry of the metallatetrylidyne complexes.- Plumbylidyne transfer reaction.- Access to the first NHC-stabilized disilavinylidene.- Summary and Outlook.- Experimental Section.
Erscheinungsdatum | 02.02.2019 |
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Reihe/Serie | Springer Theses |
Zusatzinfo | XXII, 344 p. 162 illus., 26 illus. in color. |
Verlagsort | Cham |
Sprache | englisch |
Maße | 155 x 235 mm |
Gewicht | 713 g |
Themenwelt | Naturwissenschaften ► Chemie ► Analytische Chemie |
Naturwissenschaften ► Chemie ► Anorganische Chemie | |
Naturwissenschaften ► Chemie ► Organische Chemie | |
Schlagworte | Heavier Analogue of Alkylidyne Complexes • Heavier Analogue of Metallacarbyne Complexes • Heavy tetrel elements (Si-Pb) • NHC-Stabilized Disilavinylidene • Open-Shell Tetrylidyne Complexes • Planar Tetracoordinated Silicon (ptSi) • Plumbylidyne Transfer Reaction • transition metals |
ISBN-10 | 3-030-02624-8 / 3030026248 |
ISBN-13 | 978-3-030-02624-0 / 9783030026240 |
Zustand | Neuware |
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