Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene
Seiten
2018
|
Softcover reprint of the original 1st ed. 2017
Springer Verlag, Singapore
978-981-10-9247-3 (ISBN)
Springer Verlag, Singapore
978-981-10-9247-3 (ISBN)
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd–Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<
Introduction.- Experimental and Theoretical Methods.- Design of Pd-Ni Bimetallic Catalyst.- Effect of Oxide Supports on Pd–Ni Bimetallic Catalysts.- Replacing Precious Metals with Carbide Catalysts.- Liquid Phase Hydrogenation of Acetylene.- Conclusion.
Erscheinungsdatum | 18.08.2018 |
---|---|
Reihe/Serie | Springer Theses |
Zusatzinfo | 42 Illustrations, color; 41 Illustrations, black and white; XII, 141 p. 83 illus., 42 illus. in color. |
Verlagsort | Singapore |
Sprache | englisch |
Maße | 155 x 235 mm |
Themenwelt | Naturwissenschaften ► Chemie ► Physikalische Chemie |
Naturwissenschaften ► Chemie ► Technische Chemie | |
Technik | |
Schlagworte | 1,3-butadiene • Acetylene • Liquid-phase hydrogenation • Pd-Ni bimetallic catalyst • Selective hydrogenation |
ISBN-10 | 981-10-9247-8 / 9811092478 |
ISBN-13 | 978-981-10-9247-3 / 9789811092473 |
Zustand | Neuware |
Haben Sie eine Frage zum Produkt? |
Mehr entdecken
aus dem Bereich
aus dem Bereich
Quantenmechanik | Spektroskopie | Statistische Thermodynamik
Buch | Softcover (2024)
De Gruyter (Verlag)
59,95 €
Thermodynamik | Kinetik | Elektrochemie
Buch | Softcover (2024)
De Gruyter (Verlag)
59,95 €
Set aus Lehrbuch und Arbeitsbuch
Buch | Hardcover (2022)
Wiley-VCH (Verlag)
109,00 €